Potassium bisulfide (HCID 102109)

개요

This material contains potassium hydrosulfide in solution. It will have a rotten egg like odor. It has a pH between 8.5-11.5. It is a transparent to dark green liquid. Contact with heat or acidic materials will evolve highly toxic hydrogen sulfide. The liquid is highly corrosive to the skin and eyes. Ingestion causes severe burning and corrosion in all portions of the gastrointestinal tract.

이름 및 식별자

우선 이름: Potassium bisulfide
IUPAC: potassium sulfanide
현지명: 칼륨 히드로황화물
영어명: POTASSIUM HYDROSULFIDE
분자식: HKS
분자량: 72.17

이름 및 동의어

potassium hydrosulfide1310-61-8Potassium bisulfidePotassium hydrogensulphidepotassium hydrogen sulfidePotassium sulfide (K(SH))SX1L03AL9IEINECS 215-182-9DTXSID6061654POTASSIUM BISULFIDE [MI]Potassium hydrogen sulfide, anhydrousPotassium mercaptan

이름 더 보기

칼륨히드로황화물칼륨히드로황화물KSHKaliumhydrogensulfidpotassiumsulfide(k(sh))Potassiumhydrogensulfide,anhydrous,min.95%POTASSIUM HYDROSULFIDE ISO 9001：2015 REACHPotassium hydrogen sulfide, anhydrous, min. 95%

RefChem:867731Potassium sulfide (K(SH)POTASSIUM HYDROSULPHIDEDTXCID5034016POTASSIUM HYDROSULPHIDE (CORROSIVE LIQUIDS, TOXIC, N.O.S.)potassium;sulfanideMFCD00061365UNII-SX1L03AL9I

데이터베이스 식별자

CAS: 1310-61-8
PubChem CID: 102109
DTXSID: DTXSID6061654
UNII: SX1L03AL9I
EC Number: 215-182-9
Nikkaji: J96.417D

물성

구조 계산 물성

극성 표면적: 1 Å²
수소 결합 공여자 수: 1
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 2
형식 전하: 0
복잡도: 2

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Sulfur Compounds

Physical Description · 2건

This material contains potassium hydrosulfide in solution. It will have a rotten egg like odor. It has a pH between 8.5-11.5. It is a transparent to dark green liquid. Contact with heat or acidic materials will evolve highly toxic hydrogen sulfide. The liquid is highly corrosive to the skin and eyes. Ingestion causes severe burning and corrosion in all portions of the gastrointestinal tract.

Colorless, deliquescent or white, highly hygroscopic solid; [Merck Index] Solution: Transparent to dark green liquid with an odor of rotten eggs; [CAMEO] Off-white powder with an odor of rotten eggs; Hygroscopic; [Strem MSDS]

물리화학적 성질

녹는점: 450 · 450-510° forming a dark red liquid
밀도: 1.7 · 1.70
용해도: DMSO(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태: 가루
색상: 흰색에서 황백색까지
수용성: 2 O, · 매우 잘 녹는 H2O, 알코올 [MER06]
안정성: 공기에 민감한, 흡습성
EPA: Potassium sulfide (K(SH)) (1310-61-8)

화학적 성질

White to yellow crystals; hydrogen sul- fide odor. Forms the polysulfide when exposed to air. Hygroscopic; soluble in alco- hol and water.

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 25% (1 of 4) of reports.

Danger

H228 (50%): Flammable solid [Danger Flammable solids]

P203, P210, P235, P240, P241, P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P318, P319, P321, P330, P333+P317, P337+P317, P362+P364, P363, P370+P378, P391, P403+P233, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 4 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationChemical: Potassium sulfide (K(SH))

DOT LabelCorrosive Poison

Fire HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Health HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Hazards Summary · 1건

Usually found as the hemihydrate; Quickly turns yellow on exposure to air forming polysulfides and hydrogen sulfide; [Merck Index] In solution, reacts with water and may form hydrogen sulfide; Corrosive to skin and eyes; [CAMEO] May produce hydrogen sulfide gas on contact with air or stomach acids; Causes burns; Danger of irreversible effects; Inhalation may cause corrosive effects on the respiratory tract; [Strem MSDS] See Hydrogen sulfide.

Reactive GroupSulfides, Inorganic

안전 및 보호

Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

First AidExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

독성 정보

Adverse EffectsOther Poison - Chemical Asphyxiant

안전 데이터

tsca: TSCA listed
ridadr: 1382
포장분류: II
위험 등급: 4.2
기존화학 물질: KE-29136

화학 및 산업

용도 및 제조

Uses · 2건

Used in separation of metals; [Hawley]

Metal Extraction and Refining [Category: Industry]

General Manufacturing InformationPotassium sulfide (K(SH)): ACTIVE

응용 분야 · 2건

용도Separation of heavy metals.

일반 설명POTASSIUM HYDROSULFIDE contains potassium hydrosulfide in solution. POTASSIUM HYDROSULFIDE will have a rotten egg like odor. POTASSIUM HYDROSULFIDE has a pH between 8.5-11.5. POTASSIUM HYDROSULFIDE is a transparent to dark green liquid. Contact with heat or acidic materials will evolve highly toxic hydrogen sulfide. The liquid is highly corrosive to the skin and eyes. Ingestion causes severe burning and corrosion in all portions of the gastrointestinal tract.