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플루오린화 메틸(플루오르화 메틸)

Fluoromethane

HCID 11638
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인쇄 미리보기
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
13453-52-6
표준 SMILES
CF
InChIKey
NBVXSUQYWXRMNV-UHFFFAOYSA-N
분자식
CH3F
평균 분자량
34.033 g/mol
단동위원소 질량
34.02187826

개요

Methyl fluoride (or fluoromethane) is a colorless flammable gas which is heavier than air. It has an agreeable ether-like odor. It is narcotic in high concentrations. It burns with evolution of hydrogen fluoride. The flame is colorless, similar to alcohol. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

이름 및 식별자

우선 이름
Fluoromethane
IUPAC
fluoromethane
현지명
플루오린화 메틸(플루오르화 메틸)
영어명
Methyl fluoride
분자식
CH3F
분자량
34.03

이름 및 동의어

FLUOROMETHANEMethyl fluoride593-53-3Freon 41HFC-41UN245454A9X6F0CMHFC 41DTXSID6060474CHEBI:28826UN-2454RefChem:599427
이름 더 보기
플루오르화메틸플루오린화메틸(플루오르화메틸)플루오린화메틸(플루오르화메틸)(METHYLFLUORIDE)플루오로메테인불화메틸R41F41R 41FC-41HFC41A gasFron-41freon41
DTXCID4042593209-796-6Methane, fluoro-CH3FCarbon monofluorideFluormethanMethylfluoridMonofluormethan

데이터베이스 식별자

CAS
13453-52-6、3889-75-6、593-53-3
PubChem CID
11638
DTXSID
DTXSID6060474
ChEMBL
CHEMBL116838
ChEBI
CHEBI:28826
UNII
54A9X6F0CM
EC Number
209-796-6
Nikkaji
J1.245.458I、J2.696D、J298.853D

물성

구조 계산 물성

XLogP
0.6
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
2
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical ClassesFlammable agents - 3rd degree
SolventsSolvents -> Chlorofluorocarbons
SpringerMaterials PropertiesDunham energy parameter
Density0.557 @25 °C
Boiling Point-78.4 °C @760 [mm Hg]
Melting Point-143.3 °C
Vapor Pressure750 [mm Hg] @-78.599999999999994 °C
Physical Description · 3건

Methyl fluoride (or fluoromethane) is a colorless flammable gas which is heavier than air. It has an agreeable ether-like odor. It is narcotic in high concentrations. It burns with evolution of hydrogen fluoride. The flame is colorless, similar to alcohol. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

CBI

Gas with a pleasant ether-like odor; [Merck Index] Colorless gas; [Hawley] Colorless gas with a sweet odor; [MSDSonline]

물리화학적 성질

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H220 (99.2%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P377, P381, P403, and P410+P403 (click each P-code to see the statement)

Aggregated GHS information provided per 129 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H220: Extremely flammable gas [Danger Flammable gases]

유해성 정보

Regulatory Information · 4건

Methane, fluoro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methane, fluoro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Fluoromethane (EC: 209-796-6)

Fluoromethane: HSNO Approval: HSR001007 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Gas
Fire Hazards · 3건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

· EXTREMELY FLAMMABLE.

Health Hazards · 3건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

Hazards Summary · 1건

High concentrations have narcotic effects; [Hawley] Extremely flammable; Can form explosive mixtures with air; High concentrations have narcotic effects; In confined space spill, may displace air and act as simple asphyxiant; Evaporating liquid can cause frostbite; [CAMEO] May cause flash fire; Inhalation of high concentrations can cause CNS depression; Evaporating liquid can cause frostbite; [MSDSonline]

화학 및 산업

용도 및 제조

UsesHydrofluorocarbons are increasingly being used as substitutes for chlorofluorocarbons, e.g., refrigerants, propellants in aerosols, and blowing agents for foams; they do not deplete the ozone layer of the atmosphere. [Ullmann]
U.S. Production2023: <50,000 lb
Consumer UsesOther
Industry UsesEtching agent
General Manufacturing Information · 2건

Computer and Electronic Product Manufacturing

Methane, fluoro-: ACTIVE

응용 분야 · 1건

일반 설명METHYL FLUORIDE (or fluoromethane) is a colorless flammable gas which is heavier than air. METHYL FLUORIDE has an agreeable ether-like odor. METHYL FLUORIDE is narcotic in high concentrations. METHYL FLUORIDE burns with evolution of hydrogen fluoride. The flame is colorless, similar to alcohol. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

상·하류 제품 정보

상류 원료

에틸플루오로디메틸실란1-Pentene-1,3-dione, 4,4,5,5,5-pentafluoro-2-(trifluoromethyl)-3-Pentanone, 1,1,1,2,2,5,5,5-octafluoro-4-(trifluoromethyl)-Propanoyl fluoride, 2,3,3,3-tetrafluoro-

관련 반응

2건
반응 기록 만들기
HRID 41730 반응식
HRID 41730반응물로uspto-grants-2013_09
HRID 2198386 반응식
HRID 2198386반응물로uspto-grants-1982_11

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
녹는점
-115 °C · -115°C
끓는 점
-79 °C · -79°C
밀도
0 · 0,877 g/cm3
증기압
1965 · 1965-5874kPa at 0-15℃
굴절률
1.174 · 1.1740
수용성
1.787 g/L · 1.787g/L(29.9ºC)
비열
1.1 J/ · Cp(gas): 1.1 J/(g·K), at 25℃
Henry's Law Constant
6.1 · 6.1×10-4 mol/(m3Pa) at 25℃, Burkholder et al. (2019)
안정성
안정적인. 가연성이 매우 높습니다. 강한 산화제와 호환되지 않습니다.
LogP
0.51 at · 0.51 at 20℃ and pH7
EPA
-41 · HFC-41 (593-53-3)

화학적 성질

colourless gas with an ether-like odour

DOT ID and Guide · 2건

2454 115

2454 115

Reactive GroupFluorinated Organic Compounds
Reactivity AlertsHighly Flammable
Reactivity Profile · 1건

Halogenated aliphatic compounds, such as METHYL FLUORIDE, are moderately or very reactive. Halogenated organics generally become less reactive as more of their hydrogen atoms are replaced with halogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. The prolonged mixing of halogenated solvents with metallic or other azides may cause the slow formation of explosive azides, for example methylene chloride and sodium azide, [Chem. Eng. News, 1986, 64(51)].

DOT Hazard Classification · 3건

Methyl fluoride, or Refrigerant gas R 41

UN2454

Div 2.1 Flammable gas (49 eCFR § 173.115)

Air and Water ReactionsHighly flammable. It burns in air with evolution of hydrogen fluoride.
Hazard Classes and Categories · 3건

Flam. Gas 1 (99.2%)

Flammable gases (including chemically unstable gases) - Category 1

Flammable agents - 3rd degree

안전 및 보호

Fire FightingExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Accidental Release Measures · 4건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 3건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

General First Aid:

Exposure Control and Personal Protection · 2건

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Isolation and Evacuation · 3건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Immediate precautionary measure

Immediate precautionary measure

Protective Action Criteria (PAC) · 3건

3000 [ppm]

10000 [ppm]

60000 [ppm]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Emergency Response Planning Guidelines · 2건

· DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

· DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

독성 정보

Adverse EffectsNeurotoxin - Acute solvent syndrome

안전 데이터

tsca
TSCA listed
ridadr
UN 2454 (METHYL FLUORIDE (REFRIGERANT GAS R 41))
HS 번호
2903430010
risk_code
12
hazard_code
F,F+
safety_code
16-33
위험 등급
2.1
기존화학 물질
2009-3-3858
위험 참고 사항
Flammable
Propane, 1,1,2,3,3-pentafluoro-1,3-dimethoxy-
(플루오로메틸)트리메틸실란
1,1,2,3,3,3-헥사플루오로프로필메틸에테르
메톡시메틸트리메틸실란
3,3,3-Trifluoro-2-(trifluoromethyl)propionyl fluoride
2-[디플로로(메톡시)메틸]-1,1,1,3,3,3-헥사플로로프로판
디메틸 에테르
Trimethylfluorosilane

하류 제품

4-브로모-메타-크실렌4-플루오로-2-메틸아닐린3-플루오로-2-메틸아닐린1-(1-Methyl-1H-indol-3-yl)-1-ethanone펜타플루오로에테인(펜타플루오르에탄)테트라플루오르에틸렌

추가 설명

정의ChEBI: A member of the class of fluoromethanes that is methane in which a single hydrogen is substituted by a fluorine atom.