브롬화 티타늄(IV)

Titanium tetrabromide

HCID 123263CAS 7789-68-6

기본 정보

표준 SMILES
[Br][Ti]([Br])([Br])[Br]
InChIKey
UBZYKBZMAMTNKW-UHFFFAOYSA-J
분자식
Br4Ti
평균 분자량
367.48 g/mol
단동위원소 질량
363.62129

이름 및 식별자

우선 이름
Titanium tetrabromide
IUPAC
tetrabromotitanium
현지명
브롬화 티타늄(IV)
영어명
TITANIUM(IV) BROMIDE
분자식
Br4Ti
분자량
367.48

이름 및 동의어

Titanium tetrabromidetetrabromotitaniumTitanium(iv)bromideTiBr4UNII-1CBW950X1W1CBW950X1WEINECS 232-185-0titanium(4+) tetrabromideSCHEMBL42720Titanium(IV) bromide, 98%DTXSID90894990CS-0111542
이름 더 보기
브롬화티타늄(IV)브롬화티타늄(IV)Titanium bromideTITANIUM(IV) BROMIDETitanium(Ⅳ) BromideTetrabromotitanium(IV)Titanium(IV) bromide,98%Titanium(IV) bromide 98%Titanium(IV) tetrabromide
Q411616Titanium(IV) bromide, anhydrous, powder, 99.99% trace metals basis

데이터베이스 식별자

CAS
7789-68-6
PubChem CID
123263
DTXSID
DTXSID90894990
EC Number
232-185-0

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
5

실험 및 물리화학적 성질

Physical DescriptionAmber-yellow or orange highly hygroscopic solid; mp = 28.25 deg C; [Merck Index] Orange solid with an acrid odor; mp = 39 deg C; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
38 · 38-40 °C(lit.)
끓는 점
230 °C · 230 °C(lit.)
밀도
3.25 g/mL · 3.25 g/mL at 25 °C(lit.)
인화점
233 °C · 233°C
저장 조건
2 · 2-8°C, protect from light, stored under nitrogen
용해도
2 O · reacts with H2O

화학적 성질

Orange low melting lumps and powder

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation];H318 (92.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 68 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationTitanium bromide (TiBr4), (T-4)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards SummaryDecomposed by water; [Merck Index] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Titanium tetrachloride.
Hazard Classes and CategoriesSkin Corr. 1B (100%);Eye Dam. 1 (92.6%)

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.;Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

규제 정보

Regulatory InformationTitanium bromide (TiBr4), (T-4)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

안전 데이터

wgk
3
tsca
No
ridadr
UN 3260 8/PG 2
HS 번호
28275900
risk_code
14-34
hazard_code
C

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

응용 분야 · 1건

용도Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates.

공급사34 곳

北京华美互利生物化工010-56205725 · [email protected]
韶远科技(上海)有限公司021-50795510 4000665055 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]

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2건

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