메틸틴트리클로라이드
Trichloromethylstannane
기본 정보
- CAS
993-16-8- 표준 SMILES
[CH3][Sn]([Cl])([Cl])[Cl]- InChIKey
YFRLQYJXUZRYDN-UHFFFAOYSA-K- 분자식
- CH3Cl3Sn
- 평균 분자량
- 240.1 g/mol
- 단동위원소 질량
- 239.83222784
개요
Monomethyltin trichloride is an organotin compound. Tin is a chemical element with the symbol Sn and atomic number 50. It is a natural component of the earth's crust and is obtained chiefly from the mineral cassiterite, where it occurs as tin dioxide. (L307, L309)
이름 및 식별자
- 우선 이름
- Trichloromethylstannane
- IUPAC
- trichloro(methyl)stannane
- 현지명
- 메틸틴트리클로라이드
- 영어명
- Methyltin trichloride
- 분자식
- CH3Cl3Sn
- 분자량
- 240.1
이름 및 동의어
Methyltin trichloride993-16-8TrichloromethylstannaneMethyltrichlorotintrichloro(methyl)stannaneMonomethyltin trichlorideTrichloromethyltinStannane, trichloromethyl-MethyltrichlorostannaneTin, methyl-, trichlorideCCRIS 6327DTXSID1027346
이름 더 보기
메틸틴트리클로라이드삼염소화주석메틸삼염소화주석메틸(Monomethyltintrichloride)메틸틴 트라이클로라이드methyl-titrichlorideMONOMETHYLTINCHLORIDEMethyltrichlorotin(IV)methyltrichloro-stannantrichloromethyl-stannan
Stannane, methyltrichloro-EINECS 213-608-8Q2E6V14U06DTXCID907346MMTCIStannane, methyltrichloroStannane, trichloromethylRefChem:899236
데이터베이스 식별자
- CAS
993-16-8- PubChem CID
- 101940
- DTXSID
DTXSID1027346- UNII
- Q2E6V14U06
- EC Number
- 213-608-8
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 5
- 형식 전하
- 0
- 복잡도
- 28.4
실험 및 물리화학적 성질
Chemical ClassesMetals -> Tin Compounds, Organic
Vapor Pressure1.25 [mmHg]
Physical Description
Liquid
Produced as a solid or aqueous solution; Off-white to gray solid or clear colorless liquid; [OECD: SIDS Dossier] Off-white crystalline solid; [Sigma-Aldrich MSDS]
물리화학적 성질
- 녹는점
- 48 · 48-51 °C(lit.)
- 끓는 점
- 171 °C · 171 °C(lit.)
- 인화점
- 105 °F · 105 °F
- 저장 조건
- Flammables area
- 용해도
- 클로로포름, 메탄올에 용해됩니다.
- 물리적 상태
- 수정 같은
- 색상
- 하얀색
- InChI
- InChI=1S/CH3.3ClH.Sn/h1H3;3*1H;/q;;;;+3/p-3
- InChIKey
- YFRLQYJXUZRYDN-UHFFFAOYSA-K
- SMILES
- [Sn](Cl)(Cl)(Cl)C
- EPA
- Stannane, trichloromethyl- (993-16-8)
화학적 성질
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Warning
H361d: Suspected of damaging the unborn child [Warning Reproductive toxicity]
P203, P280, P318, P405, and P501 (click each P-code to see the statement)
Danger
H228 (43.9%): Flammable solid [Danger Flammable solids]
P203, P210, P240, P241, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P318, P321, P330, P333+P317, P361+P364, P362+P364, P363, P370+P378, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
유해성 정보
Regulatory Information
Chemical: Stannane, trichloromethyl-
Stannane, trichloromethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Stannane, trichloromethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Stannane, trichloromethyl-: Does not have an individual approval but may be used under an appropriate group standard
Other Safety InformationIMAP assessments - Stannane, trichloromethyl-: Human health tier II assessment
Hazards Summary
Produced as a mixture with up to 10% dimethyltin dichloride (CAS# 753-73-1); [ECHA - Proposal for Harmonised Classification and Labelling] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause skin sensitization; Harmful by ingestion; Toxic by inhalation and skin absorption; [Sigma-Aldrich MSDS] See Tin, organic compounds.
Hazard Classes and Categories
Flam. Sol. 2 (43.9%)
Acute toxicity (ingestion) - category 4
Repr. 2
안전 및 보호
화학 및 산업
약리 정보
Metabolism/Metabolites
Though tin metal is very poorly absorbed, tin compounds may be absorbed via oral, inhalation, or dermal routes, with organotin compounds being much more readily absorbed than inorganic tin compounds. Tin may enter the bloodstream and bind to hemoglobin, where it is distributed and accumulates mainly in the kidney, liver, lung, and bone. Organotin compounds may undergo dealkylation, hydroxylation, dearylation, and oxidation catalyzed by cytochrome P-450 enzymes in the liver. The alkyl products of dealkylation are conjugated with glutathione and further metabolized to mercapturic acid derivatives. Tin and its metabolites are excreted mainly in the urine and feces. (L308)
용도 및 제조
UsesUsed to make other organotin compounds; [ECHA - Proposal for Harmonised Classification and Labelling]
U.S. Production2023: 550,000 - <1,000,000 lb
Industry UsesIntermediate
General Manufacturing Information
All Other Chemical Product and Preparation Manufacturing
Stannane, trichloromethyl-: ACTIVE
응용 분야
용도A chemical used in the synthesis of metallasilesesquiloxanes. Also used in the preparation of organotin(IV) complexes showing antibacterial activities.
관련 반응
5건
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