化工社化工社 化学情報印刷レポート · 研究参考用
1-Bromooctane → 1-Bromo-4-(4-octoxyphenyl)benzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Bromooctane | HCID 8140 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 4-Bromo-4'-hydroxybiphenyl | HCID 95093 | — |
| 溶媒 | Methyl Ethyl Ketone | HCID 6569 | — |
| 生成物 | 1-Bromo-4-(4-octoxyphenyl)benzene | HCID 2801787 | 66% |
反応手順
A mixture of 4-bromo-4′-hydroxybiphenyl (50.00 g, 0.2008 mol), 1-bromooctane (50.38 g, 0.2610 mol), potassium carbonate (47.11 g, 0.3414 mol) and butanone (500 cm3) was heated under reflux overnight. The cooled mixture was filtered and the solvent removed on a rotary evaporator. The crude solid was recrystallised from ethanol to yield a white crystalline solid (47.30 g, 66%, m.pt 120° C.).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06867243B2 |
| 出典データセット | uspto-grants-2005_03 |
| ORD ID | ord-263d104894ca455f8b26e455383efa48 |
| 出典メモ | uspto-grants-2005_03 |