CAS 1760-24-3 (Trimethoxysilylpropyl)ethylenediamine (HCID 15659)

개요

RN given refers to parent cpd; a silylating agent

이름 및 식별자

우선 이름: (Trimethoxysilylpropyl)ethylenediamine
IUPAC: N'-(3-trimethoxysilylpropyl)ethane-1,2-diamine
현지명: N-[3-(트리메톡시실릴)프로필]-1,2-에탄디아민
영어명: N-[3-(Trimethoxysilyl)propyl]ethylenediamine
분자식: C8H22N2O3Si
분자량: 222.36

이름 및 동의어

en-APTASDow corning Z-6020 silane(trimethoxysilylpropyl)ethylenediamineN-(3-Trimethoxysilylpropyl)-ethylenediamineDTXSID5027433Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy-28ZCS5GA8GETHYLENEDIAMINE, N-(3-(TRIMETHOXYSILYL)PROPYL)-Aminoethyl-aminopropyl-trimethoxysilaneN-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamineDTXCID607433N-[3-(trimethoxysilyl)propyl]ethane-1,2-diamine

이름 더 보기

N-[3-(트리메톡시실릴)프로필]-1,2-에탄디아민N-[3-(트라이메톡시시릴)프로필]에틸렌다이아민)(AEAPTMS)N-[3-(트리메톡시실릴)프로필]-1,2-에탄디아민(N-[3-(TRIMETHOXYSILYL)PROPYL]-1...(트라이메톡시시릴프로필)에틸렌다이아민[3-[(2-아미노에틸)아미노]프로필]트라이메톡시실란[N-(베타-아미노에틸)-감마-아미노프로필]트라이에톡시실란[감마-(베타-아미노에틸아미노프로필)]트라이메톡시실란1,2-에탄다이아민, N-[3-(트라이메톡시시릴)프로필]-3-[[[N-(2-아미노에틸)아미노]프로필]트라이메톡시]실란A-1120AEAPTMSAP 132Dow Corning Z-6020 실란KBM 603N-(2-아미노에틸)-3-(아미노프로필)트라이메톡시실란N-(2-아미노에틸)-3-프로필아미노트라이메톡시실란N-[(트라이메톡시시릴)프로필]에틸렌다이아민N-[3-(트라이메톡시시릴)프로필]-에틸렌다이아민N-[3-(트라이에톡시시릴)프로필]-1,2-에틸렌다이아민SH 6020KH-792N-(2-AMINOETHYL)-3-AMINOPROPYLTRIMETHOXYSILANEDAMON1-(3-(TriMethoxysilyl)propyl)ethane-1,2-diaMineKH－791gf91kbm603(AMINOETHYL)-3-AMINOPROPYLTRIMETHOXY-SILANE

1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)-N-[3-(Trimethoxysilyl)propyl]-1,2-ethanediamine1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]-N-(3-(TRIMETHOXYSILYL)PROPYL)ETHANE-1,2-DIAMINEN-AAPTN-silaneRefChem:826123trimethoxysilylpropylethylenediaminen-(2-aminoethyl)-3-aminopropyl-trimethoxysilane

데이터베이스 식별자

CAS: 1760-24-3
PubChem CID: 15659
DTXSID: DTXSID5027433
ChEMBL: CHEMBL3188366
UNII: 28ZCS5GA8G
EC Number: 217-164-6
Nikkaji: J53.972D

물성

구조 계산 물성

극성 표면적: 65.7 Å²
수소 결합 공여자 수: 2
수소 결합 수용자 수: 5
회전 가능 결합 수: 9
무거운 원자 수: 14
형식 전하: 0
복잡도: 125

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metalloid Compounds (Silicon)

Density1.01 @25 °C

Vapor Pressure0.03 [mmHg]

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2건

Liquid

Light yellow liquid; [Sigma-Aldrich MSDS]

물리화학적 성질

녹는점: 0 °C · 0°C
끓는 점: 146 °C15 · 146 °C15 mm Hg(lit.)
밀도: 1.028 g/mL · 1.028 g/mL at 25 °C(lit.)
증기압: 1.5 hPa · 1.5 hPa (20 °C)
굴절률: 20 · n20/D 1.444(lit.)
인화점: 220 °F · 220 °F
저장 조건: 30 °C · Store below +30°C.
용해도: 톨루엔과 혼합 가능.
물리적 상태: 액체
산도 계수 (pKa): 10.11 · 10.11±0.19(Predicted)
Specific Gravity: 1.01 · 1.01
색상: 무색투명~연황색
수소이온지수(pH): 10 · 10 (10g/l, H2O, 20℃)
수용성: 물과 반응
BRN: 636230 · 636230
InChI: 1S/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3
InChIKey: PHQOGHDTIVQXHL-UHFFFAOYSA-N
SMILES: CO[Si](CCCNCCN)(OC)OC
LogP: -4 · -4--0.82 at 20℃
NIST: N-(2-Aminoethyl-3-aminopropyl)trimethoxysilane(1760-24-3)
EPA: 1 · 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- (1760-24-3)

화학적 성질

Colorless transparent liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 28.7% (514 of 1791) of reports.

Danger

H302 (10.9%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P330, P332+P317, P333+P317, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1791 reports by companies from 45 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: 1,2-Ethanediamine, N-[3-(trimethoxysilyl)propyl]-

1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 05-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15039

1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to environment

Hazards Summary · 1건

Rapidly hydrolyzed; A moderate skin and severe eye irritant in rabbits; Skin sensitizing potential observed in guinea pig maximization test; No systemic toxicity, reproductive toxicity, or developmental toxicity observed in repeated-dose oral study of rats at doses up to 500 mg/kg/day; [OECD SIDS: N-(3-(Trimethoxysilyl)propyl)ethylenediamine (AEAPTMS) - 2003] May cause eye injury and skin sensitization; [ECHA REACH Registrations] Reacts with water producing methanol; An irritant that may cause serious eye injury; May cause skin sensitization; [Sigma-Aldrich MSDS] See Silane, (4-aminobutyl)diethoxymethyl-. See Methyl alcohol.

Hazard Classes and CategoriesAcute Tox. 4 (10.9%)

안전 및 보호

Protective Action Criteria (PAC) · 3건

1.6 [mg/m3]

18 [mg/m3]

110 [mg/m3]

독성 정보

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: KV7400000
ridadr: UN 3267 8/PG 2
독성: LD50 orally in Rabbit: 2413 mg/kg LD50 dermal Rat > 2000 mg/kg
HS 번호: 29310095
risk_code: 38-41-43-52/53-42/43-37/38
hazard_code: Xn,Xi
safety_code: 26-39-61-37/39-24-36/37/39-23
포장분류: III
위험 등급: 8
기존화학 물질: KE-34385
F 고인화성물질: 1-10
자연 발화 온도: 300 °C
Hazard Classifications: Acute Tox. 4 InhalationEye Dam. 1Skin Sens. 1BSTOT RE 2 Inhalation
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

Uses · 2건

A silylating agent. [ChemIDplus] Used as a coupling agent, adhesion promoter, and crosslinker in fiberglass, adhesives, sealants, foundry resins, and coatings; [OECD SIDS: N-(3-(Trimethoxysilyl)propyl)ethylenediamine (AEAPTMS) - 2003]

Molding and Core Making [Category: Foundry]

U.S. Production2023: 1,000,000 - <2,500,000 lb

Consumer UsesAdhesion/cohesion promoter

Industry UsesPlating agent

Household ProductsInformation on 4 consumer products that contain N-(3-(Trimethoxysilyl)propyl)ethylenediamine in the following categories is provided:

General Manufacturing Information · 2건

All Other Basic Inorganic Chemical Manufacturing

1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]-: ACTIVE

응용 분야 · 1건

용도N-[3-(Trimethoxysilyl)propyl]ethylenediamine has also been used as an organic ligand for the surface modification of silica gel to uptake heavy metal ions. It can react with fluorinated carbon nanotubes (F-CNT) to form aminoalkylalkoxysilane functionalized carbon nanotubes.