트리뷰틸틴 염화물
트리뷰틸틴염화물 · 트라이뷰틸클로로스탄네인 · 모노클로로트라이뷰틸주석 · 염화 트라이-n-뷰틸주석 · 염화 트라이뷰틸주석 · 클로로트라이-n-뷰틸스탄네인 · 클로로트라이-n-뷰틸주석 · 클로로트라이뷰틸스탄네인
식별자 및 물리적 특성
| CAS No. | 1461-22-9 |
|---|---|
| 분자식 | C12H27ClSn |
| 평균 분자량 | 325.5 g/mol |
| 단동위원소 질량 | 326.08232324 g/mol |
| SMILES | CCC[CH2][Sn]([Cl])([CH2]CCC)[CH2]CCC |
| InChIKey | GCTFWCDSFPMHHS-UHFFFAOYSA-M |
| PubChem CID | 15096 |
| ChEBI | CHEBI:79734 |
| EC No. | 215-958-7 |
| DTXSID | DTXSID3027403 |
| 현지명 | 트리뷰틸틴 염화물 |
화학 및 물리적 성질
| 극성 표면적 | 0 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 0 |
| 회전 가능 결합 수 | 9 |
| 무거운 원자 수 | 14 |
| 형식 전하 | 0 |
| 복잡도 | 104 |
| 물질 분류 | Metals -> Tin Compounds, Organic |
| LogP(분배 계수) | log Kow = 4.76 |
| 밀도 | 1.20 @ 20 °C/4 °C1.2 g/mL at 25 °C(lit.) |
| Color/Form | LiquidColorless liquid |
| 용해도 | Soluble in the common organic solvents, including alcohol, heptane, benzene, and toluene.Insoluble in cold water but hydrolyzes in hot water0.017g/L |
| Endocrine Disruptors | Potential endocrine disrupting compound |
| 끓는 점 | 171-173 °C @ 25 mm Hg171-173 °C25 mm Hg(lit.) |
| Decomposition | When heated to decomp it emits toxic fumes of /hydrogen chloride/. |
| 증기압 | 0.00927 [mmHg]<0.01 mm Hg ( 20 °C) |
| Food Contact Substances | FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR |
| 굴절률 | Index of refraction = 1.4903 @ 25 °Cn20/D 1.492(lit.) |
| Physical Description | LiquidColorless liquid[HSDB] Unpleasant odor[MSDSonline] |
| 녹는점 | -9 °C |
| 인화점 | >230 °F |
| 저장 조건 | 2-8°C |
| 물리적 상태 | 액체 |
| 비중 | 1.186 |
| 색상 | 무색의 |
| 용해도 | 실질적으로 불용성 |
| BRN | 3535715 |
| 안정성 | 흡습성 |
| InChIKey | GCTFWCDSFPMHHS-UHFFFAOYSA-M |
| LogP(분배 계수) | 2.21 at 23℃ |
| NIST | Tri-n-butyltin chloride(1461-22-9) |
| EPA | Tributyltin chloride (1461-22-9) |
화학적 성질
Colorless or light yellow clear liquid. Soluble in the common organic solvents; including alcohol, heptane, benzene, and toluene; insoluble in cold water, but hydrolyzes in hot water.
안전 및 규제
| GHS 분류 | DangerH301+H311 (53.6%): Toxic if swallowed or in contact with skin [Danger Acute toxicity, oralacute toxicity, dermal]P203, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P316, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P318, P319, P320, P321, P330, P332+P317, P333+P317, P337+P317, P361+P364, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 194 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H301: Toxic if swallowed [Danger Acute toxicity, oral] |
|---|---|
| 규제 정보 | Chemical: Stannane, tributylchloro-Hazard Traits - BioaccumulationEnvironmental PersistenceStannane, tributylchloro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Stannane, tributylchloro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 13-11-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/13798Tributyltin chloride: HSNO Approval: HSR004733 Approved with controls |
| 유해성 요약 | Causes tremor and ataxia in lethal dose animal studiesToxicity includes hepatitis[RTECS] Highly irritating to eyesVery toxic to marine organisms[Sax] Hydrolyzed by waterAn irritantCan be absorbed through skin[MSDSonline] See Tin, organic compounds. See Bis(tri-n-butyltin)oxide. |
| Hazard Classes and Categories | Acute Tox. 3 (100%)Acute toxicity (Oral) - Category 3 |
| Shipping Name/ Number DOT/UN/NA/IMO | UN 3146Organotin cmpd, solid, not otherwise specifiedUN 2788Organotin cmpd, liquid, not otherwise specifiedIMO 6.1Organotin cmpd, liquid or solid, not otherwise specified |
용도
용도
Tributyltin Chloride is a triorganotin compound with insecticidal acitivity. It is an endocrine disruptor as well as an inhibitor for the V-ATPases (potential targets in the treatmen t of diseases such as osteoporosis and cancer). Tributyltin Chloride has the functions of antiseptic, sterilization and mildew proof and widely used in wood preservation, ship paint, etc. Further, it is used in hot end glass coating and rodent-repellent for cable coatings.
제조 및 합성 방법
제조 방법
Tributyltin chloride is prepared by a redistribution reaction by combining stannic chloride and tetrabutyltin: 3 (C4H9)4Sn + SnCl4 → 4 (C4H9)3SnCl.