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Oxygen → 1-Nitroadamantane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | (Trifluoromethyl)benzene | HCID 7368 | — |
| 反応物 | Adamantane | HCID 9238 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 反応物 | Nitrogen Dioxide | HCID 178526396 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 1-Adamantanol | HCID 64152 | 2% |
| 生成物 | 1-Nitroadamantane | HCID 64165 | 73% |
| 生成物 | 1-Adamantyl acetate | HCID 519973 | 1% |
反応手順
Into a flask, 1 mmole of adamantane, 0.05 mmole of N-hydroxyphthalimide, 15 mmole of nitrogen dioxide (NO2), 1 ml of acetonitrile and 2 ml of trifluoromethylbenzene were added and stirred for 5 hours at 60° C. in an atmosphere of oxygen. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and nitroadamantane (yield 73%), adamantanol (yield 2%), acetyloxyadamantane (yield 1%) and adamantanone (yield 3%) were formed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06468487B1 |
| 出典データセット | uspto-grants-2002_10 |
| ORD ID | ord-684f6da515db4ca99b2f29e56dd22d9f |
| 出典メモ | uspto-grants-2002_10 |