기본 정보
- 표준 SMILES
CC1CNCC(C)O1- InChIKey
HNVIQLPOGUDBSU-UHFFFAOYSA-N- 분자식
- C6H13NO
- 평균 분자량
- 115.17 g/mol
- 단동위원소 질량
- 115.09971404
개요
2,6-dimethyl morpholine is a clear liquid. (NTP, 1992)
이름 및 식별자
- 우선 이름
- 2,6-Dimethylmorpholine
- IUPAC
- 2,6-dimethylmorpholine
- 현지명
- 디메틸모르폴린
- 영어명
- Dimethylmorpholine
- 분자식
- C6H13NO
- 분자량
- 115.17
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
141-91-3- PubChem CID
- 110862
- DTXSID
DTXSID6022002- EC Number
- 205-509-3
- Nikkaji
- J34.694B
물성
구조 계산 물성
- XLogP
- 0.3
- 극성 표면적
- 21.3 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 8
- 형식 전하
- 0
- 복잡도
- 66.9
실험 및 물리화학적 성질
Density
0.9346 at 68 °F (NTP, 1992) - Less dense than water; will float
0.9346 @ 20 °C/20 °C
Solubility
greater than or equal to 0.1 mg/mL at 66 °F (NTP, 1992)
SOL IN ALL PROPORTIONS WITH WATER, ALCOHOL, BENZENE, PETROLEUM ETHER; SOL IN ACETONE
Flash Point
112 °F (NTP, 1992)
112 °F (44 °C) OC
Boiling Point
297 °F at 760 mmHg (NTP, 1992)
146.6 °C @ 760 MM HG
Melting Point
-121 °F (NTP, 1992)
FREEZING POINT: -85 °C
Physical Description
2,6-dimethyl morpholine is a clear liquid. (NTP, 1992)
Clear liquid; [CAMEO]
물리화학적 성질
- 녹는점
- 85 °C · −85 °C(lit.)
- 끓는 점
- 147 °C · 147 °C(lit.)
- 밀도
- 0.935 g/mL · 0.935 g/mL at 25 °C(lit.)
- 굴절률
- 20 · n20/D 1.446(lit.)
- 인화점
- 120 °F · 120 °F
- 용해도
- 클로로포름(소량으로 용해), 메탄올(약간 용해됨)
- 물리적 상태
- 기름
- 산도 계수 (pKa)
- 9.04 · 9.04±0.60(Predicted)
- 색상
- 무색
- 수용성
- 19 · 19&C에서 >=0.01g/100mL
- BRN
- 103036 · 103036
- 안정성
- 안정적인. 산화제, 강산과 호환되지 않습니다. 가연성.
- InChI
- 1S/C6H13NO/c1-5-3-7-4-6(2)8-5/h5-7H,3-4H2,1-2H3
- InChIKey
- HNVIQLPOGUDBSU-UHFFFAOYSA-N
- SMILES
- CC1CNCC(C)O1
- LogP
- -0.1 · -0.100 (est)
- NIST
- 2 · Morpholine, 2,6-dimethyl-(141-91-3)
- EPA
- 2 · 2,6-Dimethylmorpholine (141-91-3)
화학적 성질
colourless liquid
안전 및 규제
GHS 분류
GHS Classification
Danger
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P260, P262, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 213 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Chemical: Morpholine, 2,6-dimethyl-
Status: Active Update: 17-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/16356
Reactivity Profile
2,6-DIMETHYL MORPHOLINE reacts with oxidizing agents (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
NFPA Hazard Classification
2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.
2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air.
0 - Materials that in themselves are normally stable, even under fire conditions.
안전 및 보호
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
독성 정보
안전 데이터
- wgk
- 2
- tsca
- TSCA listed
- rtecs
- QE1750000
- ridadr
- UN 1992 3/PG 3
- HS 번호
- 29349990
- risk_code
- 10-21-41
- hazard_code
- Xn
- safety_code
- 16-26-36/37/39-45
- 포장분류
- III
- 위험 등급
- 3
- Hazard Classifications
- Acute Tox. 4 DermalAcute Tox. 4 OralFlam. Liq. 3Skin Corr. 1B
- 스토리지 클래스
- 3 - Flammable liquids
- 유해 물질 데이터
- 141-91-3(Hazardous Substances Data)
화학 및 산업
용도 및 제조
Uses
Used in corrosive inhibitors, stabilizers for chlorinated solvents, floor polishes, rubber additives, germicides, and textile finishing; [Hawley]
Using Disinfectants or Biocides [Category: Clean]
MFR OF CORROSION INHIBITORS; STABILIZER FOR CHLORINATED SOLVENTS; RUBLESS FLOOR POLISHES, RUBBER ACCELERATORS, GERMICIDES, TEXTILE FINISHING AGENTS, /PRC: FUNGICIDES/
응용 분야
용도cis-2,6-Dimethylmorpholine (DMMP) has been used in the preparation of microporous material composed of hybrid T2 and T3 supertetrahedral clusters.
일반 설명Clear liquid.
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