2-Bromobiphenyl

HCID 16329CAS 2052-07-5

기본 정보

표준 SMILES
Brc1ccccc1-c1ccccc1
InChIKey
KTADSLDAUJLZGL-UHFFFAOYSA-N
분자식
C12H9Br
평균 분자량
233.1 g/mol
단동위원소 질량
231.98876239

개요

2-bromobiphenyl is a clear liquid. Insoluble in water. (NTP, 1992)

이름 및 식별자

우선 이름
2-Bromobiphenyl
IUPAC
1-bromo-2-phenylbenzene
영어명
2-Bromobiphenyl
분자식
C12H9Br
분자량
233.1

이름 및 동의어

2-Bromobiphenyl2-Bromo-1,1'-biphenyl1,1'-Biphenyl, 2-bromo-1-bromo-2-phenylbenzeneO-BROMOBIPHENYLBiphenyl, 2-bromo-2-BromodiphenylDTXSID0024638m-biphenyl bromide2-BIPHENYLYL BROMIDEGXS4234YXD2-biphenyl bromide
이름 더 보기
PBB NO 12-Brombiphenyl2- BromobenzeneBROMOBIPHENYL(2-)
CCRIS 5888EINECS 218-141-3NSC 67353NSC-67353BROMOBIPHENYL, 2-UNII-GXS4234YXD2-PHENYLBROMOBENZENEPBB 1

데이터베이스 식별자

CAS
2052-07-5
PubChem CID
16329
DTXSID
DTXSID0024638
ChEMBL
CHEMBL1462584
UNII
GXS4234YXD
EC Number
218-141-3
Nikkaji
J95.603A

물성

구조 계산 물성

XLogP
4.6
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
1
무거운 원자 수
13

실험 및 물리화학적 성질

SpringerMaterials Properties13C nuclear magnetic resonance spectrum
LogP4.59
Density1.2175 (NTP, 1992) - Denser than water; will sink
SolubilityInsoluble (NTP, 1992)
Boiling Point565 to 568 °F at 760 mmHg (NTP, 1992)
Melting Point34.7 to 35.6 °F (NTP, 1992)

물리화학적 성질

녹는점
1.5 · 1.5-2 °C(lit.)
끓는 점
297 · 297-298 °C(lit.)
밀도
1.352 g/mL · 1.352 g/mL at 25 °C(lit.)
굴절률
20 · n20/D 1.628(lit.)
인화점
113 °C · 113 °C
저장 조건
Sealed in dry,Room Temperature

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 6.2% (2 of 32) of reports.

Warning

H315 (93.8%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 32 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

S - indicates a substance that is identified in a final Significant New Use Rule.

Status: Active Update: 10-01-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/30357

Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Reactive GroupAryl Halides
Reactivity Profile2-BROMOBIPHENYL is sensitive to light. Low reactivity. (NTP, 1992)
Air and Water ReactionsInsoluble in water.
Hazard Classes and CategoriesSkin Irrit. 2 (93.8%)

안전 및 보호

Fire FightingFires involving this material should be controlled using a dry chemical carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

안전 데이터

wgk
3
tsca
TSCA listed
HS 번호
29036990
risk_code
36/37/38-20/21/22
hazard_code
Xi,Xn
safety_code
23-24/25-37/39-26-36

화학 및 산업

용도 및 제조

General Manufacturing Information1,1'-Biphenyl, 2-bromo-: ACTIVE
응용 분야 · 2건

용도It is used as an intermediate of organic synthesis and pharmaceutical. It also can react with norborn-2-ene to get 5-phenyl-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene, in synthesis of a novel trispirocyclic hydrocarbon. It is used as a reference compound to investigate extraction efficiency of solid-phase micro extraction fibers, based on methacrylic acid-trimethylolpropanetrimethacrylate copolymers.

일반 설명Clear liquid. Insoluble in water.

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]

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