트리스(4-플루오로페닐)포스핀

Tris(4-fluorophenyl)phosphine

HCID 140387CAS 18437-78-0

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: Fc1ccc(P(c2ccc(F)cc2)c2ccc(F)cc2)cc1
InChIKey: GEPJPYNDFSOARB-UHFFFAOYSA-N
분자식: C18H12F3P
평균 분자량: 316.3 g/mol
단동위원소 질량: 316.06287187

이름 및 식별자

우선 이름: Tris(4-fluorophenyl)phosphine
IUPAC: tris(4-fluorophenyl)phosphane
현지명: 트리스(4-플루오로페닐)포스핀
영어명: Tris(4-fluorophenyl)phosphine
분자식: C18H12F3P
분자량: 316.26

이름 및 동의어

Tris(4-fluorophenyl)phosphinePhosphine, tris(4-fluorophenyl)-Phosphine, tris(p-fluorophenyl)-DTXSID80171565tri-(4-Fluorophenyl)phosphineNSC 158458RefChem:192107DTXCID7094056627-663-4GEPJPYNDFSOARB-UHFFFAOYSA-N18437-78-0tris(4-fluorophenyl)phosphane

이름 더 보기

트리스(4-플루오로페닐)포스핀Tris(4-fLTris(4-fluoropheTris(4-fluorophenyl)Tris(4-Flurophenyl)Phosphinetri(4-fluorophenyl)phosphinoTri-(p-fluorophenyl)phosphine

Tris(p-fluorophenyl)phosphineMFCD00013553TRI(4-FLUOROPHENYL)PHOSPHINEp(4-fc6h4)3C18H12F3PSCHEMBL196718tris (p-fluorophenyl)phosphineCS-W009423

데이터베이스 식별자

CAS: 18437-78-0
PubChem CID: 140387
DTXSID: DTXSID80171565
EC Number: 627-663-4
Nikkaji: J126.187H

물성

구조 계산 물성

XLogP: 4.9
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 3
회전 가능 결합 수: 3
무거운 원자 수: 22
형식 전하: 0
복잡도: 275

물리화학적 성질

녹는점: 79 · 79-83 °C(lit.)
끓는 점: 160 °C/0.1mmHg · 160°C/0.1mmHg(lit.)
저장 조건: Inert atmosphere,Room Temperature
물리적 상태: 결정성 분말
색상: 흰색에서 아주 약간 노란색
수용성: 물에 불용성.
BRN: 919838 · 919838
InChI: InChI=1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey: GEPJPYNDFSOARB-UHFFFAOYSA-N
SMILES: P(C1=CC=C(F)C=C1)(C1=CC=C(F)C=C1)C1=CC=C(F)C=C1

화학적 성질

white to light yellow crystal powde

안전 및 규제

GHS 분류

GHS Classification · 5건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.8%)

안전 데이터

wgk: 3
HS 번호: 29319090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
위험 등급: IRRITANT
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야 · 2건

용도Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes. Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

일반 설명We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

제조 방법

with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.