(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide → HCID 67932474、化合物

反応式

NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[C:37]1([S:43]([C:45]2[CH:50]=[CH:49][C:48]([N:51]([CH3:53])[CH3:52])=[C:47]([N+:54]([O-])=O)[CH:46]=2)=[O:44])[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1>>[C:37]1([S:43]([C:45]2[CH:50]=[CH:49][C:48]([N:51]([CH3:52])[CH3:53])=[C:47]([NH2:54])[CH:46]=2)=[O:44])[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1

参加物

反応物 2

HCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

HCID 67932473HCID 67932473、化合物

生成物 1

HCID 67932474HCID 67932474、化合物収率 90%

実験手順

Following the procedure described in Example 39 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of phenyl-(4-dimethylamino-3-nitrophenyl) sulfoxide, the title compound is obtained.

出典と根拠

ORDレコード: ord-97b838510ebc4421898598133d44f326
出典データセット: uspto-grants-1987_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04710323

反応ノート

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