Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
알릴요오다이드
알릴아이오다아이드 · 3-요오드프로펜 · 알릴요오다이드 · 알릴이오다이드 · 알릴 아이오다아이드 · 요오드화합금 · 3-IODOPROPENE · 3-IODO-1-PROPENE
식별자 및 물리적 특성
| CAS No. | 556-56-9 |
|---|---|
| 분자식 | C3H5I |
| 평균 분자량 | 167.98 g/mol |
| 단동위원소 질량 | 167.94359816 g/mol |
| SMILES | C=CCI |
| InChIKey | HFEHLDPGIKPNKL-UHFFFAOYSA-N |
| PubChem CID | 11166 |
| EC No. | 209-130-4 |
| DTXSID | DTXSID5060302 |
| 현지명 | 알릴요오다이드 |
화학 및 물리적 성질
| XLogP | 2.1 |
|---|---|
| 극성 표면적 | 0 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 0 |
| 회전 가능 결합 수 | 1 |
| 무거운 원자 수 | 4 |
| 형식 전하 | 0 |
| 복잡도 | 17.2 |
| 물질 분류 | Other Classes -> Halogenated Aliphatics, UnsaturatedCorrosives |
| SpringerMaterials Properties | Schoenflies notation |
| Physical Description | Allyl iodide appears as a yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals.Yellowish liquid with a pungent unpleasant odorDarkened by light and air evolving iodine[Merck Index] Clear dark red liquid[Sigma-Aldrich MSDS] |
| 녹는점 | -99 °C |
| 끓는 점 | 102103°C |
| 밀도 | 1.837 g/mL at 25 °C(lit.) |
| 굴절률 | n20/D 1.554 |
| 인화점 | 65 °F |
| 저장 조건 | 2-8°C |
| 용해도 | 알코올: 혼화성(lit.) |
| 물리적 상태 | 액체 |
| 색상 | 투명한 노란색에서 주황색, 빨간색 또는 적갈색 |
| 용해도 | 알코올, 클로로포름, 에테르 및 디에틸 에테르에 용해됩니다. 물에 불용성. |
| Merck | 14,294 |
| BRN | 1697594 |
| 헨리 상수 | 3.8×10-3 mol/(m3Pa) at 25℃, Hilal et al. (2008) |
| 유전율 | 6.1(19℃) |
| InChI | 1S/C3H5I/c1-2-3-4/h2H,1,3H2 |
| InChIKey | HFEHLDPGIKPNKL-UHFFFAOYSA-N |
| SMILES | ICC=C |
| EPA | 1-Propene, 3-iodo- (556-56-9) |
화학적 성질
clear orange, red or red-brown liquid
안전 및 규제
| GHS 분류 | DangerH225: Highly Flammable liquid and vapor [Danger Flammable liquids]P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids] |
|---|---|
| 규제 정보 | Chemical: 1-Propene, 3-iodo-The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 운송 라벨(DOT) | Flammable Liquid Corrosive |
| 화재 위험 | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:· Flammable/combustible material. |
| 건강 유해성 | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:· May cause toxic effects if inhaled or ingested. |
| 유해성 요약 | Causes general anesthesia, cyanosis, and changes in the structure or function of salivary glands in oral lethal-dose studies of rats[RTECS] Corrosive and flammable[Merck Index] A strong skin, eye, and mucous membrane irritant[CAMEO] Causes burnsInhalation may cause corrosive injuries to upper respiratory tractHighly toxic by ingestionReadily absorbed through skin[Sigma-Aldrich MSDS] See Allyl bromide. See 2,3-Dichloro-1-propene. See Iodine for the TLV of Iodides. |
| 운송 번호 및 가이드(DOT) | 1723 132 |
| 반응성 그룹 | Halogenated Organic Compounds |
| Reactivity Alerts | Highly Flammable |
| Reactivity Profile | ALLYL IODIDE is moderately reactive. Incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. |
| DOT Hazard Classification | Allyl iodideUN1723Class 3 Flammable and combustible liquid (49 eCFR § 173.120)PG II: the degree of danger presented by the material is medium |
| Air and Water Reactions | Highly flammable. Darkens on exposure to light and air liberating Iodine [Merck 11th ed. 1989]. Insoluble in water. |
| Hazard Classes and Categories | Flam. Liq. 2 (100%)Flammable liquid - category 2Corrosives, Flammable agents - 3rd degree |
| 소화 | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: |
| 누출 비상 조치 | · CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. |
| 응급 처치 | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:General First Aid: |
| 노출 관리 및 개인 보호 | · Wear positive pressure self-contained breathing apparatus (SCBA). |
| 비화재 누출 대응 | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: |
| Isolation and Evacuation | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:Immediate precautionary measure |
| Personal Protective Equipment (PPE) | Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: |
| Emergency Response Planning Guidelines | · Some of these materials may react violently with water. |
| 유해 작용 | Dermatotoxin - Skin burns. |
| 수질 위해 등급(WGK) | 1 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | UD0450000 |
| 운송 번호(UN) | UN 1723 |
| 관세 코드 | 29033990 |
| 위험 문구(R) | 10-34-11 |
| 위험 표시 | C,T,F |
| 안전 문구(S) | 7-26-45-16 |
| 포장분류 | II |
| 위험 등급 | 3Acute Tox. 2 OralEye Dam. 1Flam. Liq. 2Skin Corr. 1B |
| F 고인화성물질 | 8-13 |
| 저장 분류 | 3 - Flammable liquids |
용도
용도
Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.
일반 설명
A yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Flash point is less than 75°F. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals.