질산리튬

Lithium nitrate appears as a white to light yellow colored crystalline solid. Denser than water. Contact with the material may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. May cause the acceleration of the burning of combustible materials. Prolonged exposure to heat or flames may result in an explosion.

Colorless deliquescent solid; [Merck Index] White to light yellow deliquescent solid; [CAMEO] Colorless hygroscopic crystals; [Sigma-Aldrich MSDS]

This chemical does not meet GHS hazard criteria for 0.4% (1 of 253) of reports.

Danger

H272 (90.5%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]；H302 (70.4%): Harmful if swallowed [Warning Acute toxicity, oral]；H319 (71.1%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

P210, P220, P264, P264+P265, P270, P280, P301+P317, P305+P351+P338, P330, P337+P317, P370+P378, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 253 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 1 of 253 reports by companies.；There are 13 notifications provided by 252 of 253 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Chemical: Nitric acid, lithium salt, trihydrate

Chemical: Nitric acid, lithium salt

Nitric acid, lithium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, lithium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 18-11-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/13673

Lithium nitrate: Does not have an individual approval but may be used under an appropriate group standard

Nitric acid, lithium salt: HSNO Approval: HSR001329 Approved with controls

IMAP assessments - Nitric acid, lithium salt, trihydrate: Human health tier I assessment

IMAP assessments - Nitric acid, lithium salt: Human health tier I assessment

Excerpt from ERG Guide 140 [Oxidizers]:；CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (ERG Guide 112). These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2024)

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).；· These substances will accelerate burning when involved in a fire.；· Some may decompose explosively when heated or involved in a fire.；· May explode from heat or contamination.；· Some will react explosively with hydrocarbons (fuels).；· May ignite combustibles (wood, paper, oil, clothing, etc.).；· Containers may explode when heated.；· Runoff may create fire or explosion hazard.

Excerpt from ERG Guide 140 [Oxidizers]:；Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024)

· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.；· Fire may produce irritating, corrosive and/or toxic gases.；· Runoff from fire control or dilution water may cause environmental contamination.

Causes normocytic anemia, changes in leukocyte counts, and hyperglycemia in 7-week intermittent oral studies of rats; [RTECS] A strong oxidizing agent that may accelerate the burning of combustible materials; May cause irritation; [CAMEO] An oxidizer that may intensify fire; May cause irritation; Targets the CNS, kidney, cardiovascular system, and thyroid; Possible carcinogen; [Sigma-Aldrich MSDS] See Lithium. See NITRATES and NITRITES.

LITHIUM NITRATE is an oxidizing agent. Mixtures with alkyl esters may explode owing to the formation of alkyl nitrates; mixtures with phosphorus, tin(II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109].

Lithium nitrate

UN2722

Div 5.1 Oxidizer (49 eCFR § 173.127)

PG III: the degree of danger presented by the material is minor；For more information about the packing group assignment, please visit 49 eCFR § 173

Excerpt from ERG Guide 140 [Oxidizers]:；SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.；LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If it can be done safely, move undamaged containers away from the area around the fire.；FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: For ammonium nitrate products: Do not fight cargo fire. Withdraw, evacuate and isolate area for at least 1600 meters (1 mile). Treat as an explosive (ERG Guide 112). Do not enter area for 24 hours or until expert advice has been provided. Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.；· Keep unauthorized personnel away.；· Stay upwind, uphill and/or upstream.；· Ventilate closed spaces before entering, but only if properly trained and equipped.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.；· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.；· Stop leak if you can do it without risk.；· Do not get water inside containers.；Small Dry Spill；· With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.；Small Liquid Spill；· Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.；Large Spill；· Dike far ahead of liquid spill for later disposal.

Excerpt from ERG Guide 140 [Oxidizers]:；Refer to the "General First Aid" section. Specific First Aid: Contaminated clothing may be a fire risk when dry. (ERG, 2024)

General First Aid:；· Call 911 or emergency medical service.；· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.；· Move victim to fresh air if it can be done safely.；· Administer oxygen if breathing is difficult.；· If victim is not breathing:；-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.；-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).；-- If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.；· Remove and isolate contaminated clothing and shoes.；· For minor skin contact, avoid spreading material on unaffected skin.；· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.；· For severe burns, immediate medical attention is required.；· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.；· Keep victim calm and warm.；· Keep victim under observation.；· For further assistance, contact your local Poison Control Center.；· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.；Specific First Aid:；· Contaminated clothing may be a fire risk when dry.

· Wear positive pressure self-contained breathing apparatus (SCBA).；· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.；· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

Excerpt from ERG Guide 140 [Oxidizers]:；Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Do not get water inside containers.；SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.；SMALL LIQUID SPILL: Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.；LARGE SPILL: Dike far ahead of liquid spill for later disposal. (ERG, 2024)

Excerpt from ERG Guide 140 [Oxidizers]:；IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.；LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).；FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. If ammonium nitrate products are in a tank, rail car or truck and involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2024)

Immediate precautionary measure；· Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.；Large Spill；· Consider initial downwind evacuation for at least 100 meters (330 feet).；Fire；· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.；· If ammonium nitrate products are in a tank, rail car or truck and involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions.

2.0 [mg/m3]

17 [mg/m3]

100 [mg/m3]

Excerpt from ERG Guide 140 [Oxidizers]:；Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)

Small Fire；· Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.；Large Fire；· Flood fire area with water from a distance.；· Do not move cargo or vehicle if cargo has been exposed to heat.；· If it can be done safely, move undamaged containers away from the area around the fire.；Fire Involving Tanks, Rail Tank Cars or Highway Tanks；· For ammonium nitrate products: Do not fight cargo fire. Withdraw, evacuate and isolate area for at least 1600 meters (1 mile). Treat as an explosive (GUIDE 112). Do not enter area for 24 hours or until expert advice has been provided.；· Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.；· Cool containers with flooding quantities of water until well after fire is out.；· ALWAYS stay away from tanks in direct contact with flames.；· For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Methemoglobinemia can be treated with supplemental oxygen and methylene blue 1% solution administered intravenously slowly over five minutes followed by IV flush with normal saline. Methylene blue restores the iron in hemoglobin to its normal (reduced) oxygen-carrying state. (L1613)

Nitrate's toxicity is a result of it's conversion to nitrite once in the body. Nitrite causes the autocatalytic oxidation of oxyhemoglobin to hydrogen peroxide and methemoglobin. This elevation of methemoglobin levels is a condition known as methemoglobinemia, and is characterized by tissue hypoxia, as methemoglobin cannot bind oxygen. (A2450, L1613)

Nitrate and nitrite poisoning causes methemoglobinemia. Symptoms include cyanosis, cardiac dysrhythmias and circulatory failure, and progressive central nervous system (CNS) effects. CNS effects can range from mild dizziness and lethargy to coma and convulsions. (L1137)

Chemical: Nitric acid, lithium salt, trihydrate

Chemical: Nitric acid, lithium salt

Nitric acid, lithium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, lithium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 18-11-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/13673

Lithium nitrate: Does not have an individual approval but may be used under an appropriate group standard

Nitric acid, lithium salt: HSNO Approval: HSR001329 Approved with controls

Intake of some amount of nitrates and nitrites is a normal part of the nitrogen cycle in humans. In vivo conversion of nitrates to nitrites can occur in the gastrointestional tract under the right conditions, significantly enhancing nitrates' toxic potency. The major metabolic pathway for nitrate is conversion to nitrite, and then to ammonia. Nitrites, nitrates, and their metabolites are excreted in the urine. (L1137)

Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)

Nitric acid, lithium salt (1:1): ACTIVE