Vinylene carbonate (HCID 13385)

이름 및 식별자

우선 이름: Vinylene carbonate
IUPAC: 1,3-dioxol-2-one
현지명: 바이닐렌 카보네이트
영어명: Vinylene carbonate
분자식: C3H2O3
분자량: 86.05

이름 및 동의어

VINYLENE CARBONATE1,3-Dioxol-2-one872-36-61X0ZZF9WFVNSC-20980NSC-47201DTXSID1074888LBG-84922RefChem:901949DTXCID8048573212-825-5Vinyl carbonate

이름 더 보기

바이닐렌카보네이트1,3-다이옥솔-2-온바이닐렌 카보네이트카본산, 고리형 바이닐렌 에스터VCVinylene carboteThe ethylene carbonateVINYLENE CARBONATE (VC)1-methyl-2,3-dihydro-1H-phosphole 1-oxideVinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT1,3-Dioxo-2-oneWITH HYDROQUINONE

2H-1,3-dioxol-2-oneCarbonic acid, cyclic vinylene esterMFCD00005380C3H2O3Vinylene carbonate (stabilized with BHT)WLN: T5OVOJ1,3-Dioxol-2-one,VC25747-73-3

데이터베이스 식별자

CAS: 872-36-6
PubChem CID: 13385
DTXSID: DTXSID1074888
UNII: 1X0ZZF9WFV
EC Number: 212-825-5
Nikkaji: J55.532K

물성

구조 계산 물성

XLogP: 0.3
극성 표면적: 35.5 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 3
회전 가능 결합 수: 0
무거운 원자 수: 6
형식 전하: 0
복잡도: 84.2

실험 및 물리화학적 성질

SpringerMaterials PropertiesSchoenflies notation

Physical DescriptionLiquid; Dry Powder

물리화학적 성질

녹는점: 19 · 19-22 °C(lit.)
끓는 점: 162 °C · 162 °C(lit.)
밀도: 1.36 g/mL · 1.360 g/mL at 20 °C
증기압: 3.35 hPa · 3.35hPa at 25℃
굴절률: 20 · n20/D 1.421(lit.)
인화점: 163 °F · 163 °F
저장 조건: 2 · 2-8°C
용해도: 11.5 g/100mL · 11.5g/100mL
물리적 상태: 액체
Specific Gravity: 1.355 · 1.355
색상: 무색~담황색
수용성: 11.5 g/100mL · 11.5g/100mL
BRN: 105683 · 105683
InChI: 1S/C3H2O3/c4-3-5-1-2-6-3/h1-2H
InChIKey: VAYTZRYEBVHVLE-UHFFFAOYSA-N
SMILES: O=C1OC=CO1
LogP: -0.36 at · -0.36 at 20℃
NIST: 1 · 1,3-Dioxol-2-one(872-36-6)
EPA: 1 · 1,3-Dioxol-2-one (872-36-6)

화학적 성질

clear colorless to light yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 0.4% (1 of 263) of reports.

Danger

H302 (99.2%): Harmful if swallowed [Warning Acute toxicity, oral]

P203, P260, P261, P262, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P354+P338, P316, P317, P318, P319, P321, P330, P332+P317, P333+P317, P361+P364, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 263 reports by companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 3건

1,3-Dioxol-2-one is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,3-Dioxol-2-one are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 19-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/10740

Peroxide Forming Chemical · 4건

Vinylene carbonate

D: Other compounds that may form peroxides

Kelly

An account of a container bursting in storage. Could be due to carbon dioxide evolution, but other factors cannot be ruled out. See Bretherick's.

Hazard Classes and CategoriesAcute Tox. 4 (99.2%)

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: FG3325000
ridadr: UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
HS 번호: 29209090
risk_code: 43-36-51/53-48/22-41-38-24-22
hazard_code: Xi,N,T
safety_code: 37/39-26-24-61-45-36/37/39
위험 등급: 6.1
기존화학 물질: 2001-3-1927
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 4 OralAquatic Chronic 2Eye Dam. 1Skin Irrit. 2Skin Sens. 1STOT RE 2 Oral
스토리지 클래스: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

화학 및 산업

용도 및 제조

U.S. Production2023: 1,000,000 - <2,500,000 lb

Consumer UsesSolvent

Industry UsesSolvent

General Manufacturing Information · 2건

Transportation Equipment Manufacturing

1,3-Dioxol-2-one: ACTIVE

응용 분야 · 2건

용도Vinylene carbonate is used as an additive to electrolyte solutions for anode side Lithiumion batteries. It also acts as a sealant to seal at least a portion of the silicon-polyvinyl acid interface. It is further used for great improvement of high temperature performance of the battery.

일반 설명This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.

제조 방법 · 1건

Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).