Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- (HCID 117406)

이름 및 식별자

우선 이름: Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-
IUPAC: trimethyl(1-phenylethenoxy)silane
영어명: 1-Phenyl-1-trimethylsiloxyethylene
분자식: C11H16OSi
분자량: 192.33

이름 및 동의어

Trimethyl((1-phenylvinyl)oxy)silaneTrimethyl[(1-phenylvinyl)oxy]silaneEINECS 237-308-11-Phenyl-1-(trimethylsiloxy)ethylenealpha-(Trimethylsiloxy)styreneBenzene, (1-((trimethylsilyl)oxy)ethenyl)-Silane, trimethyl((1-phenylethenyl)oxy)-Silane, trimethyl[(1-phenylethenyl)oxy]-DTXSID10884636Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-RefChem:562065DTXCID101024066

이름 더 보기

DK071DKFELEX0126α-(trimethylsiloxy)styreneà-(trimethylsiloxy)styreneα-(Trimethylsilyloxy)styrene1-Phenyl-1-trimethylsiloxyetheneALPHA-(TRIMETHYLSILYLOXY)STYRENE(1-phenylvinyl)oxyTrimethylsilane

237-308-113735-81-41-Phenyl-1-trimethylsiloxyethylenetrimethyl(1-phenylethenoxy)silane1-Phenyl-1-trimethylsilyloxyethyleneC11H16OSiMFCD000085821-Phenyl-1-(trimethylsilyloxy)ethylene

데이터베이스 식별자

CAS: 13735-81-4
PubChem CID: 117406
DTXSID: DTXSID10884636
UNII: X26FF7XFN5
EC Number: 237-308-1
Nikkaji: J236.395J

물성

구조 계산 물성

극성 표면적: 9.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 3
무거운 원자 수: 13
형식 전하: 0
복잡도: 175

물리화학적 성질

녹는점: 122 · 122-123 °C
끓는 점: 88 · 88-89 °C/11 mmHg (lit.)
밀도: 0.938 g/mL · 0.938 g/mL at 25 °C (lit.)
증기 밀도: 1 · >1 (vs air)
굴절률: 20 · n20/D 1.502(lit.)
인화점: 174 °F · 174 °F
저장 조건: 2 · 2-8°C
물리적 상태: 투명한 액체
색상: Colorless to Light orange to Yellow
Specific Gravity: 0.938 · 0.938
수용성: 물과 반응합니다.
BRN: 1306914 · 1306914
InChI: 1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3
InChIKey: AFFPCIMDERUIST-UHFFFAOYSA-N
SMILES: C[Si](C)(C)OC(=C)c1ccccc1
EPA: Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)

안전 및 규제

GHS 분류

GHS Classification · 5건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.5%)

안전 데이터

wgk: 3
tsca: TSCA listed
HS 번호: 2931900090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
F 고인화성물질: 10-21
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzene, [1-[(trimethylsilyl)oxy]ethenyl]-: ACTIVE

응용 분야 · 2건

용도1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

일반 설명1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.