1-Bromohexadecane → HCID 15141162、化合物

HRID 987347ノート

反応式

HRID 987347 の反応式
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].[OH:18][C:19]1[CH:20]=[C:21]([CH:24]=[C:25]([OH:28])[C:26]=1[OH:27])[CH:22]=[O:23]>>[CH2:2]([O:18][C:19]1[CH:20]=[C:21]([CH:24]=[C:25]([O:28][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])[C:26]=1[O:27][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])[CH:22]=[O:23])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

参加物

3

反応物 2

HCID 82131-BromohexadecaneHCID 836513,4,5-Trihydroxybenzaldehyde

生成物 1

HCID 15141162HCID 15141162、化合物

実験手順

The title compound was prepared according to the method as described in Example 9 above from 1-bromohexadecane and 3,4,5-trihydroxy-benzaldehyde, except the reaction mixture was heated at reflux for 4 days. After cooling, the solid material was removed by filtration and the solid washed with dichloromethane. The combined organic extracts were evaporated under reduced pressure to yield the title compound which was recrystallised from dichloromethane-ethanol.

後処理

  1. customThe title compound was prepared
  2. temperaturewas heated
  3. temperatureat reflux for 4 days
  4. temperatureAfter cooling
  5. customthe solid material was removed by filtration
  6. washthe solid washed with dichloromethane
  7. customThe combined organic extracts were evaporated under reduced pressure

出典と根拠

ORDレコード
ord-4081cdd73fc04656868dbfaefafb1f6a
出典データセット
uspto-grants-2003_10
特許番号
US06630128B1

反応ノート

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