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중크롬산나트륨

Sodium dichromate dihydrate

HCID 108005
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인쇄 미리보기
기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
7789-12-0
표준 SMILES
O.O.[Na+].[Na+].[O]=[Cr](=[O])([O-])[O][Cr](=[O])(=[O])[O-]
InChIKey
JYDRNIYTFCBIFC-UHFFFAOYSA-N
분자식
Cr2H4Na2O9
평균 분자량
298 g/mol
단동위원소 질량
297.84608

이름 및 식별자

우선 이름
Sodium dichromate dihydrate
IUPAC
disodium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium;dihydrate
현지명
중크롬산나트륨
영어명
Sodium dichromate dihydrate
분자식
Cr2H5NaO8
분자량
260.01

이름 및 동의어

Sodium dichromate dihydrate7789-12-0Disodium dichromate dihydrateChromic acid (H2Cr2O7), disodium salt, dihydrateDTXSID603206152125XYY2ADICHROMIC ACID (H2Cr2O7), DISODIUM SALT, DIHYDRATEDTXCID4012061RefChem:1098784CCRIS 6344UNII-52125XYY2Adisodium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium;dihydrate
이름 더 보기
나트륨비크롬산결정소디움디클로로메이트2H2O이크롬산나트륨나트륨디크롬산이수화물디나트륨디크롬산이수화물중크롬산나트륨(2수화물)중크롬산나트륨나트륨디크롬산이수화물소듐다이크로메이트,다이하이드레이트나트륨 이크로뮴산염, 이수화물디크롬산나트륨수화물SODIUM DICHROMATESODIUM BICHROMATESODIUM DICHROMATE GRSodium dichromate diSodium Dichromate ARSODIUM DICHROMATE 2H2OSODIUM DICHROMATE, ACSSodiumbichromateanhydrousSODIUM DICHROMATE, HYDROUSSODIUM DICHROMATE 2HYD XTL
sodium dichromate (VI) dihydrateSodium dichromate dihydrate (VI)NCGC00091922-02SODIUM CHROMATE (NA2CR2O7) DIHYDRATEEC 234-190-3DICHROMIC ACID, DISODIUM SALT, DIHYDRATESODIUM DICHROMATE DIHYDRATE (NA2CR2O7.2H2O)Sodium mu-oxidohexakis(oxido)dichromate(2-)--water (2/1/2)

데이터베이스 식별자

CAS
7789-12-0
PubChem CID
108005
DTXSID
DTXSID6032061
UNII
52125XYY2A
EC Number
616-541-6

물성

구조 계산 물성

극성 표면적
126 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
9
회전 가능 결합 수
0
무거운 원자 수
13
형식 전하
0
복잡도
194

실험 및 물리화학적 성질

Chemical ClassesMetals -> Chromium Compounds, Inorganic
Density2.35 @ 13°C
Physical DescriptionReddish to bright orange solid; Somewhat deliquescent and soluble in water; [Merck Index] Orange-red odorless crystals; Hygroscopic and soluble in water; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
91 °C · 91 °C(lit.)
끓는 점
400 °C · 400°C
밀도
2 · 2,348 g/cm3
증기 밀도
10 · 10 (vs air)
저장 조건
5 °C · Store at +5°C to +30°C.
용해도
메탄올(약간 용해됨,초음파 처리)
물리적 상태
고체
Specific Gravity
2.348 · 2.348
색상
붉은 오렌지색
냄새
냄새 없는
수소이온지수(pH)
3.5 · 3.5 (20°C, 100g/L)
수용성
730 g/L · 730g/L(20℃)
Merck
14 · 14,8609
Dielectric constant

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P261, P272, P273, P280, P302+P352, P318, P321, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2101 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

유해성 정보

Regulatory Information · 2건

Chemical: Chromic acid (H2Cr2O7), disodium salt, dihydrate

Chromic acid, disodium salt, dihydrate: HSNO Approval: HSR001440 Approved with controls

Other Safety InformationIMAP assessments - Chromates and dichromates (soluble): Human health tier II assessment
Hazards Summary · 1건

An oxidizer that may cause fire on contact with combustible materials; Causes burns; May cause skin and respiratory sensitization; Toxic by ingestion; Highly toxic by inhalation; Harmful by skin absorption; [Alfa Aesar MSDS] See Sodium dichromate. See Chromium and linked occupational diseases.

Hazard Classes and Categories · 3건

Skin Sens. 1 (100%)

Carcinogenicity - category 1A

Acute toxicity (Oral) - Category 3

안전 및 보호

Threshold Limit Values (TLV) · 2건

0.0001 [mg/m3], as Cr(VI), inhalable particulate matter

0.0005 [mg/m3], as Cr(VI), inhalable particulate matter

화학 및 산업

용도 및 제조

Uses · 2건

Used as an oxidizing agent (to make dyes, inks, and other chemicals), bleaching agent (fats, oils, sponges, and resins), tanning agent, and mordant in dyeing; Also used in electric batteries, for refining petroleum, electro-engraving copper, in corrosion inhibitors and corrosion inhibiting paints, metal treatments, hardening gelatin, defoliation of cotton and other plants and shrubs, and as a topical anti-infective; [Merck Index] Used for metal finishing (chrome plating, electroplating, passivating, anodizing, and brightening), to make vitamin K, colored glass, ceramic glazes, essential oils, and perfumes; [ExPub: ECHA - Annex XV Dossier] Found as a contaminant in drinking water from industrial uses including electroplating, leather tanning, and textile manufacturing; [NTP]

Electroplating [Category: Plate]

응용 분야

용도Sodium Dichromate Dihydrate is used as a catalyst in the synthesis of Endoperoxide II. Strong oxidizing agent in organic synthesis. Used in metal finishing as an aid in corrosion resistance.

일반 설명Solid orange-yellow crystal or powder.

상·하류 제품 정보

상류 원료

HEAVY CUT RESIDUE OIL석회석황산 나트륨Chrome iron ore돌로마이트산화크로뮴수산화알루미늄분말황산탄산나트륨(경회)

관련 반응

44건
반응 기록 만들기
HRID 3170 반응식
HRID 3170반응물로uspto-grants-1998_03
HRID 36626 반응식
HRID 36626반응물로uspto-grants-1995_05
HRID 36632 반응식
HRID 36632반응물로uspto-grants-1995_05
HRID 53628 반응식
HRID 53628반응물로uspto-grants-1997_04
HRID 77390 반응식
HRID 77390반응물로uspto-grants-2014_09
HRID 126726 반응식
HRID 126726반응물로uspto-grants-1981_03
HRID 223289 반응식
HRID 223289반응물로uspto-grants-1982_10
HRID 255397 반응식
HRID 255397반응물로uspto-grants-1987_10
1 / 6 페이지

화합물 노트

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이 페이지에서기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
2.9 · 2.9(Ambient)
InChI
1S/2Cr.2Na.2H2O.7O/h;;;;2*1H2;;;;;;;/q;;2*+1;;;;;;;;2*-1
InChIKey
JYDRNIYTFCBIFC-UHFFFAOYSA-N
SMILES
O.O.[Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O
EPA
Disodium dichromate dihydrate (7789-12-0)

화학적 성질

Orange-yellow powder. Soluble in acids and hot water; insoluble in alcohol and ether.

Permissible Exposure Limit (PEL)
0.005 [mg/m3], as Cr(VI)
Protective Action Criteria (PAC) · 3건

0.017 [mg/m3]

0.62 [mg/m3]

3.7 [mg/m3]

독성 정보

Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Carcinogen Classification · 6건

Sodium Dichromate Dihydrate

TR-546: Toxicology and Carcinogenesis Studies of Sodium Dichromate Dihydrate (CASRN 7789-12-0) in F344/N Rats and B6C3F1 Mice (Drinking Water Studies) (2008 )

05/16/07

Clear Evidence

Clear Evidence

Clear Evidence

안전 데이터

wgk
3
tsca
Yes
rtecs
HX7750000
ridadr
UN 3086 6.1/PG 1
HS 번호
28413000
risk_code
45-46-60-61-8-21-25-26-34-42/43-48/23-50/53
hazard_code
O,T+,N
safety_code
53-45-60-61
포장분류
III
위험 등급
5.1
Hazard Classifications
Acute Tox. 2 InhalationAcute Tox. 3 OralAcute Tox. 4 DermalAquatic Acute 1Aquatic Chronic 1Carc. 1BEye Dam. 1Muta. 1BOx. Sol. 2Repr. 1BResp. Sens. 1Skin Corr. 1BSkin Sens. 1STOT RE 1 Inhalation
스토리지 클래스
5.1B - Oxidizing hazardous materials
함량 및 규제정보
물질구분: 제한물질; 혼합물(제품)함량정보: 크로뮴(6+)화합물 및 이를 0.1% 이상 함유한 혼합물
유해화학물질 필터링
99-1-506;06-5-10
중점관리물질 필터링
별표1-139
백운석(CaMg(CO3)2),연소내화물

하류 제품

Acid blue 151-(2,6-디메틸페녹시)아세톤트리메틸퀴논크롬산 납Dehydrocholic acid4-아미노-1,8-나프탈이미드크롬산 스트론슘C.I. 산 바이올렛 17, 나트륨 염6-Carboxy-2,4-dihydroxypyrimidine monosodium salt메틸렌블루hydrogen [4-[[4-(diethylamino)phenyl][4-[ethyl[(3-sulphonatobenzyl)amino]-o-tolyl]methylene]-3-methylcyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium saltferric chomium lignin sulfonate피레녹신크롬 염화물, 6수화물1,2,4-TrimethoxybenzeneChroMiuM(III) sulfate hydrate메나디온Pale chrome yellowLemon chrome yellow 501(2,6-DIMETHYLPHENOXY)아세톡심water-proofing agnet ACsulfomethylated gallnuat sodium tannic acid페난트렌퀴논AcenaphthenequinoneMethyl 4-aminopyridine-3-carboxylate9-플루오레논-2-카르복실 산히드록시 황산 크롬103 chrome yellow크롬산 나트륨, 테트라수화물Potassium orotateLITHIUM DICHROMATE크롬산 나트륨4,5-디클로로나프탈렌-1,8-디카르복실산무수물4-니트로-1,8-나프탈렌디카르복실산Basic chromic sulfate황연프로베네시드acidizig fluid gelling agent CT^{1~6^}패스트그린FCF다이크로뮴산 암모늄
추가 설명 · 1건

정의A red crystallinesolid, Na2Cr2O7.2H2O, solublein water and insoluble in ethanol. Itis usually known as the dihydrate(r.d. 2.52), which starts to lose waterabove 100°C; the compound decomposesabove 400°C. It is made bymelting chrome iron ore with limeand soda ash and acidification of thechromate thus formed. Sodiumdichromate is cheaper than the correspondingpotassium compound buthas the disadvantage of being hygroscopic.It is used as a mordant in dyeing,as an oxidizing agent in organicchemistry, and in analytical chemistry.