Hydrochloric Acid → Iminoethyl methoxyacetate hydrochloride

HRID 992650

反応式

HRID 992650 の反応式
[CH3:1][O:2][CH2:3][C:4]#[N:5].C([OH:8])C.[ClH:9].[CH2:10]([O:12][CH2:13]C)C>>[ClH:9].[CH3:10][O:12][CH2:13][C:1]([O:2][CH2:3][CH:4]=[NH:5])=[O:8]

参加物

5

反応物 4

HCID 313Hydrochloric AcidHCID 702EthanolHCID 3283Diethyl EtherHCID 74442Methoxyacetonitrile

生成物 1

HCID 57478929Iminoethyl methoxyacetate hydrochloride

実験手順

A solution of 35.5 g (0.50 mol) of methoxyacetonitrile in 29 ml (23 g, 0.50 mol) of ethanol and 30 ml of absolute diethylether was cooled to 0° C. and over 1 hour 22.5 g (0.62 mol) of hydrogen chloride gas was introduced, whilst towards the end of the introduction of gas the reaction product crystallised out. To complete the precipitation 130 ml of diethylether were added and the colourless needles were filtered off.

後処理

  1. additionwas introduced, whilst towards the end of the introduction of gas the reaction product
  2. customcrystallised out
  3. customthe precipitation 130 ml of diethylether
  4. additionwere added
  5. filtrationthe colourless needles were filtered off

出典と根拠

ORDレコード
ord-a52066071dfd4d80a5ea89aab03b1819
出典データセット
uspto-grants-2002_10
特許番号
US06469039B1

関連ノート

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