Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrazinecarboxaldehyde
FORMOHYDRAZIDE · FORMIC HYDRAZIDE · FORMIC ACID HYDRAZIDE · Formic hydrazine · hydrazinecarboxaldehyde · Formhydrazide · Formylhydrazide · Formhydrazid
식별자 및 물리적 특성
| CAS No. | 624-84-0 |
|---|---|
| 분자식 | CH4N2O |
| 평균 분자량 | 60.056 g/mol |
| 단동위원소 질량 | 60.03236276 g/mol |
| SMILES | NNC=O |
| InChIKey | XZBIXDPGRMLSTC-UHFFFAOYSA-N |
| PubChem CID | 12229 |
| EC No. | 210-867-9 |
| DTXSID | DTXSID6020642 |
화학 및 물리적 성질
| XLogP | -2 |
|---|---|
| 극성 표면적 | 55.1 |
| 수소 결합 공여자 수 | 2 |
| 수소 결합 수용자 수 | 2 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 4 |
| 형식 전하 | 0 |
| 복잡도 | 20 |
| 녹는점 | 52-57 °C (lit.) |
| 끓는 점 | 90°C/0.7mmHg(lit.) |
| 밀도 | 1.094±0.06 g/cm3(Predicted) |
| 굴절률 | 1.4840 (estimate) |
| 인화점 | >230 °F |
| 저장 조건 | Keep in dark place,Inert atmosphere,Store in freezer, under -20°C |
| 용해도 | 물: 가용성2.5%, 투명, 무색 |
| pKa(산도 계수) | 13.65±0.20(Predicted) |
| 물리적 상태 | 빛나는 결정 조각 |
| 색상 | 하얀색 |
| 용해도 | 녹는 |
| BRN | 635759 |
| InChI | 1S/CH4N2O/c2-3-1-4/h1H,2H2,(H,3,4) |
| InChIKey | XZBIXDPGRMLSTC-UHFFFAOYSA-N |
| SMILES | [H]C(=O)NN |
| NIST | Formic acid hydrazide(624-84-0) |
| EPA | Hydrazinecarboxaldehyde (624-84-0) |
화학적 성질
WHITE SHINY CRYSTALLINE FLAKES
안전 및 규제
| GHS 분류 | WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (62%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]H336 (35.4%): May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposureNarcotic effects]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 79 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Hazard Classes and Categories | Skin Irrit. 2 (100%)Eye Irrit. 2 (100%)STOT SE 3 (62%)STOT SE 3 (35.4%) |
| 수질 위해 등급(WGK) | 3 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | LQ8615000 |
| 관세 코드 | 29280000 |
| 위험 문구(R) | 36/37/38-20/21/22 |
| 위험 표시 | Xi,Xn |
| 안전 문구(S) | 26-36-36/37/39 |
| F 고인화성물질 | 3-8-10 |
| 위험 등급 | Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
| 저장 분류 | 11 - Combustible Solids |
용도
용도
Formic acid hydrazide is used as a precursor in the preparation of 1,2,4-triazole derivatives. It is also used in the synthesis of 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(beta-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione, which is an anticancer agent.