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아세틸 이오다이드

Acetyl iodide

HCID 10483
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
507-02-8
표준 SMILES
CC(=O)I
InChIKey
LEKJTGQWLAUGQA-UHFFFAOYSA-N
분자식
C2H3IO
평균 분자량
169.95 g/mol
단동위원소 질량
169.92286

개요

Acetyl iodide appears as a colorless, fuming liquid with a pungent odor. Soluble in benzene and ether (Merck 11th ed., 1989). Vapors are irritating to the eyes and mucous membranes. Vapor causes pulmonary edema. Corrosive to metals and skin.

이름 및 식별자

우선 이름
Acetyl iodide
IUPAC
acetyl iodide
현지명
아세틸 이오다이드
영어명
ACETYL IODIDE
분자식
C2H3IO
분자량
169.95

이름 및 동의어

ACETYL IODIDE507-02-8UNII-JAL3KV9I1OJAL3KV9I1OUN1898EINECS 208-062-2ACETYL IODIDE [MI]UN 1898DTXSID0060141UN-1898RefChem:109060DTXCID4040894
이름 더 보기
아세틸이오다이드아세틸요오드화물Acetyl iodidieEthanoyl iodideAcetyliodide95+%Acetyl Iodide >Acetic acid iodide
208-062-2InChI=1/C2H3IO/c1-2(3)4/h1HLEKJTGQWLAUGQA-UHFFFAOYSA-NMFCD00039399C2H3IOSCHEMBL35384SCHEMBL1726770AKOS009031394

데이터베이스 식별자

CAS
507-02-8
PubChem CID
10483
DTXSID
DTXSID0060141
UNII
JAL3KV9I1O
EC Number
208-062-2
Nikkaji
J2.612C

물성

구조 계산 물성

XLogP
0.8
극성 표면적
17.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
4
형식 전하
0
복잡도
33

실험 및 물리화학적 성질

Chemical Classes · 2건

Toxic Gases & Vapors -> Acid Halides

Corrosives

SpringerMaterials PropertiesSchoenflies notation
Vapor Pressure32.4 [mmHg]
Physical Description · 2건

Acetyl iodide appears as a colorless, fuming liquid with a pungent odor. Soluble in benzene and ether (Merck 11th ed., 1989). Vapors are irritating to the eyes and mucous membranes. Vapor causes pulmonary edema. Corrosive to metals and skin.

Colorless, fuming liquid with a pungent odor that turns brown on contact with air; [CAMEO]

물리화학적 성질

끓는 점
108 °C · 108°C
밀도
420 · d420 2.0674
굴절률
20 · nD20 1.5491
물리적 상태
clear liquid to cloudy liquid
색상
Red to Dark red to Brown
Merck
14 · 14,94
LogP
0.892 · 0.892 (est)
EPA
Acetyl iodide (507-02-8)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P234, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P390, P403+P235, P405, P406, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

유해성 정보

Hazards IdentificationWater-reactive material (WR)
Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelCorrosive
Fire Hazards · 2건

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· Combustible material: may burn but does not ignite readily.

Health Hazards · 2건

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards SummaryReacts with moisture to form hydrogen iodide (hydroiodic acid); Vapors are irritating; Liquid is corrosive to skin; Inhalation can cause pulmonary edema; [CAMEO] See Iodine for the TLV of Iodides.
DOT ID and Guide1898 156

화학 및 산업

용도 및 제조

Uses · 2건

Used as a chemical intermediate; [NJ-HSFS]

Toxic Gas from Spilling Chemical in Water [Category: Other]

General Manufacturing InformationAcetyl iodide: ACTIVE
응용 분야 · 2건

개요Acetyl iodide is a colourless, fuming liquid with a pungent odour. It is soluble in benzene and ether. Acetyl iodide is toxic, corrosive, and reacts with water or steam to produce toxic and corrosive fumes. The vapours of acetyl iodide are irritating to the eyes and mucous membranes. Vapour causes pulmonary oedema. It is corrosive to metals and skin. Acetyl iodide turns brown on exposure to air as it reacts exothermically with moisture in the air to give hydrogen iodide (hydroiodic acid), a strong irritant. It decomposes in water to give acidic products. Inhalation, ingestion, or contact of the skin and the eyes with vapours, dusts, or substance may cause severe injury, burns, or death. Contact with molten form of acetyl iodide causes severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive, or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive, and/ or toxic gases. Run-off from fire control or dilution water may be corrosive and/or toxic and cause pollution.

일반 설명A colorless, fuming liquid with a pungent odor. Soluble in benzene and ether (Merck 11th ed., 1989). Vapors are irritating to the eyes and mucous membranes. Vapor causes pulmonary edema. Corrosive to metals and skin.

상·하류 제품 정보

하류 제품

아세틸콜린아이오다이드3,5-디마세타마이도-2,4,6-트리아이오도벤조익산

관련 반응

2건
반응 기록 만들기
HRID 255395 반응식
HRID 255395반응물로uspto-grants-1987_10
HRID 637883 반응식
HRID 637883반응물로uspto-grants-1985_12

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Reactive Group
Acyl Halides, Sulfonyl Halides, and Chloroformates
Reactivity AlertsWater-Reactive
Reactivity Profile · 1건

ACETYL IODIDE decomposes exothermically in water or alcohol. Reacts vigorously and exothermically with bases. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

DOT Hazard Classification · 4건

Acetyl iodide

UN1898

Class 8 Corrosive material (49 eCFR § 173.136)

PG II: the degree of danger presented by the material is medium

Air and Water ReactionsFumes in air. Turns brown on exposure to air as it reacts exothermically with moisture in the air to give hydrogen Iodide (hydroiodic acid), a strong irritant. Decomposes in water to give acidic products.

안전 및 보호

Fire FightingExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

General First Aid:

Exposure Control and Personal Protection · 2건

· Wear positive pressure self-contained breathing apparatus (SCBA).

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Isolation and Evacuation · 4건

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Immediate precautionary measure

When spilled in water

When spilled in water

Toxic-by-Inhalation (TIH) GasHI - when spill Acetyl iodide into water.
Personal Protective Equipment (PPE)Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Emergency Response Planning Guidelines· Note: Most foams will react with the material and release corrosive/toxic gases.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

규제 정보

DHS Chemicals of Interest (COI) · 4건

Acetyl iodine

A Commercial Grade

A Placarded Amount

Chemical or material that can be mixed with readily available materials.

안전 데이터

tsca
TSCA listed
ridadr
UN 1898
HS 번호
2914790090
risk_code
34
safety_code
26-36/37/39
포장분류
II
위험 등급
8
S-n-Propyl thioacetate
N,N-DI-N-부틸아세트아미드

공급사34 곳

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