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Acetic Acid → 1-Nitroadamantane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Adamantane | HCID 9238 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 生成物 | 1-Nitroadamantane | HCID 64165 | 64% |
反応手順
Into a flask, 1 mmole of adamantane, 0.1 mmole of N-hydroxyphthalimide and 6 ml of acetic acid were added to mix. The flask was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L), and then the mixture was reacted for 20 hours at 110° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and 1-nitroadamantane (yield 64%) and 1,3-dinitroadamantane (yield 12%) were formed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06468487B1 |
| 出典データセット | uspto-grants-2002_10 |
| ORD ID | ord-aec03bee9da5464ca1e458d8bae2b610 |
| 出典メモ | uspto-grants-2002_10 |