化工社化工社 化学情報印刷レポート · 研究参考用
1,3-Dinitroadamantane → 1-Amino-3-nitroadamantane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,3-Dinitroadamantane | HCID 583950 | — |
| 触媒 | Nickel | HCID 935 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 生成物 | 1-Amino-3-nitroadamantane | HCID 18410483 | 80% |
反応手順
The reaction was effected in the same manner as Example 65 except for using Raney nickel (5 mole % of Ni relative to a substrate) instead of 5% Pd-C and that reacting for 4 hours. The conversion of 1,3-dinitroadamantane was 99%, and 1-amino-3-nitroadamantane (yield 80%) was formed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06468487B1 |
| 出典データセット | uspto-grants-2002_10 |
| ORD ID | ord-321fca3a1c2d4b3d8076f12075741850 |
| 出典メモ | uspto-grants-2002_10 |