홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /화합물

염화 2-클로로에탄술포닐

Ethanesulfonylchloride, 2-chloro-

HCID 15385
새 노트새 반응견적 요청하기
인쇄 미리보기

데이터를 보충하는 중입니다. 잠시 후 페이지를 새로 고치면 최신 내용을 볼 수 있습니다

기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
1622-32-8
표준 SMILES
O=S(=O)(Cl)CCCl
InChIKey
VHCSBTPOPKFYIU-UHFFFAOYSA-N
분자식
C2H4Cl2O2S
평균 분자량
163.02 g/mol
단동위원소 질량
161.93090573

개요

Ethanesulfonyl chloride, 2-chloro- appears as a liquid. Density 1.56 g / cm3. Flash point exceeds 230 °F.

이름 및 식별자

우선 이름
Ethanesulfonylchloride, 2-chloro-
IUPAC
2-chloroethanesulfonyl chloride
현지명
염화 2-클로로에탄술포닐
영어명
2-chloroethanesulfonyl chloride
분자식
C2H4Cl2O2S
분자량
163.02

이름 및 동의어

2-Chloroethanesulfonyl chloride1622-32-8Ethanesulfonyl chloride, 2-chloro-(2-Chloroethyl)sulphonyl chloride2-Chloroethylsulfonyl chloride2-Chloroethane sulfochloridebeta-Chloroethanesulfonyl chloride2-chloro-1-ethanesulfonyl chlorideHSDB 6420ETHANESULFONYLCHLORIDE, 2-CHLORO-AET6VQ5A3Qchloroethanesulfonyl chloride
이름 더 보기
염화2-클로로에탄술포닐2-클로로-1-에테인설폰일 클로라이드oroethanesuL2-chloroethanesulfochloride2-chloroethylsulfonylchloride2-chloro-ethanesulfonylchlorid2-chloroethanesulfochloride[qr]2-CHLOROETHANESULPHONYL CHLORIDEbeta-chloroethanesulfonylchloride2-chloroethylsulfonylchloride[qr]
EINECS 216-594-1BRN 1751202DTXSID50618254-04-00-00036 (Beilstein Handbook Reference)2-chloroethanesulfonic acid chlorideRefChem:5918272Chloroethane sulfochloride2Chloroethylsulfonyl chloride

데이터베이스 식별자

CAS
1622-32-8
PubChem CID
15385
DTXSID
DTXSID5061825
UNII
AET6VQ5A3Q
EC Number
216-594-1
Nikkaji
J78.119C

물성

구조 계산 물성보충 중

XLogP
1
극성 표면적
42.5 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
2
무거운 원자 수
7
형식 전하
0
복잡도
121

실험 및 물리화학적 성질

Chemical Classes · 2건

Toxic Gases & Vapors -> Acid Halides

Reactive agents - 1st degree

SpringerMaterials PropertiesNuclear quadrupole resonance spectroscopy
Density · 3건

1.55 at 68 °F (EPA, 1998) - Denser than water; will sink

1.555 at 20 °C/4 °C

1.555 @ 20°C

Boiling Point · 2건

392 to 397 °F at 760 mmHg (EPA, 1998)

200-3 °C

Physical Description · 2건

Ethanesulfonyl chloride, 2-chloro- appears as a liquid. Density 1.56 g / cm3. Flash point exceeds 230 °F.

Liquid; [CAMEO] Colorless liquid; [MSDSonline]

물리화학적 성질

녹는점
3 °C · 3 °C
끓는 점
84 · 84-86 °C15 mm Hg(lit.)
밀도
1.56 g/mL · 1.56 g/mL at 25 °C(lit.)
증기압
15 mm · 15 mm Hg ( 84 °C)
굴절률
20 · n20/D 1.493(lit.)
인화점
230 °F · >230 °F

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H301 (97.9%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P264, P270, P271, P280, P284, P301+P316, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P330, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

유해성 정보

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelPoison Inhalation Hazard Dangerous When Wet
Fire HazardsExcerpt from ERG Guide 139 [Substances - Water-Reactive (Emitting Flammable and Toxic Gases)]:
Health HazardsExcerpt from ERG Guide 139 [Substances - Water-Reactive (Emitting Flammable and Toxic Gases)]:
Hazards Summary · 1건

Reacts with water evolving hydrogen chloride; [CAMEO] Reacts violently with water; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; Effects in high-dose animal studies include abnormal liver function tests; [MSDSonline] See Ethanesulfonyl chloride.

Reactive GroupHalogenated Organic Compounds
Special ReportsUSEPA; Chemical Profile: Ethanesulfonyl chloride, 2-chloro- (1985). Chemical safety information sheet.

화학 및 산업

용도 및 제조

General Manufacturing InformationEthanesulfonyl chloride, 2-chloro-: ACTIVE
응용 분야 · 2건

용도2-Chloroethanesulfonyl chloride was used in one-pot sulfonylation/intramolecular thia-Michael protocol for the synthesis of 1,5,2-dithiazepine 1,1-dioxides. It was also used in synthesis of vinyl sulfonamides with a furan, carbocyclic, semi cyclic or acyclic 1,3-diene moiety.

일반 설명A liquid. Density 1.56 g / cm3. Flash point exceeds 230°F.

상·하류 제품 정보

상류 원료

Phosphorothioic acid, S-(2-chloroethyl) O,O-diethyl ester이세티온산 소듐 염2-하이드록시에탄설폰산2-클로로에틸아민 염산염티오디글리콜2-머캅토에탄올

하류 제품

비닐술폰산나트륨N-(3-메톡시페닐)-2-모르폴린-4-일-2-옥소-아세트아미드Ethenesulfonic acid, 1-methylethyl ester

관련 반응

546건
반응 기록 만들기
HRID 14448 반응식
HRID 14448반응물로uspto-grants-2010_06
HRID 15881 반응식
HRID 15881반응물로uspto-grants-2010_06
HRID 31388 반응식
HRID 31388반응물로uspto-grants-2008_09
HRID 41697 반응식
HRID 41697반응물로uspto-grants-2013_09
HRID 81955 반응식
HRID 81955반응물로uspto-grants-2014_09
HRID 128594 반응식
HRID 128594반응물로uspto-grants-1995_11
HRID 139828 반응식
HRID 139828반응물로Training data from https://doi.org/10.1039/C8SC04228D (9/10)
HRID 157928 반응식
HRID 157928반응물로Training data from https://doi.org/10.1039/C8SC04228D (9/10)
1 / 69 페이지

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
저장 조건
Refrigerator
물리적 상태
액체
색상
약간 노란색에서 갈색으로 투명함
수용성
물과 반응합니다.
BRN
1751202 · 1751202
InChI
InChI=1S/C2H4Cl2O2S/c3-1-2-7(4,5)6/h1-2H2
InChIKey
VHCSBTPOPKFYIU-UHFFFAOYSA-N
SMILES
C(S(Cl)(=O)=O)CCl
EPA
2 · 2-Chloro-ethanesulfonyl chloride (1622-32-8)

화학적 성질

CLEAR SLIGHTLY YELLOW TO BROWN LIQUID

Reactivity AlertsWater-Reactive
Reactivity Profile · 1건

ETHANESULFONYL CHLORIDE, 2-CHLORO- is incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Air and Water ReactionsReacts with water to produce corrosive and toxic gaseous hydrogen chloride.
Hazard Classes and Categories · 3건

Acute Tox. 3 (97.9%)

Acute toxicity (Oral) - Category 3

Reactive agents - 1st degree

안전 및 보호

Fire FightingExcerpt from ERG Guide 139 [Substances - Water-Reactive (Emitting Flammable and Toxic Gases)]:
First Aid · 1건

Signs and Symptoms of Ethanesulfonyl Chloride, 2-Chloro- Exposure: No information is available on specific clinical effects of exposure to ethanesulfonyl chloride, 2-chloro- exposure. However, because ethanesulfonyl chloride, 2-chloro- is expected to be an irritant and general toxicant, signs and symptoms of exposure may include the following: headache, dizziness, weakness, nausea, irritation of the eyes, skin, and respiratory tract, and dermatitis. Severe respiratory tract irritation can progress to pulmonary edema, the onset of which may be delayed 24-72 hours. Irritation or burns of the esophagus or gastrointestinal tract are possible.

Nonfire Spill ResponseExcerpt from ERG Guide 139 [Substances - Water-Reactive (Emitting Flammable and Toxic Gases)]:
Disposal Methods · 1건

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Isolation and EvacuationExcerpt from ERG Guide 139 [Substances - Water-Reactive (Emitting Flammable and Toxic Gases)]:
Protective Action Criteria (PAC) · 3건

0.23 [mg/m3]

2.5 [mg/m3]

19 [mg/m3]

Personal Protective Equipment (PPE) · 1건

For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)

독성 정보

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Toxicity DataLC50 (rat) = 420 mg/m3/4h

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
KI8060000
ridadr
UN 3390 6.1/PG 1
독성
mouse,LC50,inhalation,250mg/m3/4H (250mg/m3),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 15(6), Pg. 59, 1971.
HS 번호
29049090
risk_code
22-26-34-36
hazard_code
T+
safety_code
26-28-36/37/39-45-23
포장분류
II
위험 등급
8
F 고인화성물질
10-19
유해 물질 데이터
1622-32-8(Hazardous Substances Data)
EthenesulfonaMide, N,N-bis(phenylMethyl)
1-Piperazinecarboxylic acid, 4-(ethenylsulfonyl)-, phenylmethyl ester
N-benzylethenesulfonamide
1-(Vinylsulfonyl)piperidine