트리에틸알루미늄

생산 방법In a typical example, a slurry is prepared containing 7 wt % aluminum powder (0.1 wt% zirconium catalyst content) and 45 wt% recycled triethylaluminum in a paraffin hydrocarbon fraction, boiling range 177 – 260 ℃. The slurry is pumped into the reactor at a rate of 1.5 m3/h, at a reactor temperature of 132 ℃, while hydrogen is introduced at the bottom to maintain a partial pressure of 10 MPa. Excess hydrogen is removed in flash drum, wherein pressure is decreased to 3 MPa and temperature is lowered to prevent thermal reversal of the reaction. In the ethylation reactor sufficient ethylene is added to react completely with the Al – H bonds. Temperature is held at around 85 ℃ or somewhat higher. The addition rate increases with temperature, but carboalumination of ethylene also can occur to formn-butyl groups, especially at higher temperatures. Hydrogen and ethylene partial pressure is kept low in ethylation reactor to minimize hydrogenation of ethylene to ethane and to reduce excess carboalumination products. Excess ethylene and hydrogen are removed in flash drum. A portion of the triethylaluminum product solution is recycled to reactor.

알루미늄을 포함하는 고압멸균기 내로 틸렌과 수소의 도입에 의해 제조됨. 그 반응은 중간 정도의 온도와 여러 압력에서 진행됨