CAS 1576-35-8 P-Toluenesulfonylhydrazide (HCID 15303)

이름 및 식별자

우선 이름: P-Toluenesulfonylhydrazide
IUPAC: 4-methylbenzenesulfonohydrazide
현지명: 토실하이드라자이드
영어명: 4-Methylbenzenesulfonhydrazide
분자식: C7H10N2O2S
분자량: 186.23

이름 및 동의어

1576-35-84-Methylbenzenesulfonohydrazidep-Toluenesulfonyl hydrazideTosylhydrazineTosylhydrazideBenzenesulfonic acid, 4-methyl-, hydrazideP-TOLUENESULFONYLHYDRAZIDEToluene-4-sulphonohydrazidep-toluenesulfonohydrazide(p-Tolylsulfonyl)hydrazine4-Methylbenzenesulfonyl hydrazideTsNHNH2

이름 더 보기

p-톨루엔설포닐히드라지드토실하이드라자이드4-메틸벤젠설포노하이드라자이드4-메틸벤젠설폰산 하이드라자이드N-톨루올설포닐하이드라진p-톨루엔설포하이드라자이드p-톨루엔설폰산, 하이드라자이드p-톨루엔설폰일하이드라자이드p-톨릴설폰일하이드라진벤젠설폰산, 4-메틸-, 하이드라자이드톨루엔-4-설포노하이드라자이드톨루엔-4-설폰일하이드라자이드TSHPTSHTOLUENE-4-SULFONIC ACID HYDRAZIDEP-TOLUENESULFONHYDRAZIDEP-TOLUENESULFONYLHYDRAZINE4-TOLUENESULFONYL HYDRAZIDE

CELLMIC HN-TOSYLHYDRAZINE4-tosylsulphonylhydrazineP-TOSYL HYDRAZIDENSC-18715POROFOR TSH 75Toluene-4-sulfonohydrazide4-METHYLPHENYLSULFONYL HYDRAZIDE

데이터베이스 식별자

CAS: 1576-35-8
PubChem CID: 15303
DTXSID: DTXSID8051756
ChEMBL: CHEMBL221182
UNII: LR93R5002M
EC Number: 216-407-3
Nikkaji: J40.602C

물성

구조 계산 물성

XLogP: 0.2
극성 표면적: 80.6 Å²
수소 결합 공여자 수: 2
수소 결합 수용자 수: 4
회전 가능 결합 수: 2
무거운 원자 수: 12
형식 전하: 0
복잡도: 224

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Hydrazides

Physical Description · 2건

Liquid

White solid; [Merck Index] White nearly odorless powder; [Alfa Aesar MSDS]

물리화학적 성질

녹는점: 103 · 103-108 °C(lit.)
끓는 점: 340.5 · 340.5±35.0 °C(Predicted)
밀도: 1.42 g/cm3 · 1.42g/cm3
증기압: 0 Pa · 0Pa at 20℃
굴절률: 1.54 · 1.5400 (estimate)
인화점: 60 °C · 60°C
저장 조건: -20 °C · Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
용해도: 5 g/L · 5g/L
물리적 상태: 가루
산도 계수 (pKa): 9.39 · 9.39±0.10(Predicted)
색상: 흰색 또는 회백색에서 약간 회색을 띤다.
수용성: 5 g/L · 5g/L(15℃)
BRN: 610130 · 610130
안정성: 감광성
InChI: 1S/C7H10N2O2S/c1-6-2-4-7(5-3-6)12(10,11)9-8/h2-5,9H,8H2,1H3
InChIKey: ICGLPKIVTVWCFT-UHFFFAOYSA-N
SMILES: Cc1ccc(cc1)S(=O)(=O)NN
LogP: 0.55 at · 0.55 at 25℃
EPA: 4 · Benzenesulfonic acid, 4-methyl-, hydrazide (1576-35-8)

화학적 성질

white to off-white powder

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H242: Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P280, P370+P378, P403, P410, P411, P420, and P501 (click each P-code to see the statement)

Danger

H242 (66.7%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P203, P210, P234, P235, P240, P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P316, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P391, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 4건

Chemical: Benzenesulfonic acid, 4-methyl-, hydrazide

Benzenesulfonic acid, 4-methyl-, hydrazide is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenesulfonic acid, 4-methyl-, hydrazide are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 12-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/23441

4-Toluenesulphonohydrazide: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1건

Causes somnolence and convulsions in oral lethal-dose studies of rats; [RTECS] May explode if heated under confinement; Temperatures above 120 deg C or prolonged temperatures above 50 deg C can cause exothermic decomposition with evolution of gas; A mild eye irritant; Toxic by ingestion; [Alfa Aesar MSDS] See Carbohydrazide. See Dansyl hydrazine. See p,p'-Oxybis(benzenesulfonyl hydrazide).

Hazard Classes and Categories · 3건

Self-react. D (66.7%)

Self-reactive substances and mixtures - Type D

Self-react. D

독성 정보

Adverse EffectsNeurotoxin - Other CNS neurotoxin

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: MW0210000
ridadr: UN 3226 4.1
HS 번호: 29280090
risk_code: 11-22-44-2017/11/22
hazard_code: F,Xn
safety_code: 16-26
포장분류: II
위험 등급: 4.1
기존화학 물질: 2008-2-26
Hazard Classifications: Acute Tox. 3 OralAquatic Chronic 2Self-react. D
스토리지 클래스: 5.2 - Organic peroxides and self-reacting hazardous materials
함량 및 규제정보: 물질구분: 유독물질; 혼합물(제품)함량정보: p-톨루엔술포닐히드라지드 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링: 2018-1-819

화학 및 산업

용도 및 제조

UsesUsed as a reagent and scavenger; [Merck Index]

U.S. Production2022: 28,103 lb

Industry UsesIntermediate

General Manufacturing Information · 2건

All Other Chemical Product and Preparation Manufacturing

Benzenesulfonic acid, 4-methyl-, hydrazide: ACTIVE

응용 분야

용도4-Methylbenzenesulfonhydrazide was widely used reagent for the preparation of tosylhydrazones.

상·하류 제품 정보

상류 원료

하류 제품

4,4'-Dimethylbiphenyl DI-P-톨릴아세틸렌 페닐P-톨릴설폰 1,2-비스(p-톨릴설포닐)하이드라진,N,Nμ-디토실하이드라진,4-메틸벤젠설폰산2-[(4-메틸페닐)설포닐]하이드라지드 4-(Methylphenyl)sulfonylacetonitrile N-시클로헥실-4-메틸벤젠술폰아미드 P-톨일 다이설파이드 Bay 11-7082 Dihydroeugenol 1-[(4-Methylphenyl)sulfonyl]-1H-imidazole

공급사100 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

河南多贝化工有限公司0370-6999054 17550096163 · [email protected]

爱斯特（成都）生物制药股份有限公司+86-28-85122536 85324413 · [email protected]

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