티오포스겐

티오포스겐 · CSCl2 · Thiocarbonyl dichloride · THIOCARBONYL CHLORIDE · Carbon chlorosulfide · Carbonothioyl dichloride · Thiophosg · Thiofosgen

https://huagongshe.com/ko/chemical/10040

식별자 및 물리적 특성

CAS No.	463-71-8
분자식	CCl2S
평균 분자량	114.98 g/mol
단동위원소 질량	113.9097766 g/mol
SMILES	S=C(Cl)Cl
InChIKey	ZWZVWGITAAIFPS-UHFFFAOYSA-N
PubChem CID	10040
ChEBI	CHEBI:29366
EC No.	207-341-6
DTXSID	DTXSID2060046
현지명	티오포스겐

화학 및 물리적 성질

XLogP	2.4
극성 표면적	32.1
수소 결합 공여자 수	0
수소 결합 수용자 수	1
회전 가능 결합 수	0
무거운 원자 수	4
형식 전하	0
복잡도	29
냄새	Sharp choking odorMalodorous
밀도	1.513 at 68 °F (USCG, 1999) - Denser than waterwill sink1.508 @ 15 °C
Color/Form	Reddish liquidReddish-yellow liquid
용해도	Insoluble in water, soluble in ethanol and ethyl ether클로로포름에 용해됨
Corrosivity	Corrodes metals in presence of moistureCorrosive lachrymator and moisture sensitive compound.
끓는 점	163 °F at 760 mmHg (USCG, 1999)73 °C
Decomposition	Decomposes above 200 °C to carbon disulfide (very flammable) and carbon tetrachloride.When heated to decomposition it emits very toxic fumes of /chlorides/ Cl- and /sulfur oxides/ SOx.
증기압	116.0 [mmHg]
Surface Tension	25 dynes/cm= 0.025 N/m @ 20 °C
굴절률	Index of refraction: 1.5442 @ 20 °C/Dn20/D 1.548(lit.)
Heat of Combustion	-3,400 BTU/lb= -1,900 cal/g= -80x10+5 J/kg
Heat of Vaporization	128 BTU/lb= 71 cal/g= 3.0x10+5 J/kg
녹는점	<25 °C
증기 밀도	4 (vs air)
인화점	62 °C
저장 조건	2-8°C
물리적 상태	액체
색상	붉은 액체
용해도	찬물에서는 분해가 느리고 뜨거운 물에서는 빨리 분해됨
BRN	1633495
안정성	안정적인. 그러나 물과 격렬하게 반응하여 유독한 연기를 생성합니다. 물, 알코올과 호환되지 않습니다. 2~8C에서 냉장 보관하세요.
NIST	Carbonothioic dichloride(463-71-8)
EPA	Thiophosgene (463-71-8)

화학적 성질

Reddish liquid. Decomposes in water and alcohol; soluble in ether.

안전 및 규제

GHS 분류	DangerH302: Harmful if swallowed [Warning Acute toxicity, oral]H315: Causes skin irritation [Warning Skin corrosion/irritation]H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]H331: Toxic if inhaled [Danger Acute toxicity, inhalation]H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Hazards Identification	Toxic/poison by inhalation (TIH/PIH)
규제 정보	Chemical: Carbonothioic dichlorideStatus: No longer Valid Update: 23-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/25354Thiophosgene: HSNO Approval: HSR003934 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
운송 라벨(DOT)	Poison Inhalation Hazard
화재 위험	Special Hazards of Combustion Products: Toxic phosgene, hydrogen chloride, and sulfur dioxide may be generated in a fire.Behavior in Fire: Decomposes above 200 °C to carbon bisulfide (very flammable) and carbon tetrachloride. (USCG, 1999)· Combustible material: may burn but does not ignite readily.· Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.· When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.· Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).· Vapors may travel to source of ignition and flash back.· Corrosives in contact with metals may evolve flammable hydrogen gas.· Containers may explode when heated or if contaminated with water.
건강 유해성	Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach. (USCG, 1999)

용도

Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).

일반 설명

A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.