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무스타르드 기체

Bis-(2-chloroethyl)sulfide

HCID 10461
노트반응

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기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
505-60-2
표준 SMILES
ClCCSCCCl
InChIKey
QKSKPIVNLNLAAV-UHFFFAOYSA-N
분자식
C4H8Cl2S
평균 분자량
159.081 g/mol
단동위원소 질량
157.97237662

이름 및 식별자

우선 이름
Bis-(2-chloroethyl)sulfide
IUPAC
1-Chloro-2-[(2-chloroethyl)sulfanyl]ethane
현지명
무스타르드 기체
영어명
Mustard gas
분자식
C4H8Cl2S
분자량
159.08

이름 및 동의어

비스(2-클로로에틸)설파이드머스타드가스무스타르드기체머스타드가스1,1'-싸이오비스[2-클로로에테인]1,1'-티오비스(2-클로로에탄)1-클로로-2-(2-클로로에틸설판일)에테인1-클로로-2-(베타-클로로에틸싸이오)에테인2,2'-다이클로로다이에틸 설파이드2,2'-다이클로로에틸 설파이드머스타드 가스베타,베타'-다이클로로다이에틸 설파이드
이름 더 보기
베타,베타'-다이클로로에틸 설파이드베타,베타'-디클로로디에틸황화물베타-클로로에틸아이소뷰틸 설파이드비스(2-클로로에틸) 설파이드에테인, 1,1'-싸이오비스[2-클로로-겨자가스YPERITEMustard gasSULFURMUSTARDSULPHURMUSTARDDichlorodiethyl sulfidebis-β-chloroethyl sulfideBIS(2-CHLORETHYL)SULPHIDEβ,β'-dichloroethyl sulfideBIS(2-CHLOROETHYL)SULPHIDEQKSKPIVNLNLAAV-UHFFFAOYSA-N

데이터베이스 식별자

CAS
505-60-2
PubChem CID
10461
DTXSID
DTXSID0037100
ChEMBL
CHEMBL455341
ChEBI
CHEBI:25434
UNII
T8KEC9FH9P
EC Number
684-527-7
Nikkaji
J1.571G

물성

물리화학적 성질

녹는점
13 · 13-14°
끓는 점
760 · bp760 215-217°; bp10 98°
밀도
13 · d13 1.338 (solid); d420 1.2741 (liq)
증기 밀도
5.4 · 5.4
굴절률
20 · nD20 1.53125
인화점
221 °F · 221°F
물리적 상태
액체
색상
무색(순수한 경우), 담황색의 유성 액체
수용성
0.69 g/L · 0.69g/L(25℃)
Henry's Law Constant
3 · 3.0×10-1 mol/(m3Pa) at 25℃, Hine and Mookerjee (1975)
EPA
Mustard gas (505-60-2)

화학적 성질

Mustard gas, a chlorinated sulfur compound(s), is an oily, yellow to black liquid (clear when pure). It has a sweet, burnt garlic or horseradish-like odor. The odor threshold for HD is 0.0006 milligram per cubic meter.

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

안전 데이터

tsca
TSCA listed
ridadr
2927
독성
LD50 in rats, mice (mg/kg): 3.3, 8.6 i.v. (Anslow)
포장분류
I
위험 등급
6.1(a)
기존화학 물질
KE-05-1277
유해 물질 데이터
505-60-2(Hazardous Substances Data)
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 머스타드 가스 및 이를 0.1% 이상 함유한 혼합물
유해화학물질 필터링
97-1-66
중점관리물질 필터링
별표2-60
암, 돌연변이성물질 필터링
44

화학 및 산업

응용 분야 · 3건

개요Mustard gas/sulphur mustard is an organic chemical substance synthesised by treating sulphur dichloride with ethylene. Mustard gas is a chemical substance closely related to chemical warfare class agents. It is a cytotoxic and vesicant chemical substance, and exposures are known to cause blisters on the exposed skin. Pure mustard gas/sulphur mustards are colourless, viscous liquids at room temperature. However, when used in impure form, such as warfare agents, they appear as yellow brown in colour. As the name indicates, mustard gas has an odour resembling the garlic, horseradish, or mustard plants. Mustard gas is the common name given to 1,1-thiobis(2-chloroethane), a chemical warfare agent that is believed to have first been used near Ypres in Flanders on 12 July 1917. Mustard gas is a thick liquid at ambient temperature. It is heavier than water as a liquid and heavier than air as a vapour. It does not occur naturally in the environment. Pure liquid mustard gas is colourless and odourless. It is stable, combustible, and incompatible with strong oxidising agents. Mustard gas on mixing with other chemical substances appears brown in colour and gives off a garlic-like smell. When heated, it decomposes and emits highly toxic, corrosive fumes and fumes of oxides of sulphur and chlorine-containing compounds. It is soluble in fats and oils, gasoline, kerosene, acetone, carbon tetrachloride, alcohol, tetrachloroethane, ethylbenzoate, and ether, and solubility in water is negligible. It is miscible with the OP nerve agents. During earlier years, mustard gas was in use as an important chemical warfare agent. In fact, it was used in large amounts during World Wars I and II. Mustard gas was first used by the German army in 1917. It was one of the most lethal of all the poisonous chemicals used during the war. It was reportedly used in the Iran–Iraq war in 1980–1988. It is not presently used in the United States, except for research purposes.

용도Formerly in chemical warfare. In biological studies of alkylating agents.

일반 설명Mustard gas is a clear amber colored oily liquid with a faint odor of mustard/garlic. Mustard gas is not readily combustible. Its vapors are heavier than air, are very toxic, and can be absorbed through the skin. The effects from exposure to the material include blindness which may be delayed. Prolonged exposure of the container to fire or intense heat may cause Mustard gas to violently rupture and rocket. Mustard gas is also known as dichlorodiethyl sulfide.

상·하류 제품 정보

상류 원료

2,2'-티오디에틸디아세테이트cyanoformyl chloride비스(2-클로로에테르)트리술파이드Carbonocyanidic fluoride비스(2-클로로에틸)이황화물아세틸 염화물에틸렌

하류 제품

2-클로로에틸황화비닐에테닐술파닐에텐2-클로로에탄티올1,1,1,2-테트라클로로에탄

추가 설명

정의ChEBI: An ethyl sulfide that is diethyl sulfide in which a hydrogen from each of the terminal methyl groups is replaced by a chlorine. It is a powerful vesicant regulated under the Chemical Weapons Convention.

관련 반응

2건
반응 기록 만들기
HRID 1085127 반응식
HRID 1085127반응물로uspto-grants-1991_04
HRID 1480985 반응식
HRID 1480985반응물로uspto-grants-2016_08

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