Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
디페닐[(페닐티오)페닐]술포늄헥사플루오로포스페이트
디페닐[(페닐티오)페닐]술포늄헥사플루오로포스페이트 · PAG-101 · PI-6992 · CPI-992M · TTA UV-6992 · HRcure-6992 · JADEADD PI-001 · Mixed of Triaryl-sulfonium Hexafluoro- Phosphate Salt
![디페닐[(페닐티오)페닐]술포늄헥사플루오로포스페이트 분자 구조식](/img/chemical/155018.png)
식별자 및 물리적 특성
| CAS No. | 68156-13-8 |
|---|---|
| 분자식 | C24H19S2.F6P |
| 평균 분자량 | 516.5 g/mol |
| 단동위원소 질량 | 516.05699892 g/mol |
| SMILES | F[P-](F)(F)(F)(F)F.c1ccc(Sc2ccccc2[S+](c2ccccc2)c2ccccc2)cc1 |
| InChIKey | SFWSATMGMAKCIF-UHFFFAOYSA-N |
| PubChem CID | 155018 |
| EC No. | 269-006-0 |
| DTXSID | DTXSID30987658 |
| 현지명 | 디페닐[(페닐티오)페닐]술포늄헥사플루오로포스페이트 |
화학 및 물리적 성질
| 극성 표면적 | 26.3 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 8 |
| 회전 가능 결합 수 | 5 |
| 무거운 원자 수 | 33 |
| 형식 전하 | 0 |
| 복잡도 | 436 |
| 녹는점 | 112-114 °C(Solv: methanol (67-56-1)) |
| InChI | InChI=1S/C24H19S2.F6P/c1-4-10-20(11-5-1)25-21-16-18-24(19-17-21)26(22-12-6-2-7-13-22)23-14-8-3-9-15-231-7(2,3,4,5)6/h1-19H/q+1 |
| InChIKey | MUVYOKJVJZFJTI-UHFFFAOYSA-N |
| SMILES | [S+](C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=C(C=C1)SC1=CC=CC=C1.[P-](F)(F)(F)(F)(F)F |
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 2.5% (55 of 2208) of reports.WarningH317 (96.6%): May cause an allergic skin reaction [Warning Sensitization, Skin]P261, P264+P265, P272, P280, P302+P352, P305+P351+P338, P321, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2208 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.This chemical does not meet GHS hazard criteria for 50% (1 of 2) of reports. |
|---|---|
| 규제 정보 | Chemical: Sulfonium, diphenyl[(phenylthio)phenyl]-, hexafluorophosphate(1-)Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate(1-): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| Hazard Classes and Categories | Skin Sens. 1 (96.6%)Skin Irrit. 2 (50%) |
| 신호 어 | Warning |
| 유해·위험 문구 | 암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드 H315 |
용도
용도
Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate (SON) can serve as a cationic photoinitiator in two-component photoinitiating systems with diphenyl sulfone-based dyes (DSOs). These systems are utilized to initiate the cationic polymerization of epoxides (like E51) under a 405 nm LED light source[1].