기본 정보
- 표준 SMILES
[Br][Ti]([Br])([Br])[Br]- InChIKey
UBZYKBZMAMTNKW-UHFFFAOYSA-J- 분자식
- Br4Ti
- 평균 분자량
- 367.48 g/mol
- 단동위원소 질량
- 363.62129
이름 및 식별자
- 우선 이름
- Titanium tetrabromide
- IUPAC
- tetrabromotitanium
- 현지명
- 브롬화 티타늄(IV)
- 영어명
- TITANIUM(IV) BROMIDE
- 분자식
- Br4Ti
- 분자량
- 367.48
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
7789-68-6- PubChem CID
- 123263
- DTXSID
DTXSID90894990- EC Number
- 232-185-0
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 5
- 형식 전하
- 0
- 복잡도
- 19
실험 및 물리화학적 성질
물리화학적 성질
- 녹는점
- 38 · 38-40 °C(lit.)
- 끓는 점
- 230 °C · 230 °C(lit.)
- 밀도
- 3.25 g/mL · 3.25 g/mL at 25 °C(lit.)
- 인화점
- 233 °C · 233°C
- 저장 조건
- 2 · 2-8°C, protect from light, stored under nitrogen
- 용해도
- 2 O · reacts with H2O
- 물리적 상태
- 가루
- 색상
- 오렌지 레드
- Specific Gravity
- 2.6 · 2.6
- 수용성
- 절대 알코올에 용해됩니다. 물에 분해되며 클로로카본, 벤젠, 알코올에 용해됩니다.
- 비열
- 0.36 J/ · Cp(crystal): 0.36 J/(g·K); Cp(gas): 0.27 J/(g·K), at 25℃
- Merck
- 14 · 14,9477
- InChI
- 1S/4BrH.Ti/h4*1H;/q;;;;+4/p-4
- InChIKey
- UBZYKBZMAMTNKW-UHFFFAOYSA-J
- SMILES
- Br[Ti](Br)(Br)Br
화학적 성질
Orange low melting lumps and powder
안전 및 규제
GHS 분류
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation];H318 (92.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 68 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
유해성 정보
독성 정보
Treatment
EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
Health Effects
Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)
Toxicity Summary
Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)
Signs and Symptoms
Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)
규제 정보
안전 데이터
- wgk
- 3
- tsca
- No
- ridadr
- UN 3260 8/PG 2
- HS 번호
- 28275900
- risk_code
- 14-34
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- 포장분류
- II
- 위험 등급
- 8
- 기존화학 물질
- KE-33922
- F 고인화성물질
- 3-8-10-21
- Hazard Classifications
- Eye Dam. 1Skin Corr. 1B
- 스토리지 클래스
- 8A - Combustible corrosive hazardous materials
화학 및 산업
약리 정보
Metabolism/Metabolites
Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)
응용 분야
용도Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates.
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