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HRID 986894作成日:2026年10月26日

Azobisisobutyronitrile → Bicyclo[2.2.1]hept-5-ene-2-methanol norbornene maleic anhydride

https://huagongshe.com/reaction/986894

反応式

関与物質

役割名称HCID仕込み量
反応物AzobisisobutyronitrileHCID 6547—
反応物Maleic AnhydrideHCID 7923—
反応物2-NorborneneHCID 10352—
反応物Bicyclo(2.2.1)hept-5-ene-2-methanolHCID 78946—
溶媒TetrahydrofuranHCID 8028—
生成物Bicyclo[2.2.1]hept-5-ene-2-methanol norbornene maleic anhydrideHCID 8675919057%

反応手順

To 70 ml of tetrahydrofuran was added 0.05 M of norbornylene, 0.15 M of bicyclo[2.2.1]hept-5-ene-2-methanol, 0.2 M of maleic anhydride and 0.4 g of AIBN. The resulting solution was reacted at 67° C. for 8 hours. Thereafter, a polymer was precipitated and filtered in petroleum ether/ether (1/1) solution, to obtain the title polymer (yield: 57%).

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US06630281B2
出典データセットuspto-grants-2003_10
ORD IDord-491b8530aac04a57b8bb051cb19f6fe2
出典メモuspto-grants-2003_10