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HCID 10478생성일: 2026년 10월 27일

시아노겐 요오드화물

사이아노겐아이오다이드 · 시아노겐요오드화물 · 사이아노겐 아이오다이드 · CNI · ICN · cN1A · cN-IA · NT5C1A

https://huagongshe.com/ko/chemical/10478

시아노겐 요오드화물 분자 구조식

식별자 및 물리적 특성

CAS No.506-78-5
분자식CIN
평균 분자량152.922 g/mol
단동위원소 질량152.907547 g/mol
SMILESN#CI
InChIKeyWPBXOELOQKLBDF-UHFFFAOYSA-N
PubChem CID10478
EC No.208-053-3
DTXSIDDTXSID50870573
현지명시아노겐 요오드화물

화학 및 물리적 성질

XLogP0.9
극성 표면적23.8
수소 결합 공여자 수0
수소 결합 수용자 수1
회전 가능 결합 수0
무거운 원자 수3
형식 전하0
복잡도31.3
물질 분류Toxic Gases & Vapors -> Cyanides
SpringerMaterials PropertiesDunham energy parameter
냄새Very pungent odor
맛Acrid taste
밀도2.84 (EPA, 1998) - Denser than waterwill sink2.84 g/cu cm at 18 °C2.84 g/cm³2.84 @25 °C1.840
Color/FormWhite needlesNeedles from alcohol and ethyl ether
용해도Very soluble in ethyl ether, ethanolSoluble in ethanol, ether, and volatile oilsIn water, 3.56X10+4 mg/L at 25 °CSolubility in water: slow reactionsoluble in H2O, ethanol, ethyl ether
끓는 점Sublimation at temperatures > 45 °C154.34°C (rough estimate)
녹는점295.7 °F (EPA, 1998)146.7 °C146-147 °C146.5 °C146 °C
증기 밀도Relative vapor density (air = 1): 1.54
증기압1 mmHg at 77.36 °F (EPA, 1998)1.0 [mmHg]1 mm Hg at 25.2 °CVapor pressure, Pa at 25.2 °C: 1301 [mm Hg] @25.2 °C
Heat of Vaporization40.02 kJ/mol
저장 조건Refrigerator (+4°C)
물리적 상태결정성 분말
색상베이지부터 연한 갈색 또는 연한 핑크까지
생물학적 소스rabbit
용해도H2O, EtOH, eth [CRC10]에 용해됨
비열Cp(gas): 0.32 J/(g·K), at 25℃
EPACyanogen iodide (506-78-5)

화학적 성질

Iodine cyanide (cyanogen iodide) appears as light pink crystalline or brown-coloured powder and is soluble in water. It is stable but sensitive to light. It is incompatible with strong acids, strong bases, and strong oxidising agents. Cyanogen iodide decomposes on contact with acids, bases, and ammonia alcohols and on heating producing toxic gases including hydrogen cyanide. It reacts with carbon dioxide or slowly with water to produce hydrogen cyanide.

안전 및 규제

GHS 분류DangerH301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]P261, P262, P264, P264+P265, P270, P271, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P316, P319, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.
운송 라벨(DOT)Poison Corrosive
화재 위험When heated to decomposition, it emits very toxic fumes of nitrogen oxides, cyanide, and iodide. Avoid phosphorus. (EPA, 1998)Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
화재 가능성Combustible solid
건강 유해성Causes convulsions, paralysis and death from respiratory failure. Highly toxicstrong irritant to eyes and skin. (Non-Specific -- Cyanide or Cyanide Mixture, Dry): Poisonous, may be fatal if swallowed or absorbed through skin. Contact may cause burns to the skin and eyes. Fire may produce irritating or poisonous gases. (EPA, 1998)
유해성 요약Decomposes on contact with acids, bases, or heat producing hydrogen cyanideReacts with carbon dioxide or slowly with water to produce hydrogen cyanide[ICSC] A lachrymatorExpected to be corrosive based on its similarity to cyanogen bromideCan cause pulmonary edema after a severe inhalation exposureCyanide poisoning is possible if trapped in a contaminated environment[CHEMINFO] See Hydrogen cyanide.
반응성 그룹Cyanides, Inorganic
EC 분류Symbol: T+, NR: 26/27/28-32-50/53S: (1/2)-7-28-29-45-60-61Note: A
UN 분류UN Hazard Class: 6.1UN Pack Group: I
RCRA 요건D003A solid waste containing cyanogen iodide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.

용도

용도

Generally for destroying all lower forms of life. In taxidermy for preserving insects, butterflies, etc.

일반 설명

White needles with a very pungent odor. Used in taxidermists' preservatives and generally for destroying all lower forms of life. Toxic by inhalation or ingestion.

OSHA StandardsPermissible Exposure Limit: Table Z-1 8-hr Time-Weighted Avg: 5 mg/cu m. Skin Designation. /Cyanides, as CN/
Reactivity ProfilePhosphorus(molten) plus CYANOGEN IODIDE reacts with incandescence to produce phosphorus iodide, [NFPA 491M, 1991]. Benzene and cyanogen halides yield HCl as a byproduct (Hagedorn, F. H. Gelbke, and Federal Republic of Germany. 2002. Nitriles. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA.).
Chemical DangersDecomposes on contact with acids, bases, ammonia or alcohols. This produces toxic gases including hydrogen cyanide. Decomposes on heating. This produces toxic gases including hydrogen cyanide. Reacts with carbon dioxide. This produces hydrogen cyanide. Reacts slowly with water. This produces hydrogen cyanide.
소화(Non-Specific -- Cyanide or Cyanide Mixture, Dry) Keep unnecessary people awayisolate hazard area and deny entry. Stay upwindkeep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and special protective clothing. Remove and isolate contaminated clothing at the site.In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.
응급 조치Fresh air, rest. Artificial respiration may be needed. No mouth-to-mouth artificial respiration. Administration of oxygen may be needed. Refer for medical attention.Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Wear protective gloves when inducing vomiting. Give a slurry of activated charcoal in water to drink. NO mouth-to-mouth artificial respiration. Administration of oxygen may be needed. Refer for medical attention .
응급 처치Warning: Effects, including skin reactions, may be delayed. Caution is advised. Vital signs should be monitored closely. Heart palpitation may begin within minutes after exposure.
안전 보관Separated from incompatible materials and food and feedstuffs. Dry. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access.
노출 관리 및 개인 보호2.0 [mg/m3], as CN, inhalable fraction[German Research Foundation (DFG)]
소화 절차Small fires: dry chemical, carbon dioxide, water spray, or foam. Large fires: water spray, fog, or foam. Move container from fire area if you can do so without risk. Fight fire from maximum distance. Dike fire control water for later disposaldo not scatter the material. Keep unnecessary people awayisolate hazard area and deny entry. Stay upwindkeep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and special protective clothing. Remove and isolate contaminated clothing at the site. Poisonous gases are produced in fire including cyanide gas, iodide gas and nitrogen oxides. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated water. Notify local health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors, or shows any signs of deforming), withdraw immediately to a secure position.
보관 조건Separated from incompatible materials, food and feedstuffs. Dry. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access.Store in tightly closed containers in a cool, well ventilated area. Metal containers involving the transfer of this chemical should be grounded and bonded. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition such as smoking and open flames, are prohibited where this chemical is used, handled or stored in a manner that could create a potential fire or explosion hazard.
정리 방법Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment.Wear nitrile rubber gloves, eye protection, laboratory coat and self-contained breathing apparatus if necessary. Cover spill with a 1:1:1 mixture by weight of sodium carbonate or calcium carbonate, clay cat litter (bentonite) and sand. Scoop into a container and transport to the fume hood. Add to a pail of water. Cautiously, and with stirring, add to an alkaline solution of calcium hypochlorite or household bleach. After 24 hours, decant solution to the drain with 50 times its volume of water. Discard the solid residue with normal refuse.
비화재 누출 대응(Non-Specific -- Cyanide or Cyanide Mixture, Dry) Do not touch spilled materialstop leak if you can do so without risk. Use water spray to reduce vapors.
처리 방법Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D003, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.Wear nitrile rubber gloves, laboratory coat and eye protection. In the fume hood, add slowly and cautiously, with stirring, to a large volume of alkaline calcium hypochlorite solution or household bleach. After 24 hours, flush down the drain with 50 times its volume of water.SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
누출 처리Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Sweep spilled substance into covered sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment.
Preventive MeasuresSRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.SRP: Local exhaust ventilation should be applied wherever there is an incidence of point source emissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants.PREVENT DISPERSION OF DUST! STRICT HYGIENE! Use local exhaust or breathing protection. Wear protective gloves, protective clothing. Wear safety goggles, face shield or eye protection in combination with breathing protection. Do not eat, drink, or smoke during work. Wash hands before eating.
TreatmentAntidotes to cyanide poisoning include hydroxocobalamin and sodium nitrite, which release the cyanide from the cytochrome system, and rhodanase, which is an enzyme occurring naturally in mammals that combines serum cyanide with thiosulfate, producing comparatively harmless thiocyanate. Oxygen therapy can also be administered. (L97)
건강 영향Exposure to high levels of cyanide for a short time harms the brain and heart and can even cause coma, seizures, apnea, cardiac arrest and death. Chronic inhalation of cyanide causes breathing difficulties, chest pain, vomiting, blood changes, headaches, and enlargement of the thyroid gland. Skin contact with cyanide salts can irritate and produce sores. (L96, L97)
유해 작용Other Poison - Chemical Asphyxiant
노출 경로The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.Inhalation (L96)oral (L96)dermal (L96)
독성 요약Organic nitriles decompose into cyanide ions both in vivo and in vitro. Consequently the primary mechanism of toxicity for organic nitriles is their production of toxic cyanide ions or hydrogen cyanide. Cyanide is an inhibitor of cytochrome c oxidase in the fourth complex of the electron transport chain (found in the membrane of the mitochondria of eukaryotic cells). It complexes with the ferric iron atom in this enzyme. The binding of cyanide to this cytochrome prevents transport of electrons from cytochrome c oxidase to oxygen. As a result, the electron transport chain is disrupted and the cell can no longer aerobically produce ATP for energy. Tissues that mainly depend on aerobic respiration, such as the central nervous system and the heart, are particularly affected. Cyanide is also known produce some of its toxic effects by binding to catalase, glutathione peroxidase, methemoglobin, hydroxocobalamin, phosphatase, tyrosinase, ascorbic acid oxidase, xanthine oxidase, succinic dehydrogenase, and Cu/Zn superoxide dismutase. Cyanide binds to the ferric ion of methemoglobin to form inactive cyanmethemoglobin. (L97)
Signs and SymptomsSore throat. Headache. Confusion. Weakness. Shortness of breath. Convulsions. Unconsciousness.MAY BE ABSORBED! Redness. Pain. See Inhalation.Burning sensation. Nausea. Vomiting. Diarrhoea. See Inhalation.Cyanide poisoning is identified by rapid, deep breathing and shortness of breath, general weakness, giddiness, headaches, vertigo, confusion, convulsions/seizures and eventually loss of consciousness. (L96, L97)
ICSC Environmental DataThe substance is very toxic to aquatic organisms.
Medical SurveillanceLaboratory Findings. 1. An elevated blood cyanide concentration. Mild effects may be apparent at concentrations of 0.5-1.0 ug/mL, and concentrations of 2.5 ug/mL and higher are associated with coma, convulsions and death. 2. Acidosis. Metabolic acidosis with a high concentration of lactic acid (lactic acidosis) or a metabolic acidosis with an unexplained high anion gap (if the means to measure lactic acid are not available) may be present. Because oxygen cannot be utilized, anaerobic metabolism with the production of lactic acid replaces aerobic metabolism. Lactic acidosis, however, may reflect other disease states and is not specific for cyanide poisoning. 3. Oxygen content of venous blood greater than normal. This also is a result of poisoning of the intramitochondrial respiratory chain and the resulting failure of cells to extract oxygen from arterial blood. This finding is also not specific for cyanide poisoning. /Hydrogen cyanide and cyanogen chloride/
Human Toxicity Excerpts/SIGNS AND SYMPTOMS/ Inhalation: Sore throat. Headache. Confusion. Weakness. Shortness of breath. Convulsions. Unconsciousness. Skin: MAY BE ABSORBED! Redness. Pain. Eyes: Redness. Pain. EFFECTS OF SHORT-TERM EXPOSURE: The substance is severely irritating to the eyes the skin and the respiratory tract. The substance may cause effects on the cellular respiration, resulting in convulsions and unconsciousness. Exposure may result in death. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the thyroid./SIGNS AND SYMPTOMS/ Strong irritant to eyes and skin./SIGNS AND SYMPTOMS/ 100 mg/cu m /of cyanogen iodide/ causes immediate irritation of the respiratory passages and smarting of the eyes, with severe blepharospasm and lacrimation. Chronic exposure causes hoarseness, conjunctivitis, and edema of the lids./SIGNS AND SYMPTOMS/ Caution: Causes convulsions, paralysis, death from respiratory failure.
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Antidote and Emergency TreatmentImmediate first aid: Remove patient from contact with the material. Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Cyanide and related compounds/Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Administer amyl nitrite ampules as per protocol and physician order ... . Monitor for shock and treat if necessary ... . Monitor for pulmonary edema and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . /Cyanide and related compounds/Advanced treatment: Consider Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Administer cyanide antidote kit as per protocol and physician order ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Cyanide and related compounds/Cyanokit is indicated for the treatment of known or suspected cyanide poisoning. ... If clinical suspicion of cyanide poisoning is high, Cyanokit should be administered without delay.... Cyanokit (hydroxocobalamin for injection) 5 g is a cyanide antidote package which contains two colorless 250 mL glass vials, each of which contains 2.5 g dark red lyophilized hydroxocobalamin, pH adjusted with hydrochloric acid, two transfer spikes, one IV administration set, one quick use reference guide and one package insert. The action of Cyanokit in the treatment of cyanide poisoning is based on its ability to bind cyanide ions. ...Caution should be exercised when administering other cyanide antidotes simultaneously with Cyanokit, as the safety of co-administration has not been established. If a decision is made to administer another cyanide antidote with Cyanokit, these drugs should not be administered concurrently in the same IV line. /Cyanide/In cases of respiratory compromise secure airway and respiration via endotracheal intubation. If not possible, perform cricothyroidotomy if equipped and trained to do so. Patients who are in shock or have seizures should be treated according to advanced life support (ALS) protocols. These patients or those who have arrhythmias may be seriously acidoticconsider giving, under medical supervision, each patient 1 mEq/kg intravenous sodium bicarbonate. ... When possible, treatment with cyanide antidotes should be given under medical supervision to unconscious victims who have known or strongly suspected cyanide poisoning. Cyanide antidotes - amyl nitrite perles and iv infusions of sodium nitrite and sodium thiosulfate - are packaged in the cyanide antidote kit. Amyl nitrite perles should be broken onto a gauze pad and held under the nose, over the Ambu-valve intake, or placed under the lip of the face mask.... . If the patient has not responded to oxygen and amyl nitrite treatment, infuse sodium nitrite iv as soon as possible. ... Monitor blood pressure ... . Next, infuse sodium thiosulfate iv. .../Hydrogen cyanide/
CERCLA 보고 수량Releases of CERCLA hazardous substances are subject to the release reporting requirement of CERCLA section 103, codified at 40 CFR part 302, in addition to the requirements of 40 CFR part 355. Cyanogen iodide is an extremely hazardous substance (EHS) subject to reporting requirements when stored in amounts in excess of its threshold planning quantity (TPQ) of 1,000 or 10,000 lbs. Extremely hazardous substances that are solids are subject to either of two threshold planning quantities ... The lower quantity applies only if the solid exists in powdered form and has a particle size less than 100 micronsor is handled in solution or in molten formor meets the criteria for a National Fire Protection Association (NFPA) rating of 2, 3 or 4 for reactivity. If the solid does not meet any of these criteria, it is subject to the upper ... threshold planning quantity ... .
청정수법 요건Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Cyanides/
수질 위해 등급(WGK)WGK 1
TSCA 등재 상태TSCA listed
운송 번호(UN)3290
관세 코드28530090
포장분류I
위험 등급6.1(a)
기존화학 물질KE-09065
저장 분류10 - Combustible liquids
유해 물질 데이터506-78-5(Hazardous Substances Data)