Phenyl triflimide (HCID 142176)

이름 및 식별자

우선 이름: Phenyl triflimide
IUPAC: 1,1,1-trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide
영어명: N-Phenyl-bis(trifluoromethanesulfonimide)
분자식: C8H5F6NO4S2
분자량: 357.25

이름 및 동의어

37595-74-7N,N-Bis(trifluoromethylsulfonyl)anilinePhenyl triflimide1,1,1-Trifluoro-N-phenyl-N-((trifluoromethyl)sulfonyl)methanesulfonamideN-PhenyltrifluoromethanesulfonimideN,N-Bis(trifluoromethanesulfonyl)anilineTf2NPhN-Phenylbis(trifluoromethanesulphonimide)n-phenyltriflimide1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamideTIC0LRR43XNSC 240874

이름 더 보기

PhNTf2N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE)1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamidephenyltrifluoromethanesulfonimidetrifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamideN-PHENYLT

NSC-240874phenyl bis((trifluoromethyl)sulfonyl)aminePHENYL TRIFLIMIDE [MI]N-phenyltrifluoromethylsulfonimideDTXSID70191030EC 609-445-0n,n-bis(trifluoromethylsulfonyl)phenylamine1,1,1-Trifluoro-N-phenyl-N-((trifluoromethyl)sulfonyl)methane sulfonamide

데이터베이스 식별자

CAS: 37595-74-7
PubChem CID: 142176
DTXSID: DTXSID70191030
UNII: TIC0LRR43X
EC Number: 609-445-0
Nikkaji: J267.288J

물성

구조 계산 물성

XLogP: 3.1
극성 표면적: 88.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 11
회전 가능 결합 수: 3
무거운 원자 수: 21
형식 전하: 0
복잡도: 518

실험 및 물리화학적 성질

PFASPFAS -> PFAS identified in REACH Regulation EC No. 1272/2008

물리화학적 성질

녹는점: 100 · 100-102 °C(lit.)
끓는 점: 305.3 · 305.3±52.0 °C(Predicted)
밀도: 1.766 · 1.766±0.06 g/cm3(Predicted)
저장 조건: Keep in dark place,Sealed in dry,Room Temperature
용해도: 메탄올에 용해됩니다. 클로로포름과 에틸 아세테이트에 약간 용해됩니다.
물리적 상태: 결정 또는 결정성 분말
산도 계수 (pKa): -13.12 · -13.12±0.50(Predicted)
색상: 흰색 또는 무색
BRN: 1269141 · 1269141
안정성: 수분에 민감한
InChI: InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
InChIKey: DIOHEXPTUTVCNX-UHFFFAOYSA-N
SMILES: C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
NIST: N-phenyltrifluoromethanesulfonimide(37595-74-7)

화학적 성질

white to off-white crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 55 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationStatus: Active Update: 17-05-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/16472

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

안전 데이터

wgk: 3
tsca: No
HS 번호: 29242100
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
위험 등급: IRRITANT
F 고인화성물질: 21
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야 · 2건

용도제약 중간체

개요N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation.

상·하류 제품 정보

상류 원료

하류 제품

1-Boc-4-메탄술포닐옥시피페리딘 2-(triMethylsilyl)ethyl 4-(trifluoroMethylsulfonyloxy)-5,6-dihydropyridine-1(2H)-carboxylate 1-CYCLOHEXEN-1-YL트리플루오로메탄-Methyl 3-((Trifluoromethylsulfonyl)oxy)phenylacetate

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

怀化元研达生物技术有限责任公司18711085600 · [email protected]

INTATRADE GmbH+49 3493/605464 · [email protected]

연결된 노트

불러오는 중…

Phenyl triflimide

기본 정보