10124-56-8O=P(=O)[O-].[Na+]AQMNWCRSESPIJM-UHFFFAOYSA-MThe CIR Expert Panel concluded that the following 31 ingredients are safe in the present practices of use and concentration in cosmetics as described in this safety assessment, when formulated to be non-irritating...Sodium Metaphosphate...
Cosmetic ingredients (Sodium Metaphosphate) -> CIR (Cosmetic Ingredient Review)
Buffering; Chelating
White powder. Practically insol in water and in aq solns of pyrophosphates and hexametaphosphates. Sol in mineral acids. Does not form complexes with Fe(II), Fe(III), U(IV) salts. /Maddrell's salt (polymeric sodium metaphosphate)/
Sol in water (pH adjusted to 8-8.6). Insol in organic solvents. Possess dispersing and deflocculating properties, coagulate albumins, and inhibit the crystallinization of slightly sol compds such as calcium carbonate and calcium sulfate. /Glassy sodium metaphosphate; Graham's salt/
Large Crystals; Dry Powder
White solid, practically insoluble in water; [Merck Index]
This chemical does not meet GHS hazard criteria for 90.5% (526 of 581) of all reports.
Not Classified
Aggregated GHS information provided per 581 reports by companies from 8 notifications to the ECHA C&L Inventory.
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Chemical: Metaphosphoric acid (HPO3), sodium salt
Chemical: Metaphosphoric acid, sodium salt
Metaphosphoric acid (HPO3), sodium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Metaphosphoric acid (HPO3), sodium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 11-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14376
Metaphosphoric acid (HPO3), sodium salt: Does not have an individual approval but may be used under an appropriate group standard
Metaphosphoric acid, sodium salt: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
It changes to sodium trimetaphosphate above 505 deg C and to sodium hexametaphosphate above 607 deg C; [Merck Index] Intraperitoneal LD50 (mouse) = 830 mg/kg; Acute tubular necrosis is adverse effect in IP lethal dose studies; [ChemIDplus] See Sodium tetrametaphosphate.
CIR ingredient: Sodium Metaphosphate
Used in toothpaste and dentifrices (abrasive), detergents, water softeners, food additives (sequestrant and emulsifier), and textile processing; [HSDB]
Textiles (Fiber & Fabric Manufacturing) [Category: Industry]
Used in toothpaste formulations as an abrasive.
Dental polishing agents, detergent builders, water softeners, sequestrants, emulsifiers, food additives, textile processing, laundering. /Sodium metaphosphate/
In dentifrices, polishing agents, abrasive detergents. /Maddrell's salt (polymeric sodim metaphosphate)/
2023: 1,135,421 lb
(1977) 5.93X10+10 GRAMS
(1979) 6.71X10+10 GRAMS
Dehydration of sodium phosphates (e.g. Na2H2P2O7, NaH2PO4, Na2HPO4). Upon heating NaH2PO4 or NaNH4HPO4 to 250 °C and then slowly to 350 °C, first Na2H2P2O7 and then the insol Maddrell's salt is obtained, which is stable to about 500 °C; at 505 deg it changes to sodium trimetaphosphate, and above 607 °C to sodium hexametaphosphate. According to Maddrell, Ann. 61, 63 (1847) the salt may be prepd by heating two parts NaNO3 with one part H3PO4. An improved procedure is described by v. Knorre, Z. Anorg. Chem. 24, 397 (1900). /Maddrell's salt (polymeric sodium metaphosphate)/
Prepd by rapidly chilling molten sodium metaphosphate. /Glassy sodium metaphosphate; Graham's salt/
불러오는 중…
10124-56-8、10361-03-2、14550-21-1、50813-16-6DTXSID6040244The sodium polyphosphates class consists of several amorphous, water soluble polyphosphates composed of linear chains of metaphosphate units, (NaPO3)x where x ≥ 2, terminated by Na2PO4- groups. They are usually identified by their Na2O/ P2O5 ratio or their P2O5 content. The Na2O/P2O5 ratios vary from about 1.3 for sodium tetrapolyphosphate, where x = approximately 4; through about 1.1 for Graham’s salt, commonly called sodium hexametaphosphate, where x = 13 to 18; to about 1.0 for the higher molecular weight sodium polyphosphates, where x = 20 to 100 or more. The pH of their solution varies from about 3 to 9. For additional details of description, refer to Burdock (1997).
Not Classified
Skin Irrit. 2 (100%)
Not Classified
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
2.7 [mg/m3]
30 [mg/m3]
180 [mg/m3]
The CIR Expert Panel concluded that the following 31 ingredients are safe in the present practices of use and concentration in cosmetics as described in this safety assessment, when formulated to be non-irritating...Sodium Metaphosphate...
Safe for use in cosmetics, with qualifications
Food Additives -> EMULSIFIER; SEQUESTRANT; TEXTURIZER; THICKENER -> JECFA Functional Classes
Food Additives -> EMULSIFIER; SEQUESTRANT; TEXTURIZER; THICKENER -> JECFA Functional Classes
Food Additives -> EMULSIFIER; SEQUESTRANT; TEXTURIZER; THICKENER -> JECFA Functional Classes
Cosmetics -> Buffering; Chelating
Not Known or Reasonably Ascertainable
Metaphosphoric acid (HPO3), sodium salt (1:1): ACTIVE
SODIUM METAPHOSPHATE INHIBITED GROWTH OF E COLI.
(NaPO3)n where "n" may be 2 or more. Several different forms are known.
(NaPO3)n. The value of n ranges from 3 to 10 (cyclic molecules) or may be much larger number (polymer). The vitreous sodium phosphates having N2O/P2O5 mole ratios near unity are classified as sodium metaphosphates (Graham's salts). The average number of of phosphorus atoms per molecule in these glasses ranges from 25 to infinity.
The term sodium metaphosphate has also been extended to short-chain vitreous compositions, the molecules of which exhibit the polyphosphate formula Na(n+2)PnO(3n+1) with n as low as 4-5. These materials are more correctly called sodium pyrophosphates.
용도1. 금 속이온 봉쇄작용, 완충작용, 분산작용, 세척작용 2. 수처리, 제지, 염 색조제, 금속표면처리, 방 첨 제 3. 육류의 결착성을 향상시키므로 햄, 소시지 어륙반죽 제품에 0.3% 용된 다. 4. 간장, 된 장 의 변색방지, 점조성부여등의 목적으로 0.01~0.2%첨가. 5. 물엿의 변색, 착색방지, 주류 청량 음 료 등의 침전방지에도 효과가 있으며 밀국수, 메밀국수, 기타 면의 감촉을 좋게하고 수산물 건제품 의 지방산화를 억제하 며, 광택유지에 효과가 있다. 6. 게, 연어, 송어, 다랑어등의 통조림에 생 성 되는 struvite방지
용도sodium hexametaphosphate is a chelating agent and a corrosion inhibitor. This is an inorganic salt.
Sodium hexametaphosphate is prepared by heating monosodium phosphate (NaH2PO4) rapidly to a clear melt, which occurs slightly above 625°C. Rapid chilling of this melt produces a very soluble glass, which is then crushed or milled.