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구리 아세트산 모노수화물

Cupric acetate monohydrate

HCID 165397
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
6046-93-1
표준 SMILES
CC(=O)[O-].CC(=O)[O-].O.[Cu+2]
InChIKey
NWFNSTOSIVLCJA-UHFFFAOYSA-L
분자식
C4H8CuO5
평균 분자량
199.65 g/mol
단동위원소 질량
198.96677086

개요

See also: Copper (II) acetate, monohydrate (annotation moved to); Copper di(acetate) hydrate (annotation moved to).

이름 및 식별자

우선 이름
Cupric acetate monohydrate
IUPAC
copper;diacetate;hydrate
현지명
구리 아세트산 모노수화물
영어명
Copper (II) acetate monohydrate
분자식
C4H8CuO5
분자량
199.65

이름 및 동의어

Copper(II) acetate monohydrateCupric acetate monohydrateCopper(2+) acetate, monohydrate39J9V52S86DTXSID90209202RefChem:580026DTXCID701316936046-93-1Copper(II) acetate hydratecopper acetate monohydrate66923-66-8Copper (II) Acetate Monohydrate
이름 더 보기
결정녹청(CRYSTALLIZEDVERDIGRIS)구리(II)아세트산모노수화물(COPPER(II)ACETATEMONOHYDRATE)구리아세트산모노수화물구리아세트산모노수화물아세트산,구리(2+)염,모노수화물(ACETICACID,COPPER(2+)SALT,MONOHYDRATE)구리(2+)아세트산모노수화물(COPPER(2+)ACETATEMONOHYDRATE)구리디아세트산모노수화물(COPPERDIACETATEMONOHYDRATE)중성녹청구리아세트산모노수화물COPPER ACETATECuAcCu(OAc)2·H2O205-553-3CopperdiacetatemonohydrateVERDIGRIS
Copper diacetate monohydrateAcetic acid, copper(2+) salt, monohydratecopper;diacetate;hydrateC4H8CuO5Copper(II) acetate xhydrateCopper (II) acetate hydrateCopper(II)acetate monohydratecopper acetate hydrate

데이터베이스 식별자

CAS
6046-93-1
PubChem CID
165397
DTXSID
DTXSID90209202
UNII
39J9V52S86
EC Number
611-978-9

물성

구조 계산 물성보충 중

극성 표면적
81.3 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
5
회전 가능 결합 수
0
무거운 원자 수
10
형식 전하
0
복잡도
25.5

실험 및 물리화학적 성질

Chemical ClassesMetals -> Organic Acids, Metal Salts
Melting Point115 °C
Physical DescriptionDark green solid; [Merck Index] Blue-green odorless powder; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
115 °C · 115 °C
끓는 점
240 °C · 240 °C
밀도
1.88 · 1.88
증기 밀도
6.9 · 6.9 (vs air)
저장 조건
5 °C · Store at +5°C to +30°C.
용해도
72 g/L · 72g/L
물리적 상태
고체
색상
짙은 녹색
Specific Gravity
1.882 · 1.882
수소이온지수(pH)
5.2 · 5.2-5.5 (20g/l, H2O, 20℃)
냄새
약간의 아세트산 냄새
수용성
72 g/L · 72g/L(20℃)
Merck
14 · 14,2624
BRN
3730548 · 3730548

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 235 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

유해성 정보

Regulatory Information · 2건

Chemical: Acetic acid, copper(2+) salt, monohydrate

Regulation (EC) No 1831/2003 (amended)

Other Safety InformationIMAP assessments - Acetic acid, copper(2+) salt, monohydrate: Human health tier I assessment
Hazards SummaryA skin and strong eye irritant; Harmful by ingestion; [Alfa Aesar MSDS] See Copper(II) acetate.
Hazard Classes and Categories · 2건

Acute Tox. 4 (100%)

Acute toxicity (Oral) - Category 4

안전 및 보호

Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Threshold Limit Values (TLV)1.0 [mg/m3], as Cu

화학 및 산업

용도 및 제조

Uses · 2건

Used to make Paris Green and Fehling's reagent, as a fungicide, catalyst, ceramic pigment, and in textile dyeing; [Merck Index]

Farming (Pesticides) [Category: Industry]

응용 분야 · 1건

일반 설명Copper (II) acetate monohydrate is soluble in water and slightly soluble in methanol, diethylether and acetone. It can be synthesized by reacting acetic acid with copper (II) carbonate or copper(II) hydroxide or copper (II) oxide. Large scale commercial production is undertaken by placing copper metal in the presence of air and refluxing acetic acid. As a transition metal acetate, it can be used to form oxide nanoparticles by sonochemical methods.

제조 방법 · 1건

Copper(II) acetate monohydrate can easily be produced by the reaction of acetic acid solutions with copper(II) carbonate or copper(II) hydroxide or by the reaction of copper(II) oxide with hot acetic acid. Large-scale commercial production uses copper metal in the presence of air and refluxing acetic acid. Copper(II) acetate monohydrate is used as a catalyst in the polymerization of organic materials and as a mordant in the dying of textiles. It is also used as a ceramic pigment and as a fungicide.

상·하류 제품 정보

상류 원료

황산동(II)아세트산(빙초산)탄산 제II구리탄산나트륨(경회)

하류 제품

아디핀산

관련 반응

144건
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안정성
안정적인. 산화제와 호환되지 않습니다.
InChI
1S/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2
InChIKey
NWFNSTOSIVLCJA-UHFFFAOYSA-L
SMILES
O.CC(=O)O[Cu]OC(C)=O
LogP
-0.285 · -0.285 (est)

화학적 성질

Copper acetate monohydrate is a greenish Blue powder or small crystals with odour of acetic acid.

Permissible Exposure Limit (PEL)
1.0 [mg/m3], as Cu
Protective Action Criteria (PAC) · 3건

9.4 [mg/m3]

23 [mg/m3]

140 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

독성 정보

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

안전 데이터

wgk
3
tsca
Yes
rtecs
AG3500000
ridadr
UN 3077 9/PG 3
독성
LD50 orally in Rabbit: 501 mg/kg
HS 번호
29152900
risk_code
22-36/37/38-50/53-34
hazard_code
Xn,N,Xi,C
safety_code
36/37/39-60-61-36-26-45
포장분류
III
위험 등급
9
Hazard Classifications
Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 2Eye Dam. 1Skin Corr. 1B
스토리지 클래스
8B - Non-combustible corrosive hazardous materials
3-Fluoropyridine-2-carboxylic acid
2,4-펜탄디온
Nabumetone
3-(Methylthio)butanal
Dye-fixing agent M
6-Methyl-2-(methylsulfanyl)pyrimidin-4-ylamine
a copper chelate
3,4-헥산디온
요오드아세트산
프로피온산
메틸(3-)티오프로피온알데히드
1,3- 디페닐구아니딘
2-Amino-6-t-butyl-4-(trifluoromethyl)pyrimidine
크로톤산
DL-메티오닌
calcium copper phosphate
옥신-구리
황산동
NETILMICIN 황산염
phthalogen auxiliary agent K
4-Chloro-6-methyl-2-(methylthio)pyrimidine
6-Methyl-2-(methylthio)pyrimidin-4-ol
벤질
L-메티오닌
2-Mercapto-6-methylpyrimidin-4-ol