1314-96-1[S]=[Sr]XXCMBPUMZXRBTN-UHFFFAOYSA-NStrontium sulfide is a gray powder with an odor of H2S in moist air. (NTP, 1992)
1314-96-13.7 at 59 °F (NTP, 1992) - Denser than water; will sink
3.70 AT 25 °C
GREY, CUBIC CRYSTALS
GRAY POWDER
Slightly sol in water; soluble in acid.
Slightly soluble in water; soluble in acids with decomp.
When heated to decomposition it emits toxic fumes of /sulfur oxides & hydrogen sulfide./
DECOMPOSES IN ACIDS OR HOT WATER
greater than 3632 °F (NTP, 1992)
2002 °C
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Danger
H290 (80.2%): May be corrosive to metals [Warning Corrosive to Metals]
P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 217 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Used to make strontium chemicals, paint pigments, luminescent coatings, and pigments in cosmetics and celluloid; Also used as a depilatory; [HSDB]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
DEPILATORY; MFR OF STRONTIUM CHEMICALS; LUMINOUS PAINTS
Used in pigments which are used in interior paints & enamels, luminescent coatings, cosmetics & celluloid
In luminous paints; as a depilatory.
Reduction of celestite, with coke at high temp.
/Non-luminous/ strontium sulfide /is/ made by reduction of the sulfate ... The luminous sulfide is prepared by heating strontium hydroxide with sulfur.
GRADES: TECHNICAL; HIGH PURITY
Article of commerce contains 65-75% of strontium sulfide.
200 mesh, 99.9% purity grade /available/
Luminous inorganic pigment: green (in daylight), purple (fluorescent), blue (phosphorescent); pigment white 9; calcium-strontium sulfide
For more Formulations/Preparations (Complete) data for STRONTIUM SULFIDE (6 total), please visit the HSDB record page.
Strontium sulfide (SrS): ACTIVE
Of the nineteen metal sulfides investigated for the reduction of nitrogen oxide, strontium sulfide appeared to be one of the most promising. Combinations of the most likely sulfides and catalysts were tested and strontium sulfide-sodium fluoride was one of the six best.
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Strontium sulfide is a gray powder with an odor of H2S in moist air. (NTP, 1992)
Grey solid; [Merck Index] Grey powder with an odor of rotten eggs; [MSDSonline]
Strontium sulfide is a grey powder giving a hydrogen sulphide-like smell in the air. It is insoluble in cold water, and decomposes in hot water and acid. In the wet air can decompose to H2S, can also be oxidised to SrSO4. heating for 3 hours to light red, and water vapour contact with the formation of SrO, SrSO4, H2 and SO2. reaction with acid to produce H2S.
D003; A waste containing strontium (such as strontium sulfide) may or may not be characterized as a hazardous waste following testing by the Toxicity Characteristic Leaching Procedure as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations. /Sulfide cmpd/
(AL) ALABAMA 8 pCi/l /Strontium 90/
(CA) CALIFORNIA 8 pCi/l /Strontium 90/
(CT) CONNECTICUT 8 pCi/l /Strontium 90/
(IL) ILLINOIS 8 pCi/l /Strontium 90/
For more State Drinking Water Standards (Complete) data for STRONTIUM SULFIDE (6 total), please visit the HSDB record page.
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with 5% acetic acid, then transfer the dampened material to a suitable container. Use absorbent paper dampened with 5% acetic acid to pick up any remaining material. Your contaminated clothing and the absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with 5% acetic acid followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number P107, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D003, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste. /Sulfide compound/
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.
CASES OF LOCALIZED DERMATITIS ARE REPORTED. TAKEN BY MOUTH, IT IS THE SULFIDE MOIETY & NOT THE STRONTIUM THAT IS RESPONSIBLE FOR THE HIGH TOXICITY. GASTRIC ACID DECOMPOSES IT TO HYDROGEN SULFIDE.
Ingestion of carbon disulfide or sol sulfides causes vomiting, headache, cyanosis, resp depression, fall of blood pressure, loss of consciousness, tremors, convulsions, & death. /Hydrogen sulfide, other sulfides, mercaptans, carbon disulfide & propane sultone/
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... Monitor for shock and treat if necessary ... Anticipate seizures and treat if necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline ... Treat with rapid rewarming techniques ... if frostbite occurs. /Hydrogen sulfide and related compounds/
Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or in respiratory arrest. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W TKO. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of pulmonary edema. Consider vasopressors to treat hypotension without signs of hypovolemia ... . Treat seizures with diazepam (Valium) ... . In severe cases use amyl nitrite and sodium nitrite (from the cyanide antidote kit) as described for cyanide poisoning; omit the sodium thiosulfate injection. Early administration will be the most effective. DIRECT PHYSICIAN ORDER ONLY ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Hydrogen sulfide and related compounds/
(AL) ALABAMA 8 pCi/l /Strontium 90/
(CA) CALIFORNIA 8 pCi/l /Strontium 90/
(CT) CONNECTICUT 8 pCi/l /Strontium 90/
(IL) ILLINOIS 8 pCi/l /Strontium 90/
For more State Drinking Water Standards (Complete) data for STRONTIUM SULFIDE (6 total), please visit the HSDB record page.
(FL) FLORIDA 4,200 ug/l /Strontium/
(ME) MAINE 4200 ug/l /Strontium/
용도Strontium sulfide (SrS) smells like rotten eggs. It is used as a depilatory to remove hair from skin and hides or In luminous paints.
일반 설명Gray powder with an odor of H2S in moist air.
생산 방법Strontium sulfide, grayish-white solid (thermodynamic Ksp 500) reactive with water to form strontium hydrosulfide, Sr(SH)2, solution. Strontium hydrosulfide is formed (1) by reaction of strontium sulfide and H2O, (2) by saturation of strontium hydroxide solution with H2S. Strontium polysulfides are formed by boiling strontium hydrosulfide with sulfur.
Strontium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio: Sr+S+heat→SrS SrS can also be produced by the “carbothermic reduction” of calcium sulfate, which entails the conversion of carbon, usually as charcoal, to CO2: SrSO4+2C→SrS+ 2CO2 This can react further: 3SrSO4+SrS→4SrO+ 4SO2 A mixture of oxide-sulfide is the result. Thus, this type of preparation cannot be used to prepare a pure SrS salt.