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Acetic Acid → 1-Nitroadamantane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Adamantane | HCID 9238 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 生成物 | 1-Nitroadamantane | HCID 64165 | 81% |
反応手順
1.8 g (0.024 mole based on N2O3 basis) of the frozen blue liquid, 1 mmole of adamantane, 0.05 mmole of N-hydroxyphthalimide and 5 ml of acetic acid were mixed, and then the mixture was reacted for 10 hours at 100° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, nitroadamantane (yield 81%) was formed with conversion of 99%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06468487B1 |
| 出典データセット | uspto-grants-2002_10 |
| ORD ID | ord-02f480573d1a4329bcc8d5451fa6a9a5 |
| 出典メモ | uspto-grants-2002_10 |