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카드뮴 셀레니드

Cadmium selenide

HCID 14784
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
1306-24-7
표준 SMILES
[Se]=[Cd]
InChIKey
AQCDIIAORKRFCD-UHFFFAOYSA-N
분자식
CdSe
평균 분자량
191.38 g/mol
단동위원소 질량
193.8198798

개요

Cadmium selenide is a cadmium molecular entity.

이름 및 식별자

우선 이름
Cadmium selenide
IUPAC
selanylidenecadmium
현지명
카드뮴 셀레니드
영어명
Cadmium selenide
분자식
CdSe
분자량
191.37

이름 및 동의어

CADMIUM SELENIDE1306-24-7Cadmium selenide (CdSe)selanylidenecadmiumcadmium(II) selenidecadmium(2+) selenideDTXSID1061651A7F646JC5CCHEBI:50834CdSe cpdRefChem:122596DTXCID2033990
이름 더 보기
카드뮴셀레니드카드뮴셀레니드카드뮴 셀레나이드셀라닐리덴카드뮴셀레늄화 카드뮴카드모셀리트카드뮴 모노셀레나이드카드뮴 컬러카드뮴 혼합물카드뮴모노셀레니드카드뮴셀레늄화합물카드뮴셀레나이드Red BBSLUMIDOT CDSEProMotion CodeCadmium ColoursselenoxocadmiumLumidot CdSe 520cadmium selemideCadmium monoselenide
215-148-3EINECS 215-148-3UNII-A7F646JC5C(Selenido)cadmiumSCHEMBL19326Cadmium selenide, 325 meshFC164914NS00112451

데이터베이스 식별자

CAS
1306-24-7、157453-13-9、331269-19-3
PubChem CID
14784
DTXSID
DTXSID1061651
ChEBI
CHEBI:50834
EC Number
215-148-3
Nikkaji
J96.071C

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
2
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Cadmium Compounds, Inorganic
SpringerMaterials Propertiesvalence band parameter
Physical Description · 2건

Dry Powder

White to brown solid; Turns red in sunlight; [Merck Index] Red or black odorless powder; Insoluble in water; [MSDSonline]

물리화학적 성질

녹는점
1350 °C · >1350°C
끓는 점
69 °C · 69.00°C
밀도
5.81 g/mL · 5.81 g/mL at 25 °C(lit.)
굴절률
2.87 · 2.87 (900 nm)
저장 조건
2 · 2-8°C
용해도
2 O · insoluble in H2O
물리적 상태
세분화된
색상
갈색-빨간색에서 검정색까지
Specific Gravity
5.81 · 5.81
수용성
물에 불용성.
Merck
14 · 14,1626
안정성
냉각
InChI
1S/Cd.Se
InChIKey

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H301+H331 (32.5%): Toxic if swallowed or if inhaled [Danger Acute toxicity, oral; acute toxicity, inhalation]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P317, P318, P319, P321, P330, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 323 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

유해성 정보

Regulatory Information · 5건

Chemical: Cadmium selenide (CdSe)

Cadmium selenide (CdSe) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cadmium selenide (CdSe) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 04-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23754

Restricted substance: Cadmium selenide

Cadmium selenide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Mixed zinc cadmium sulfides and selenides: Human health tier II assessment
Hazards SummaryAn irritant; Can be absorbed through skin; Danger of cumulative effects; [MSDSonline] See Cadmium and the linked diseases. See Selenium.
Hazard Classes and Categories · 2건

Acute Tox. 3 (98.1%)

Acute toxicity - category 4

안전 및 보호

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Cadmium is absorbed from oral, inhalation, and dermal routes. Cadmium initially binds to metallothionein and albumin and is transported mainly to the kidney and liver. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Cadmium is not known to undergo any direct metabolic conversion and is excreted unchanged, mainly in the urine. Selenium may be absorbed through inhalation and ingestion, while some selenium compounds may also be absorbed dermally. Once in the body, selenium is distributed mainly to the liver and kidney. Selenium is an essential micronutrient and is a component of glutathione peroxidase, iodothyronine 5'-deiodinases, and thioredoxin reductase. Organic selenium is first metabolized into inorganic selenium. Inorganic selenium is reduced stepwise to the intermediate hydrogen selenide, which is either incorporated into selenoproteins after being transformed to selenophosphate and selenocysteinyl tRNA or excreted into the urine after being transformed into methylated metabolites of selenide. Elemental selenium is also methylated before excretion. Selenium is primarily eliminated in the urine and feces, but certain selenium compounds may also be exhaled. (L619, L6)

용도 및 제조

Uses · 3건

Used in photoconductors, semiconductors, photoelectric cells, rectifiers, and phosphors; [Merck Index] Used as red pigment; [Hawley]

Semiconductor Manufacturing [Category: Industry]

Cadmium selenide is used as a semiconductor. It is also found in laser diodes. (L471)

U.S. Production2023: 50,000 - <250,000 lb
Consumer UsesSemiconductor and photovoltaic agent
Industry UsesSemiconductor and photovoltaic agent
Household ProductsInformation on 6 consumer products that contain Cadmium selenide in the following categories is provided:

관련 반응

0건
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
AQCDIIAORKRFCD-UHFFFAOYSA-N
SMILES
[Se]=[Cd]
Knoop Microhardness
1300 · 1300, N/mm2
EPA
Cadmium selenide (CdSe) (1306-24-7)
화학적 성질 · 1건

3–12mm pieces (sintered), and -325 mesh 10μm or less with 99.999% purity; white to brown; cub or hexagonal crystal(s); hex: a=0.4309nm, c=0.7021 nm, enthalpy of fusion 305.307 kJ/mol; becomes red in sunlight; used as a red pigment, in semiconductors, and as an evaporation material and sputtering target to produce photoconductive films and infrared filters; possible use in the electrofabrication of microdiode arrays [HAW93] [MER06] [CER91] [KLE93] [KRE91]

Exposure Control and Personal Protection · 2건

Biological Exposure Indices (BEI) [ACGIH] - Cd in urine = 5 ug/g creatinine; Cd in blood = 5 ug/L; sampling time not critical; Monitoring in blood should be preferred during the initial year of exposure and whenever changes in the degree of exposure are suspected. [ACGIH]

0.02 [mg/m3], inhalable fraction, as Se[German Research Foundation (DFG)]

Minimum Risk Level · 1건

Acute Inhalation: 0.00003 mg/m3 (Cadmium) (L134) Chronic Inhalation: 0.00001 mg/m3 (Cadmium) (L134) Intermediate Oral: 0.0005 mg/kg/day (Cadmium) (L134) Chronic Oral: 0.0001 mg/kg/day (Cadmium) (L134) Chronic Oral: 0.005 mg/kg/day (Selenium) (L134)

Threshold Limit Values (TLV)0.01 [mg/m3], as Cd ( 0.002 mg/m3, as Cd, respirable fraction) 0.2 mg/m3, as Se
Permissible Exposure Limit (PEL)0.005 [mg/m3], as Cd( see 29 CFR 1910.1027) 0.2 mg/m3, as Se
Immediately Dangerous to Life or Health (IDLH)9.0 [mg/m3], as Cd

독성 정보

TreatmentCadmium poisoning is treated by removal from exposure and supportive care. If ingested, induced vomiting or gastric lavage may be performed. (L139)
Health Effects · 1건

Chronic exposure to cadmium fumes can cause chemical pneumonitis, pulmonary edema, and lung diseases such as bronchitis and emphysema. Cadmium also accumulates in the kidneys, causing permanent damage. Loss of bone density also occurs. Chronic oral exposure to high concentrations of selenium compounds can produce a disease called selenosis. The major signs of selenosis are hair loss, nail brittleness, and neurological abnormalities (such as numbness and other odd sensations in the extremities). Animal studies have shown that selenium may also affect sperm production and the female reproductive cycle. (L619, L6)

Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L6) ; inhalation (L6) ; dermal (L6)
Toxicity Summary · 1건

Cadmium initially binds to metallothionein and is transported to the kidney. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Accumulation of cadmium in the kidney results in increased excretion of vital low and high weight molecular proteins. Cadmium is a high affinity zinc analog and can interfere in its biological processes. It also binds to and activates the estrogen receptor, likely stimulating the growth of certain types of cancer cells and causing other estrogenic effects, such as reproductive dysfunction. Cadmium causes cell apoptosis by activating mitogen-activated protein kinases. Selenium readily substitutes for sulfur in biomolecules and in many biochemical reactions, especially when the concentration of selenium is high and the concentration of sulfur is low. Inactivation of the sulfhydryl enzymes necessary for oxidative reactions in cellular respiration, through effects on mitochondrial and microsomal electron transport, might contribute to acute selenium toxicity. Selenomethionine (a common organic selenium compound) also appears to randomly substitute for methionine in protein synthesis. This substitution may affect the structure and functionability of the protein, for example, by altering disulfide bridges. Inorganic forms of selenium appear to react with tissue thiols by redox catalysis, resulting in formation of reactive oxygen species and causing damage by oxidative stress. (L619, L8, A18, A19, A28)

Signs and Symptoms · 1건

Acute inhalation of cadmium fumes results in metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Ingestion of cadmium causes vomiting and diarrhea. Short-term oral exposure to high concentrations of selenium may cause nausea, vomiting, and diarrhea. Brief exposures to high levels of elemental selenium or selenium dioxide in air can result in respiratory tract irritation, bronchitis, difficulty breathing, and stomach pains. Longer-term exposure to either of these air-borne forms can cause respiratory irritation, bronchial spasms, and coughing. (L619, L6)

Carcinogen Classification1, carcinogenic to humans. (L135)

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
EV2300000
ridadr
UN 2570 6.1/PG 3
HS 번호
28429090
risk_code
21-23/25-33-50/53-65-52/53-48/20-38-20/21/22-11-63
hazard_code
T,N,Xn,F
safety_code
36/37-45-60-61-28-20/21-62-16
포장분류
II
위험 등급
6.1
기존화학 물질
KE-04422
Hazard Classifications
Acute Tox. 3 InhalationAcute Tox. 3 OralAcute Tox. 4 DermalAquatic Acute 1Aquatic Chronic 1STOT RE 2 Oral
스토리지 클래스
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 셀레늄 또는 그 화합물과 셀렌화합물을 1% 이상 함유한 혼합물
유해화학물질 필터링
97-1-134
General Manufacturing Information · 2건

Electrical Equipment, Appliance, and Component Manufacturing

Cadmium selenide (CdSe): ACTIVE

응용 분야 · 3건

개요Cadmium selenide (CdSe) appears as grayish-brown or red crystals, is insoluble in water, highly toxic, and has a melting point of 1350°C. It can be produced by co-heating metallic cadmium with hydrogen selenide and is used in electron emitters, spectral analysis, photoconductors, semiconductors, and photosensitive components.

용도Cadmium selenide is used as a n-type semiconductor and its nanoparticles are used in laser diodes, opto-electronic devices, nanosensing, biomedical imaging and high efficiency solar cells. Since, it is transparent to infrared light, it finds application in photoresistors and windows for instruments utilizing IR light.

일반 설명CdSe crystal can exist in solid hexagonal or cubic structure. CdSe behaves as an n-type semiconductor, with a bandgap of 1.74 eV (300K).1

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