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Adamantane → 1-Nitroadamantane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Adamantane | HCID 9238 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 反応物 | Nitric Oxide | HCID 145068 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 1-Adamantanol | HCID 64152 | 17% |
| 生成物 | 1-Nitroadamantane | HCID 64165 | 30% |
反応手順
Into a flask, 1 mmole of adamantane, 0.05 mmole of N-hydroxyphthalimide and 5 ml of acetic acid were added to mix and then the flask was equipped with a gas bag (about 1L) of nitrogen monoxide NO. The mixture was reacted for 8 hours at 100° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, The conversion of adamantane was 95%, and nitroadamantane (yield 30%), adamantanol (yield 17%) and acetyloxyadamantane (yield 33%) were formed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06468487B1 |
| 出典データセット | uspto-grants-2002_10 |
| ORD ID | ord-936800d461a648ebb2b88230cf9f8568 |
| 出典メモ | uspto-grants-2002_10 |