Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
디페닐클로로아르신
디페닐클로로아르신 · 디페닐클로로아르신(DIPHENYLCHLOROARSINE) · 다이페닐클로로아르신 · 디펜일클로로신 · clark1 · clarki · bluecross · sneezinggas
식별자 및 물리적 특성
| CAS No. | 712-48-1 |
|---|---|
| 분자식 | C12H10AsCl |
| 평균 분자량 | 264.58 g/mol |
| 단동위원소 질량 | 263.968698 g/mol |
| SMILES | Cl[As](c1ccccc1)c1ccccc1 |
| InChIKey | YHHKGKCOLGRKKB-UHFFFAOYSA-N |
| PubChem CID | 12836 |
| EC No. | 211-921-4 |
| DTXSID | DTXSID30858733 |
| 현지명 | 디페닐클로로아르신 |
화학 및 물리적 성질
| 극성 표면적 | 0 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 0 |
| 회전 가능 결합 수 | 2 |
| 무거운 원자 수 | 14 |
| 형식 전하 | 0 |
| 복잡도 | 142 |
| 물질 분류 | Reactive agents - 1st degree |
| 밀도 | Relative density (water = 1): 1.4 (45 °C)1.333 @ 40°C1.4820 |
| 용해도 | Solubility in water, g/100ml: 0.2 (poor) |
| Decomposition | 333 °C |
| 녹는점 | 38-44 °C44°C |
| 증기 밀도 | Relative vapor density (air = 1): 9.15 |
| 증기압 | Vapor pressure, Pa at 20 °C: 0.060.00049 [mm Hg] @20 °C |
| Physical Description | Diphenylchloroarsine appears as a chemical warfare vomiting agent. It is a colorless crystalline solid, or a dark-brown liquid. Strongly irritating to skin and eyes. Toxic by ingestion and inhalation.COLOURLESS CRYSTALS. TECHNICAL-GRADE PRODUCT: DARK BROWN LIQUID. |
| 끓는 점 | 337°C |
| 굴절률 | 1.6332 |
| 물리적 상태 | 고체 |
| 헨리 상수 | 6.1×101 mol/(m3Pa) at 25℃, Ebert et al. (2023) |
| EPA | Diphenylchlorarsine (712-48-1) |
안전 및 규제
| 규제 정보 | Restricted substance: ChlorodiphenylarsineThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
|---|---|
| 운송 라벨(DOT) | Poison |
| 화재 위험 | For information on chemical warfare vomiting agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. |
| 건강 유해성 | For information on chemical warfare vomiting agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin. |
| 운송 번호 및 가이드(DOT) | 3450 1511699 151 |
| 반응성 그룹 | Acyl Halides, Sulfonyl Halides, and Chloroformates |
| EC 분류 | Symbol: T, NR: 23/25-50/53S: (1/2)-20/21-28-45-60-61Note: A |
| UN 분류 | UN Hazard Class: 6.1UN Pack Group: I |
| Reactivity Alerts | Strong Reducing Agent |
| Reactivity Profile | DIPHENYLCHLOROARSINE is incompatible with strong oxidizing agents, amines, and alkalis. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. |
| Chemical Dangers | Decomposes on heating. This produces toxic fumes including arsenic and chlorine. Reacts with strong oxidants. |
| Packaging and Labelling | Unbreakable packaging. Put breakable packaging into closed unbreakable container. Severe marine pollutant. |
| 소화 | For information on chemical warfare vomiting agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water. |
용도
일반 설명
A colorless crystalline solid, or a dark-brown liquid. Strongly irritating to skin and eyes. Toxic by ingestion and inhalation. Used as a military poison gas.