기본 정보
- 표준 SMILES
CCCCP(CCCC)CCCC- InChIKey
TUQOTMZNTHZOKS-UHFFFAOYSA-N- 분자식
- C12H27P
- 평균 분자량
- 202.32 g/mol
- 단동위원소 질량
- 202.18503749
개요
Tributylphosphine is a colorless to yellowish liquid with a strong garlic-like odor. It is insoluble in water. It is liable to heat and ignite spontaneously in air. If involved in a fire phosphine gas, a highly flammable and toxic gas, will evolve. It is irritating to mucous membranes.
이름 및 식별자
- 우선 이름
- Tributylphosphine
- IUPAC
- tributylphosphane
- 현지명
- 트리-n-부틸포스핀
- 영어명
- Tributylphosphine
- 분자식
- C12H27P
- 분자량
- 202.32
이름 및 동의어
TributylphosphineTributylphosphaneTri-n-butylphosphine998-40-3Phosphine, tributyl-Tris(butyl)phosphineTributylfosfinDTXSID90469980O52FJR7WNUN3254NSC-91700DTXCID7026998
이름 더 보기
트리부틸포스핀트리-n-부틸포스핀트라이부틸포스핀트라이뷰틸포스핀TBUPP(n-Bu)3cytop 340TributylphosphorusNSC 91700(n-C4H9)3PCYTOP(R) 340
RefChem:190921213-651-2tributyl phosphineTri-n-butyl phosphinetributyl-phosphaneMFCD00009462Bu3PPBu3
데이터베이스 식별자
- CAS
998-40-3- PubChem CID
- 13831
- DTXSID
DTXSID9046998- ChEMBL
CHEMBL3185473- UNII
- 0O52FJR7WN
- EC Number
- 213-651-2
- Nikkaji
- J56.131B
물성
구조 계산 물성
- XLogP
- 3.7
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 9
- 무거운 원자 수
- 13
- 형식 전하
- 0
- 복잡도
- 72.1
실험 및 물리화학적 성질
Chemical ClassesOther Classes -> Phosphorus Compounds
Density0.812 @25 °C
Boiling Point240 °C @760 [mm Hg]
Vapor Pressure16 [mm Hg] @121 °C
Physical Description
Tributylphosphine is a colorless to yellowish liquid with a strong garlic-like odor. It is insoluble in water. It is liable to heat and ignite spontaneously in air. If involved in a fire phosphine gas, a highly flammable and toxic gas, will evolve. It is irritating to mucous membranes.
Liquid
Colorless to yellowish liquid with a strong odor like garlic; [CAMEO] Clear colorless liquid; [Sigma-Aldrich MSDS]
물리화학적 성질
- 녹는점
- -65 °C · -65 °C
- 끓는 점
- 150 °C50 · 150 °C50 mm Hg(lit.)
- 밀도
- 0.81 g/mL · 0.81 g/mL at 25 °C(lit.)
- 증기 밀도
- 9 · 9 (vs air)
- 증기압
- 1.9 Pa · 1.9Pa at 20℃
- 굴절률
- 20 · n20/D 1.462(lit.)
- 인화점
- 99 °F · 99 °F
- 저장 조건
- 2 · 2-8°C
- 물리적 상태
- 액체
- 색상
- 무색~담황색 투명
- Specific Gravity
- 0.82 · 0.820 (20/4℃)
- 수용성
- 불용성
- BRN
- 1738261 · 1738261
- 안정성
- 안정적이지만 자연발화성 - 공기 중에서 자연적으로 인화성이 있음. 산화제와 호환되지 않습니다. 수분에 민감합니다.
- InChI
- 1S/C12H27P/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
- InChIKey
- TUQOTMZNTHZOKS-UHFFFAOYSA-N
- SMILES
- CCCCP(CCCC)CCCC
- NIST
- Phosphine, tributyl-(998-40-3)
- EPA
- Phosphine, tributyl- (998-40-3)
화학적 성질
Tributylphosphine is a clear liquid with a nauseating odor. It reacts slowly with atmospheric oxygen, and rapidly with other oxidizing agents.
안전 및 규제
GHS 분류
GHS Classification
Danger
H226 (15.7%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P222, P231, P233, P235, P240, P241, P242, P243, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P335+P334, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P370+P378, P391, P403+P235, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 287 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Not Classified
Danger
유해성 정보
Regulatory Information
Chemical: Phosphine, tributyl-
Phosphine, tributyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphine, tributyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 25-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/18531
Phosphine, tributyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
DOT LabelSpontaneously Combustible
Fire Hazards
Excerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
· Flammable/combustible material.
Health Hazards
Excerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
· Fire will produce irritating, corrosive and/or toxic gases.
Hazards Summary
Pyrophoric; May ignite on contact with water or moisture; [CAMEO] Causes burns; [EPA OHM/TADS] Pyrophoric; Reacts violently with water; Causes burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract; Harmful by ingestion and skin absorption; [Sigma-Aldrich MSDS] See Triphenylphosphine and tert-Butylphosphine.
DOT ID and Guide3254 135
Reactive GroupAmines, Phosphines, and Pyridines
Reactivity AlertsHighly Flammable
Reactivity ProfileOrganophosphines, such as TRIBUTYLPHOSPHANE, are susceptible to partial oxidation by oxidizing agents, resulting in the release of phosphine oxides.
DOT Hazard Classification
Tributylphosphane
UN3254
Div 4.2 Spontaneously combustible material (49 eCFR § 173.124)
PG I: the degree of danger presented by the material is great
Air and Water ReactionsHighly flammable. May ignite on contact with air or moist air. Insoluble in water.
Hazard Classes and Categories
Flam. Liq. 3 (15.7%)
Pyrophoric liquids - Category 1
안전 및 보호
Fire FightingExcerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
Isolation and Evacuation
Excerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
Immediate precautionary measure
Protective Action Criteria (PAC)
2.3 [mg/m3]
25 [mg/m3]
150 [mg/m3]
Personal Protective Equipment (PPE)Excerpt from ERG Guide 135 [Substances - Spontaneously Combustible]:
Emergency Response Planning Guidelines· DO NOT USE WATER, CO2 OR FOAM ON MATERIAL ITSELF.
독성 정보
Adverse EffectsDermatotoxin - Skin burns.
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- SZ3270000
- ridadr
- UN 3254
- HS 번호
- 29319090
- risk_code
- 36/38-34-21/22-17-11-37-36/37/38-61
- hazard_code
- Xi,F,C,T
- safety_code
- 41-36/37/39-26-16-45-43-17-5-53
- 포장분류
- I
- 위험 등급
- 4.2
- F 고인화성물질
- 10-13-23
- 자연 발화 온도
- 392 °F
- Hazard Classifications
- Aquatic Chronic 3Eye Dam. 1Repr. 1BSkin Corr. 1ASTOT SE 3
- 스토리지 클래스
- 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
화학 및 산업
용도 및 제조
Uses
Used as a polymerization cross-linking catalyst, organic intermediate, and as a catalyst component for hydrogenation in the petroleum industry; [EPA OHM/TADS]
Petroleum Production and Refining [Category: Industry]
U.S. Production2023: 50,000 - <250,000 lb
Industry UsesIntermediate
General Manufacturing Information
All Other Basic Organic Chemical Manufacturing
Phosphine, tributyl-: ACTIVE
응용 분야
용도Tributylphosphine is usually used as catalyst for Domino reactions of activated conjugated dienes with β,γ-unsaturated-α-ketoesters, [3+2]-Cycloadditions,Umpolung addition reactions,Reductive carbonylation, Allylation reactions.
일반 설명Tributylphosphane is a colorless to yellowish liquid with a strong garlic-like odor. Tributylphosphane is insoluble in water. Tributylphosphane is liable to heat and ignite spontaneously in air. If involved in a fire phosphine gas, a highly flammable and toxic gas, will evolve. Tributylphosphane is irritating to mucous membranes.
상·하류 제품 정보
상류 원료
하류 제품
공급사50 곳
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
安徽至善新材料有限公司0554-2114112 18118134211 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
宁波亿诺化学品有限公司86-574-27787657 · [email protected]
北京东华力拓科技发展有限公司010-88425576 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
北京瑞仕邦精细化工技术有限公司+86 (10) 6296-8398 · [email protected]
上海德默医药科技有限公司400-021-7337 2355568890 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
上海景颜化工科技有限公司13817811078 · [email protected]
嘉兴市艾森化工有限公司0573-85285100 18627885956 · [email protected]
池州捷峰生物科技有限公司0566-8928158 · [email protected]
维赛诺化学技术（北京）有限公司13811761079 · [email protected]
上海隆盛化工有限公司58099637 13585536065 · [email protected]
上海长根化学科技有限公司021-69106814 13917161715
唐山默内德贸易有限公司0315-8309571 15633399667 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
南京维奥化工有限公司Please Send Email 18652950785 · [email protected]
南京辛西亚生物科技有限公司0550-5618439 15951861180 · [email protected]
上海慧客化学有限公司15026939015 · [email protected]
河南多贝化工有限公司0370-2785118 17550508557 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
广州艾格生物科技有限公司86-20-28069315 28069316 · [email protected]
上海思域化工科技有限公司86-21-34053660 · [email protected]
苏州思变化学技术有限公司0512-65617459 18915409046 · [email protected]
赛默飞世尔科技（中国）有限公司800-810-5118 · [email protected]
天津尚德药缘科技有限公司13132578992 · [email protected]
上海特伯化学科技有限公司+86-21-60341587 · [email protected]
江苏艾康生物医药研发有限公司025-66113011 13913916777 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.03-36680489 · [email protected]
深圳康特腾科技有限公司86-0755-86635001 · [email protected]
越林试剂021-62960152 · [email protected]
北京格林凯默科技有限公司131-21959385 18804271668 · [email protected]
上海泽信化工科技有限公司021-60136491 15901897992
上海倍卓生物科技有限公司021-61119791,13386096464 · [email protected]
苏州爱玛特生物科技有限公司0512-56316828 4008675858 · [email protected]
北京环宇世纪化学科技有限公司hysj_bj.com
上海将来实业股份有限公司021-61552785 · [email protected]
安徽科迪达化工有限公司0554-2106669 · [email protected]
郑州阿尔法化工有限公司0371-53732842 15981811963 · [email protected]
上海爱蝶实业有限公司021-58957966 18930537195 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
广拓化学（上海）有限公司021-60899189-8001 18918189673 · [email protected]
上海御略医药科技有限公司021-60345187 13671753212 · [email protected]
上海马氏化学科技有限公司19916721580 · [email protected]
관련 반응
2,474건
연결된 노트
불러오는 중…