反応式
[N+:1]([C:4]12[CH2:13][CH:8]3[CH2:9][CH:10]([CH2:12][C:6]([N+:14]([O-])=O)([CH2:7]3)[CH2:5]1)[CH2:11]2)([O-:3])=[O:2]>[Ni].[Pd]>[NH2:14][C:6]12[CH2:7][CH:8]3[CH2:9][CH:10]([CH2:11][C:4]([N+:1]([O-:3])=[O:2])([CH2:13]3)[CH2:5]1)[CH2:12]2参加物
4
実験手順
The reaction was effected in the same manner as Example 65 except for using Raney nickel (5 mole % of Ni relative to a substrate) instead of 5% Pd-C and that reacting for 4 hours. The conversion of 1,3-dinitroadamantane was 99%, and 1-amino-3-nitroadamantane (yield 80%) was formed.
出典と根拠
- ORDレコード
- ord-321fca3a1c2d4b3d8076f12075741850
- 出典データセット
- uspto-grants-2002_10
- 特許番号
- US06468487B1
関連ノート
読み込み中…