CAS 13569-65-8 Rhodium chloride trihydrate (HCID 11459718)

이름 및 식별자

우선 이름: Rhodium chloride trihydrate
IUPAC: trichlororhodium;trihydrate
영어명: Rhodium (III) chloride trihydrate
분자식: Cl3H6O3Rh
분자량: 263.31

이름 및 동의어

Rhodium(III) chloride trihydrateRhodium chloride trihydrateRefChem:883009Rhodium (III) chloride, trihydrateRhodium (III) chloride, hydrateRhodium chloride (RhCl3), trihydrateRhodium chloride, trihydrate13569-65-8Rhodium (III) chloride trihydratetrichlororhodium;trihydrateH6Cl3O3RhSCHEMBL16444

이름 더 보기

RHODIUM CHLORIDEchloride trihydratetrichlororhodium trihydrateRHODIUM TRICHLORIDE TRIHYDRATETriaquatrichlororhodiumRHODIUM CHLORIDE, HYDROUSRHODIUM TRICHLORIDE, HYDRATERhodiumTrichlorideForSynthesisRhodium (III) chloride solution

rhodium(III)-chloride trihydrateDTXSID90929110Trichloridorhodium--water (1/3)AKOS015964084AC-18130Rhodium(3+) chloride--water (1/3/3)

데이터베이스 식별자

CAS: 13569-65-8、13876-89-6
PubChem CID: 11459718
DTXSID: DTXSID90929110

물성

구조 계산 물성

극성 표면적: 3 Å²
수소 결합 공여자 수: 3
수소 결합 수용자 수: 3
회전 가능 결합 수: 0
무거운 원자 수: 7
형식 전하: 0
복잡도: 8

실험 및 물리화학적 성질

DensityRelative density (water = 1): >1

SolubilitySolubility in water: soluble

Decomposition100 °C

Physical Description · 2건

Red deliquescent solid; [ICSC] Dark red odorless crystals; Soluble in water; [BASF MSDS]

RED DELIQUESCENT POWDER.

물리화학적 성질

Melting point: 100 °C · 100 °C (decomp)
Density: 1 g/cm3 · 1 g/cm3
storage temp.: Sealed in dry,Room Temperature
Appearance: Reddish brown to black Solid
InChI: InChI=1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChIKey: HSSMNYDDDSNUKH-UHFFFAOYSA-K
SMILES: [Rh](Cl)(Cl)Cl.O
CAS DataBase Reference: 13569 · 13569-65-8(CAS DataBase Reference)
FDA UNII: 4 D88MX3Z8 · Q4D88MX3Z8
Symbol(GHS): 7 · GHS07
Signal word: Danger
Hazard statements: 302 · H302-H318-H341-H290-H410
Precautionary statements: 273 · P273-P391-P501-P201-P202-P281-P308+P313-P405-P501-P234-P390-P404-P264-P270-P301+P312-P330-P501-P280-P305+P351+P338-P310
Hazard Codes: Xn
Risk Statements: 22 · 22-41
Safety Statements: 26 · 26-36/39
RIDADR: 3260 · 3260
WGK Germany: 1 slightly · WGK 1 slightly water endangering
HazardClass: 8 · 8
PackingGroup: III
HS Code: 28439090 · 28439090
Toxicity: 50 orally · LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H290 (97.2%): May be corrosive to metals [Warning Corrosive to Metals]；H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]；H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H341 (96.3%): Suspected of causing genetic defects [Warning Germ cell mutagenicity]；H400 (95.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (95.4%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P203, P234, P264, P264+P265, P270, P273, P280, P301+P317, P305+P354+P338, P317, P318, P330, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 109 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationRhodium chloride (RhCl3), trihydrate: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire. See Chemical dangers

Hazards SummaryIntraperitoneal LD50 (mouse) = 369 mg/kg; [RTECS] No listed effects of short-term or long-term exposure; [ICSC] An irritant that may cause burns; May cause skin sensitization; [BASF MSDS] See Rhodium chloride.

UN ClassificationUN Hazard Class: 8; UN Pack Group: III

Chemical DangersDecomposes on heating. This produces toxic and corrosive fumes including hydrogen chloride (see ICSC 0163). This generates toxic hazard. Reacts violently with iron pentacarbonyl and zinc. This generates explosion hazard.

Packaging and LabellingUnbreakable packaging. Put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.

안전 및 보호

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 4건

Fresh air. Seek medical attention if you feel unwell.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Seek medical attention if you feel unwell.

Safe StorageSeparated from incompatible materials. Well closed. Dry. See Chemical Dangers.

Spillage Disposal · 1건

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

Eye PreventionWear safety spectacles.

Inhalation RiskA harmful concentration of airborne particles can be reached quickly , especially if powdered.

독성 정보

Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Signs and Symptoms · 2건

Cough.

Redness. Pain.

규제 정보

Regulatory InformationRhodium chloride (RhCl3), trihydrate: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: WGK 1 slightly water endangering
ridadr: 3260
hs_code: 28439090
Toxicity: LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg
risk_code: 22-41
Signal word: Danger
Symbol(GHS): GHS07
hazard_code: Xn
safety_code: 26-36/39
hazard_class: 8
packing_group: III
Hazard statements: H302-H318-H341-H290-H410
Precautionary statements: P273-P391-P501-P201-P202-P281-P308+P313-P405-P501-P234-P390-P404-P264-P270-P301+P312-P330-P501-P280-P305+P351+P338-P310

화학 및 산업

용도 및 제조

UsesUsed as a catalyst for the conversion of methane to acetic acid; [ExPub: Health Council of the Netherlands]

응용 분야 · 1건

DescriptionRhodium trichloride is an odourless, red-brown to black crystalline powder. It is corrosive to steel and aluminium. It is hygroscopic and absorbs moisture or water from the air. It is incompatible with strong oxidising agents. On decomposition, rhodium trichloride emits hydrogen chloride, carbon monoxide, carbon dioxide, and rhodium/rhodium oxides.