(디메틸 아미노메틸렌 아미노메틸렌) 디메틸염화암모늄

Gold's Reagent

HCID 11008255

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 20353-93-9
표준 SMILES: CN(C)C=NC=[N+](C)C.[Cl-]
InChIKey: DEIBXAPEZDJDRC-UHFFFAOYSA-M
분자식: C6H14ClN3
평균 분자량: 163.65 g/mol
단동위원소 질량: 163.08762513

이름 및 식별자

우선 이름: Gold's Reagent
IUPAC: (dimethylaminomethylideneamino)methylidene-dimethylazanium chloride
현지명: (디메틸 아미노메틸렌 아미노메틸렌) 디메틸염화암모늄
영어명: (DIMETHYLAMINOMETHYLENE-AMINOMETHYLENE)DIMETHYLAMMONIUM CHLORIDE
분자식: C6H14ClN3
분자량: 163.65

이름 및 동의어

Gold's ReagentRefChem:782603627-641-420353-93-9({[(dimethylamino)methylidene]amino}methylidene)dimethylazanium chloride[3-(Dimethylamino)-2-azaprop-2-en-1-ylidene]dimethylammonium chlorideN-((((Dimethylamino)methylene)amino)methylene)-N-methylmethanaminium chlorideMFCD00011793bis(dimethylaminomethylidene)azanium;chloride(dimethylaminomethylene-aminomethylene)dimethylammonium chloride(Dimethylaminomethyleneaminomethylene)dimethylammonium chloride(([(Dimethylamino)methylidene]amino)methylidene)dimethylazanium chloride

이름 더 보기

(디메틸아미노메틸렌아미노메틸렌)디메틸염화암모늄황금의 시약(디메틸아미노메틸렌-아미노메틸렌)디메틸암모늄클로라이드Gold'sReagent>Gold's Reagent 95%Gold′s Reagent, CAS 20353-93-9

ST51038132[[[(Dimethylamino)methylene]amino]methylene]dimethylammonium Chloridegold'SGold inverted exclamation mark s ReagentGold's Reagent 95%SCHEMBL296458SCHEMBL296459SCHEMBL27861214

데이터베이스 식별자

CAS: 20353-93-9
PubChem CID: 11008255
DTXSID: DTXSID20451631
EC Number: 627-641-4

물성

구조 계산 물성

극성 표면적: 18.6 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 2
무거운 원자 수: 10
형식 전하: 0
복잡도: 106

물리화학적 성질

녹는점: 100 · 100-102 °C (lit.)
용해도: 메탄올에 용해됨
물리적 상태: powder to crystal
색상: Light orange to Yellow to Green
InChI: InChI=1S/C6H14N3.ClH/c1-8(2)5-7-6-9(3)4;/h5-6H,1-4H3;1H/q+1;/p-1
InChIKey: DEIBXAPEZDJDRC-UHFFFAOYSA-M
SMILES: N(C)(C)/C=N/C=[N+](/C)\C.[Cl-]

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

안전 데이터

wgk: 3
HS 번호: 2925.29.9000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야

용도Gold′s Reagent was used in the synthesis of 4-hydroxyquinazoline by reacting with ortho aminobenzoic acids.

용도[[[(Dimethylamino)methylene]amino]methylene]dimethylammonium Chloride is a β-dimethylaminomethylenating agent for ketones and amines; yields enamino derivatives of esters and lactones; converts Grignard reagents to aldehydes.