(Dimethylphenylsilyl) boronic acid pinacol ester
기본 정보
- CAS
185990-03-8- 표준 SMILES
CC1(C)OB([Si](C)(C)c2ccccc2)OC1(C)C- InChIKey
ARMSAQNLTKGMGM-UHFFFAOYSA-N- 분자식
- C14H23BO2Si
- 평균 분자량
- 262.23 g/mol
- 단동위원소 질량
- 262.1560367
이름 및 식별자
- 우선 이름
- (Dimethylphenylsilyl) boronic acid pinacol ester
- IUPAC
- dimethyl-phenyl-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane
- 영어명
- (Dimethylphenylsilyl)boronic acid pinac&
- 분자식
- C14H23BO2Si
- 분자량
- 262.23
이름 및 동의어
(Dimethylphenylsilyl) boronic acid pinacol esterRefChem:406190874-932-9185990-03-8(Dimethylphenylsilyl)boronic acid pinacol esterDimethyl(phenyl)(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silaneDimethyl-phenyl-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silaneMFCD056641112-(Dimethylphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(DIMETHYLPHENYLSILYL)BORONIC ACID PINAC&(Dimethylphenylsilyl)boronicacidpinacolesterC14H23BO2Si
이름 더 보기
SKL219diMethylphenylsilyl boronic esterDimethylphenylsilyl boronic pinacol ester(DiMethylphenylsilyl)boronic acid pinacol ester 95%2-(Dimethylphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborol...
SCHEMBL12470176DTXSID00436709ARMSAQNLTKGMGM-UHFFFAOYSA-NAKOS015908903DS-7463FD60077SY052857DB-200392
데이터베이스 식별자
- CAS
185990-03-8- PubChem CID
- 10199126
- DTXSID
DTXSID00436709- EC Number
- 874-932-9
- Nikkaji
- J1.044.235D
물성
구조 계산 물성
- 극성 표면적
- 18.5 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 2
- 무거운 원자 수
- 18
- 형식 전하
- 0
- 복잡도
- 293
물리화학적 성질
- 끓는 점
- 120 °C/0.08mmHg · 120°C/0.08mmHg(lit.)
- 밀도
- 0.962 g/mL · 0.962 g/mL at 25 °C
- 굴절률
- 20 · n20/D 1.4946
- 인화점
- 110 °C · 110 °C
- 저장 조건
- Inert atmosphere,Room Temperature
- 용해도
- 일반적인 유기용매 에 용해됨.
- 물리적 상태
- 투명한 액체
- 색상
- Colorless to Light yellow to Light orange
- Specific Gravity
- 0.962 · 0.962
- InChI
- 1S/C14H23BO2Si/c1-13(2)14(3,4)17-15(16-13)18(5,6)12-10-8-7-9-11-12/h7-11H,1-6H3
- InChIKey
- ARMSAQNLTKGMGM-UHFFFAOYSA-N
- SMILES
- CC1(C)OB(OC1(C)C)[Si](C)(C)c2ccccc2
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.
안전 데이터
- wgk
- 3
- HS 번호
- 2934.99.4400
- 스토리지 클래스
- 10 - Combustible liquids
화학 및 산업
응용 분야
용도2-(Dimethylphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane is widely used as silaboration and silylation reagent for unsaturated organic compounds; a derivative having diethylamino group on the silicon atom for use as a precursor for silylene generation.
제조 방법
2-(Dimethylphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1) is prepared by reaction of dimethylphenylsilyllithium with 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (pinacolborane, 2 equiv) or 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (2 equiv).
상·하류 제품 정보
상류 원료
하류 제품
관련 반응
1건
화합물 노트
불러오는 중…