비스(메틸티오)(트리메틸실릴)메탄

Bis(methylthio)(trimethylsilyl)methane

HCID 11008541
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기본 정보

CAS
37891-79-5
표준 SMILES
CSC(SC)[Si](C)(C)C
InChIKey
QEPMPXAUMUWNNO-UHFFFAOYSA-N
분자식
C6H16S2Si
평균 분자량
180.4 g/mol
단동위원소 질량
180.04626904

이름 및 식별자

우선 이름
Bis(methylthio)(trimethylsilyl)methane
IUPAC
bis(methylsulfanyl)methyl-trimethylsilane
현지명
비스(메틸티오)(트리메틸실릴)메탄
영어명
Bis(methylthio)(trimethylsilyl)methane
분자식
C6H16S2Si
분자량
180.41

이름 및 동의어

Bis(methylthio)(trimethylsilyl)methane37891-79-5DTXSID30451662RefChem:329865DTXCID20402481678-055-0MFCD01631301[bis(methylsulfanyl)methyl]trimethylsilaneTrimethylbis(methylthio)methylsilanebis(methylsulfanyl)methyl-trimethylsilaneBis(methylthio)methyltrimethylsilaneBis(methylsulfanyl)methyl-trimethyl-silane
이름 더 보기
비스(메틸티오)(트리메틸실릴)메탄Silane, [bis(methylthio)methyl]trimethyl-Bis(methylthio)(trimethylsilyl)methane >Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane
C6H16S2SiSCHEMBL9665484Bis(methylthio)trimethylsilylmethaneTrimethylsilyl-bis(methylthio)methaneAKOS006229377bis(methylsulphanyl)trimethylsilylmethaneSY057884DB-264553

데이터베이스 식별자

CAS
37891-79-5
PubChem CID
11008541
DTXSID
DTXSID30451662
EC Number
678-055-0
Nikkaji
J1.255.324B

물성

구조 계산 물성

극성 표면적
50.6 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
3
무거운 원자 수
9

물리화학적 성질

끓는 점
82 °C · 82 °C(Press: 10.0 Torr)
밀도
0.941 · 0.941±0.06 g/cm3(Predicted)
굴절률
1.506 · 1.5060-1.5100
용해도
물에 불용성, 유기 용액에 용해됨
물리적 상태
투명한 액체
색상
Colorless to Light yellow to Light orange

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P264, P264+P265, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, and P362+P364 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

안전 데이터

HS 번호
2931.90.9010

화학 및 산업

응용 분야 · 1건

용도Bis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals from aldehydes and ketones;acyl anion synthon for conjugate additions to enones and enoates;useful for one-carbon homologations.The bis(methylthio)ketene acetals are useful synthetic intermediates because they are readily converted into S-methyl thioesters (eq 9) or the corresponding carboxylic acids and esters.

제조 방법

prepared from lithiobis(methylthio)- methane by silylation with chlorotrimethylsilane (eq 1).Both bis(methylthio)methane and chlorotrimethylsilane are commercially available.

공급사33 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

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