기본 정보
- 표준 SMILES
OP(O)O- InChIKey
OJMIONKXNSYLSR-UHFFFAOYSA-N- 분자식
- H3O3P
- 평균 분자량
- 81.996 g/mol
- 단동위원소 질량
- 81.98198059
개요
Phosphorous acid is a phosphorus oxoacid. It is a conjugate acid of a dihydrogenphosphite. It is a tautomer of a phosphonic acid.
이름 및 식별자
- 우선 이름
- Phosphorous acid
- IUPAC
- phosphorous acid
- 현지명
- 포스포로우수 산
- 영어명
- Orthophosphorus acid
- 분자식
- H3O3P
- 분자량
- 82
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
10294-56-1、14901-63-4- PubChem CID
- 107909
- DTXSID
DTXSID7035511- ChEBI
CHEBI:36361- EC Number
- 233-663-1
- Nikkaji
- J95.182J
물성
구조 계산 물성
- XLogP
- -1.5
- 극성 표면적
- 60.7 Ų
- 수소 결합 공여자 수
- 3
- 수소 결합 수용자 수
- 3
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 4
- 형식 전하
- 0
- 복잡도
- 8
실험 및 물리화학적 성질
Physical Description
Liquid
Solid
물리화학적 성질
- 산도 계수 (pKa)
- 2.22 · 2.22±0.10(Predicted)
- InChI
- InChI=1S/H3O3P/c1-4(2)3/h1-3H
- InChIKey
- OJMIONKXNSYLSR-UHFFFAOYSA-N
- SMILES
- P(O)(O)O
- NIST
- 3 PO3 · H3PO3(10294-56-1)
- EPA
- Phosphorous acid (10294-56-1)
안전 및 규제
GHS 분류
GHS Classification
Danger
H302: Harmful if swallowed [Warning Acute toxicity, oral]
P260, P264, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P363, P405, and P501 (click each P-code to see the statement)
This chemical does not meet GHS hazard criteria for 0.3% (2 of 719) of reports.
Danger
H302 (89.3%): Harmful if swallowed [Warning Acute toxicity, oral]
유해성 정보
Regulatory Information
Chemical: Phosphorous acid
Phosphorous acid is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphorous acid are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Phosphorous acid: Does not have an individual approval but may be used under an appropriate group standard
DOT Hazard Classification
Phosphorous acid
UN2834
Class 8 Corrosive material (49 eCFR § 173.136)
PG III: the degree of danger presented by the material is minor
Hazard Classes and Categories
Acute Tox. 4 (89.3%)
Acute toxicity - category 4
Self-reactive substances and mixtures - Type G
Acute Tox. 4 *
안전 및 보호
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
Protective Action Criteria (PAC)
3.0 [mg/m3]
30 [mg/m3]
150 [mg/m3]
안전 데이터
- tsca
- TSCA listed
- ridadr
- UN 2834
- risk_code
- 22-35
- hazard_code
- Xn,C
- safety_code
- 1/2-26-36/37/39-45
- 포장분류
- III
- 위험 등급
- 8
- 기존화학 물질
- KE-28696
화학 및 산업
용도 및 제조
Use Classification
EPA Safer Chemical Functional Use Classes -> Oxidants and Oxidant Stabilizers
Safer Chemical Classes -> Yellow triangle - The chemical has met Safer Choice Criteria for its functional ingredient-class, but has some hazard profile issues
General Manufacturing Information
Not Known or Reasonably Ascertainable
Phosphorous acid: ACTIVE
응용 분야
용도Phosphorous acid is a reducer in chemical reactions and a raw material in the making of phosphorous acid salts. A plant defoliant.
상·하류 제품 정보
상류 원료
하류 제품
공급사50 곳
추가 설명
정의A white crystalline solid. It is a monobasic acid forming the anion H2PO2- in water. The sodium salt, and hence the acid, can be prepared by heating yellow phosphorus with sodium hydroxide solution. The free acid and its salts are powerful reducing agents.
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