기본 정보
- 표준 SMILES
O=C([O-])[O-].[Rb+].[Rb+]- InChIKey
WPFGFHJALYCVMO-UHFFFAOYSA-L- 분자식
- CO3Rb2
- 평균 분자량
- 230.944 g/mol
- 단동위원소 질량
- 229.80832334
이름 및 식별자
- 우선 이름
- Carbonic acid, rubidium salt (1:2)
- IUPAC
- bis(rubidium(1+));carbonate
- 현지명
- 루비듐 탄산염
- 영어명
- Rubidium carbonate
- 분자식
- CH3O3Rb
- 분자량
- 148.5
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
584-09-8- PubChem CID
- 11431
- DTXSID
DTXSID50889428- EC Number
- 209-530-9
- Nikkaji
- J443J
물성
구조 계산 물성
- 극성 표면적
- 63.2 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 3
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 6
- 형식 전하
- 0
- 복잡도
- 18.8
실험 및 물리화학적 성질
물리화학적 성질
- 녹는점
- 837 °C · 837 °C
- 끓는 점
- 740 ℃ · decomposes at 740℃ [KIR82]
- 저장 조건
- 30 °C · Store below +30°C.
- 용해도
- 4500 g/L · 4500g/L
- 물리적 상태
- 가루
- 색상
- 하얀색
- 수소이온지수(pH)
- 11.7 · 11.7 (50g/l, H2O, 20℃)
- 수용성
- 녹는
- 비열
- 0.79 J/ · Cp(crystal): 0.79 J/(g·K), at 25℃
- InChI
- InChI=1S/CH2O3.Rb.H/c2-1(3)4;;/h(H2,2,3,4);;
- InChIKey
- WPFGFHJALYCVMO-UHFFFAOYSA-L
- SMILES
- C(O)(O)=O.[RbH]
- EPA
- Carbonic acid, dirubidium salt (584-09-8)
화학적 성질
White powder.Extremely hygroscopic; soluble in water. Dissociates above 900C. The thermal decomposition of rubidium carbonate to produce rubidium oxide and carbon dioxide. This reaction takes place at a temperature of over 900°C in vacuo. The decomposition of Rb2CO3·3H2O2 and Cs2CO3·3H2O2 under isothermal conditions was studied (55–85°) and it was shown that the decomposition of these compounds is self-accelerated. The final products are M2CO3, H2O, and O2. Rb2CO3·3H2O2 has a much higher thermal stability than Cs2CO3·3H2O2.
안전 및 규제
GHS 분류
GHS Classification
Warning
H315 (56.9%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 72 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Chemical: Carbonic acid, dirubidium salt
Carbonic acid, dirubidium salt: Does not have an individual approval but may be used under an appropriate group standard
독성 정보
안전 데이터
- wgk
- 2
- tsca
- TSCA listed
- rtecs
- FG0650000
- 독성
- LD50 orally in Rabbit: 2625 mg/kg
- HS 번호
- 2836 99 17
- risk_code
- 36/37/38
- hazard_code
- Xi
- safety_code
- 26-36/37/39-37/39
- 기존화학 물질
- KE-30645
- F 고인화성물질
- 3-10
- Hazard Classifications
- Eye Dam. 1Skin Corr. 1CSTOT SE 3
- 스토리지 클래스
- 8A - Combustible corrosive hazardous materials
화학 및 산업
용도 및 제조
응용 분야
개요Rubidium carbonate is a white powder or colorless crystal with a monoclinic crystal structure. Its chemical formula is Rb2CO3. Rubidium is often sold as rubidium carbonate The chemical properties of rubidium carbonate are stable. Rubidium carbonate is very hygroscopic, soluble in water, and insoluble in alcohol. It can be converted to other rubidium compounds by heating or by reacting with acids. Rubidium carbonate is used in the preparation of rubidium metal, other rubidium salts,and rubidium single crystals. It is also used as a specific glass additives, catalysts, analytical reagents and others. For example, rubidium carbonate can be incorporated into the metal oxide electron transport layers, which can improve the lifetime of quantum-dot light emitting diodes[1]. It can also exist as an alkaline in the high-temperature nucleophile synthesis of a semi-crystalline, aromatic poly(ether ketone)[2].
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