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스트론튬 황화물

Strontium sulfide

HCID 14820
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
1314-96-1
표준 SMILES
[S]=[Sr]
InChIKey
XXCMBPUMZXRBTN-UHFFFAOYSA-N
분자식
SSr
평균 분자량
119.69 g/mol
단동위원소 질량
119.87768343

개요

Strontium sulfide is a gray powder with an odor of H2S in moist air. (NTP, 1992)

이름 및 식별자

우선 이름
Strontium sulfide
IUPAC
sulfanylidenestrontium
현지명
스트론튬 황화물
영어명
Strontium sulfide
분자식
SSr
분자량
119.68

이름 및 동의어

STRONTIUM SULFIDE1314-96-1Strontium sulphideStrontium monosulfideHSDB 12UNII-06I13IA27TEINECS 215-249-2EC 215-249-206I13IA27TPIGMENT WHITE 8RefChem:186101C.I. 77847
이름 더 보기
스트론튬황화물스트론튬황화물스트론튬설파이드황화스트론튬SrSCI 77847thioxostrontiumPIGMENT WHITE Sstrontiummonosulfidestrontiumsulfide(srs)STRONTIUM (II) SULFIDE
C.I. PIGMENT WHITE 8STRONTIUM SULFIDE [INCI]DTXCID501355978DTXSID70927179STRONTIUM SULFIDE [HSDB]STRONTIUM SULFIDE [MI]sulfanylidenestrontiumStrontium sulfide (SrS)

데이터베이스 식별자

CAS
1314-96-1
PubChem CID
14820
EC Number
215-249-2
Nikkaji
J134.320C

물성

구조 계산 물성

극성 표면적
32.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
2
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsDepilatory
SpringerMaterials Propertiesthermal expansion coefficient
OdorHAS ODOR OF HYDROGEN SULFIDE IN MOIST AIR
Density · 2건

3.7 at 59 °F (NTP, 1992) - Denser than water; will sink

3.70 AT 25 °C

Color/Form · 2건

GREY, CUBIC CRYSTALS

GRAY POWDER

Solubility · 2건

Slightly sol in water; soluble in acid.

Slightly soluble in water; soluble in acids with decomp.

Decomposition · 2건

When heated to decomposition it emits toxic fumes of /sulfur oxides & hydrogen sulfide./

DECOMPOSES IN ACIDS OR HOT WATER

Melting Point · 2건

greater than 3632 °F (NTP, 1992)

2002 °C

Refractive IndexINDEX OF REFRACTION: 2.107
Physical Description

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H290 (80.2%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 217 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationREACH registered substance: Strontium sulphide (EC: 215-249-2)
Fire PotentialModerate fire ... risk.
Health HazardsACUTE/CHRONIC HAZARDS: Irritant to skin and tissue. Moderate fire hazard and explosion risk. (NTP, 1992)
Hazards SummaryA skin and tissue irritant; [Hawley]; May liberate hydrogen sulfide in the presence of heat or acid; [HSDB] Releases hydrogen sulfide slowly in moist air; [CAMEO] An irritant; [MSDSonline] See Strontium. See Hydrogen sulfide.
Reactive GroupSulfides, Inorganic
RCRA RequirementsD003; A solid waste containing sulfide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.
Reactivity ProfileSTRONTIUM SULFIDE reacts vigorously with acids to release hydrogen sulfide gas. May react exothermically with oxidizing agents including inorganic oxoacids, organic peroxides and epoxides, and inorganic peroxides to generate toxic gases.

화학 및 산업

약리 정보

Metabolism/MetabolitesGASTRIC ACID DECOMPOSES IT TO HYDROGEN SULFIDE.

용도 및 제조

Uses · 5건

Used to make strontium chemicals, paint pigments, luminescent coatings, and pigments in cosmetics and celluloid; Also used as a depilatory; [HSDB]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

DEPILATORY; MFR OF STRONTIUM CHEMICALS; LUMINOUS PAINTS

Used in pigments which are used in interior paints & enamels, luminescent coatings, cosmetics & celluloid

In luminous paints; as a depilatory.

Methods of Manufacturing · 2건

Reduction of celestite, with coke at high temp.

/Non-luminous/ strontium sulfide /is/ made by reduction of the sulfate ... The luminous sulfide is prepared by heating strontium hydroxide with sulfur.

Formulations/Preparations · 5건

GRADES: TECHNICAL; HIGH PURITY

Article of commerce contains 65-75% of strontium sulfide.

200 mesh, 99.9% purity grade /available/

Luminous inorganic pigment: green (in daylight), purple (fluorescent), blue (phosphorescent); pigment white 9; calcium-strontium sulfide

For more Formulations/Preparations (Complete) data for STRONTIUM SULFIDE (6 total), please visit the HSDB record page.

Use ClassificationCosmetics -> Depilatory
General Manufacturing Information · 2건

Strontium sulfide (SrS): ACTIVE

Of the nineteen metal sulfides investigated for the reduction of nitrogen oxide, strontium sulfide appeared to be one of the most promising. Combinations of the most likely sulfides and catalysts were tested and strontium sulfide-sodium fluoride was one of the six best.

응용 분야

관련 반응

0건
반응 기록 만들기

현재 필터 조건에 해당하는 반응 기록이 없습니다.

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
· 2건

Strontium sulfide is a gray powder with an odor of H2S in moist air. (NTP, 1992)

Grey solid; [Merck Index] Grey powder with an odor of rotten eggs; [MSDSonline]

Other Experimental PropertiesDECOMPOSES IN ACIDS OR HOT WATER

물리화학적 성질

녹는점
2000 °C · >2000 °C(lit.)
밀도
3 · 3,7 g/cm3
용해도
2 O; · slightly soluble in H2O; soluble in acid solutions
물리적 상태
가루
Specific Gravity
3.7 · 3.7
색상
회색
수용성
물에 약간 용해됩니다. 산에서 분해됨
비열
0.41 J/ · Cp(crystal): 0.41 J/(g·K), at 25℃
Merck
14 · 14,8849
안정성
안정적인. 산과 호환되지 않습니다.
화장품 원료 기능
제모제
InChI
1S/S.Sr
InChIKey
XXCMBPUMZXRBTN-UHFFFAOYSA-N
SMILES
S=[Sr]
EPA
Strontium sulfide (1314-96-1)
화학적 성질 · 1건

Strontium sulfide is a grey powder giving a hydrogen sulphide-like smell in the air. It is insoluble in cold water, and decomposes in hot water and acid. In the wet air can decompose to H2S, can also be oxidised to SrSO4. heating for 3 hours to light red, and water vapour contact with the formation of SrO, SrSO4, H2 and SO2. reaction with acid to produce H2S.

Air and Water Reactions
Slowly releases H2S in moist air.
EPA Hazardous Waste Number · 1건

D003; A waste containing strontium (such as strontium sulfide) may or may not be characterized as a hazardous waste following testing by the Toxicity Characteristic Leaching Procedure as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations. /Sulfide cmpd/

Toxic Combustion ProductsIn presence of heat ... strontium sulfide may liberate hydrogen sulfide; if involved in a fire, it may release sulfur dioxide.
Hazard Classes and CategoriesMet. Corr. 1 (80.2%)
State Drinking Water Standards · 5건

(AL) ALABAMA 8 pCi/l /Strontium 90/

(CA) CALIFORNIA 8 pCi/l /Strontium 90/

(CT) CONNECTICUT 8 pCi/l /Strontium 90/

(IL) ILLINOIS 8 pCi/l /Strontium 90/

For more State Drinking Water Standards (Complete) data for STRONTIUM SULFIDE (6 total), please visit the HSDB record page.

안전 및 보호

Fire FightingA fire in your laboratory involving this chemical should be extinguished with a dry chemical, carbon dioxide or halon extinguisher. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Storage ConditionsKEEP DRY.
Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with 5% acetic acid, then transfer the dampened material to a suitable container. Use absorbent paper dampened with 5% acetic acid to pick up any remaining material. Your contaminated clothing and the absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with 5% acetic acid followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Disposal Methods · 2건

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number P107, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D003, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste. /Sulfide compound/

Preventive Measures · 1건

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.

독성 정보

Human Toxicity Excerpts · 2건

CASES OF LOCALIZED DERMATITIS ARE REPORTED. TAKEN BY MOUTH, IT IS THE SULFIDE MOIETY & NOT THE STRONTIUM THAT IS RESPONSIBLE FOR THE HIGH TOXICITY. GASTRIC ACID DECOMPOSES IT TO HYDROGEN SULFIDE.

Ingestion of carbon disulfide or sol sulfides causes vomiting, headache, cyanosis, resp depression, fall of blood pressure, loss of consciousness, tremors, convulsions, & death. /Hydrogen sulfide, other sulfides, mercaptans, carbon disulfide & propane sultone/

Antidote and Emergency Treatment · 2건

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... Monitor for shock and treat if necessary ... Anticipate seizures and treat if necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline ... Treat with rapid rewarming techniques ... if frostbite occurs. /Hydrogen sulfide and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or in respiratory arrest. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W TKO. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of pulmonary edema. Consider vasopressors to treat hypotension without signs of hypovolemia ... . Treat seizures with diazepam (Valium) ... . In severe cases use amyl nitrite and sodium nitrite (from the cyanide antidote kit) as described for cyanide poisoning; omit the sodium thiosulfate injection. Early administration will be the most effective. DIRECT PHYSICIAN ORDER ONLY ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Hydrogen sulfide and related compounds/

규제 정보

RCRA RequirementsD003; A solid waste containing sulfide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.
State Drinking Water Standards · 5건

(AL) ALABAMA 8 pCi/l /Strontium 90/

(CA) CALIFORNIA 8 pCi/l /Strontium 90/

(CT) CONNECTICUT 8 pCi/l /Strontium 90/

(IL) ILLINOIS 8 pCi/l /Strontium 90/

For more State Drinking Water Standards (Complete) data for STRONTIUM SULFIDE (6 total), please visit the HSDB record page.

State Drinking Water Guidelines · 2건

(FL) FLORIDA 4,200 ug/l /Strontium/

(ME) MAINE 4200 ug/l /Strontium/

Federal Drinking Water GuidelinesEPA 4000 ug/l

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 3262 8/PG 3
HS 번호
2830908500
risk_code
31-34
hazard_code
C
safety_code
26-36/37/39-45
포장분류
III
위험 등급
4.3
기존화학 물질
KE-32250
Hazard Classifications
Skin Corr. 1B
스토리지 클래스
8A - Combustible corrosive hazardous materials

용도Strontium sulfide (SrS) smells like rotten eggs. It is used as a depilatory to remove hair from skin and hides or In luminous paints.

일반 설명Gray powder with an odor of H2S in moist air.

제조 방법 · 2건

생산 방법Strontium sulfide, grayish-white solid (thermodynamic Ksp 500) reactive with water to form strontium hydrosulfide, Sr(SH)2, solution. Strontium hydrosulfide is formed (1) by reaction of strontium sulfide and H2O, (2) by saturation of strontium hydroxide solution with H2S. Strontium polysulfides are formed by boiling strontium hydrosulfide with sulfur.

Strontium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio: Sr+S+heat→SrS SrS can also be produced by the “carbothermic reduction” of calcium sulfate, which entails the conversion of carbon, usually as charcoal, to CO2: SrSO4+2C→SrS+ 2CO2 This can react further: 3SrSO4+SrS→4SrO+ 4SO2 A mixture of oxide-sulfide is the result. Thus, this type of preparation cannot be used to prepare a pure SrS salt.

상·하류 제품 정보

상류 원료

황화 수소탄산 스트론슘황산 스트론튬탄소

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