Hydrogen Peroxide → 2,6-Dimethyl-1,4-benzoquinone

HRID 985747

反応式

HRID 985747 の反応式
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[OH:9].[OH:10]O>C(O)(=O)C>[CH3:1][C:2]1[C:3](=[O:9])[C:4]([CH3:8])=[CH:5][C:6](=[O:10])[CH:7]=1

参加物

4

反応物 2

HCID 784Hydrogen PeroxideHCID 113352,6-Dimethylphenol

生成物 1

HCID 682412,6-Dimethyl-1,4-benzoquinone

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

反応条件

温度
55 °C

実験手順

A mixture of 2,6-dimethylphenol (5 mmol) and Ti-superoxide catalyst (125 mg, 20% w/w) in acetic acid (5 ml) was heated with stirring at 50-60° C. under inert atmosphere. To this reaction mixture was added aq. 30% H2O2 (20 mmol) drop wise over 15 min. and heated for 1 h. The catalyst was recovered by simple filtration and 2,6-dimethyl-1,4-benzoquinone formed (97%) was separated by chromatographic purification.

後処理

  1. temperaturewas heated
  2. temperatureheated for 1 h
  3. filtrationThe catalyst was recovered by simple filtration and 2,6-dimethyl-1,4-benzoquinone
  4. customformed (97%)
  5. customwas separated by chromatographic purification

出典と根拠

ORDレコード
ord-5ddbf9b01e3e4181a141ba979e3fdd1e
出典データセット
uspto-grants-2005_03
特許番号
US06872857B1

関連ノート

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