化工社化工社 化学情報印刷レポート · 研究参考用
Thionyl Chloride → 2-[(Phenylmethyl)thio]benzoyl chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | 2-(Benzylsulfanyl)benzoic acid | HCID 264182 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | 2-[(Phenylmethyl)thio]benzoyl chloride | HCID 20067340 | 94.1% |
反応手順
A suspension of 100 g of 2-[(phenylmethyl)thio]benzoic acid and 97.6 g of thionyl chloride in 800 ml of benzene was refluxed for about three hours then evaporated to dryness under vacuum. The residue was triturated with hexane to yield 101.2 g of 2-[(phenylmethyl)thio]benzoyl chloride, m.p. 113° to 116° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04995901 |
| 出典データセット | uspto-grants-1991_02 |
| ORD ID | ord-f6ab892768b743d48204bed41050d080 |
| 出典メモ | uspto-grants-1991_02 |