Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
O-크레실 글리시딜 에테르
O-크레실글리시딜에테르 · O-크레실글리시딜에테르(O-CRESYLGLYCIDYLETHER) · 2,3-에폭시프로필-오-톨일에터 · 2-[(2-메틸페녹시)메틸]옥시란 · 2-Methylphenyl glycidyl ether · DY 023 · Nsc11571 · o-cresyl
식별자 및 물리적 특성
| CAS No. | 2210-79-9 |
|---|---|
| 분자식 | C10H12O2 |
| 평균 분자량 | 164.2 g/mol |
| 단동위원소 질량 | 164.08372962 g/mol |
| SMILES | Cc1ccccc1OCC1CO1 |
| InChIKey | KFUSXMDYOPXKKT-UHFFFAOYSA-N |
| PubChem CID | 16640 |
| ChEMBL | CHEMBL1445408 |
| EC No. | 218-645-3 |
| DTXSID | DTXSID8024862 |
| 현지명 | O-크레실 글리시딜 에테르 |
화학 및 물리적 성질
| XLogP | 2.4 |
|---|---|
| 극성 표면적 | 21.8 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 2 |
| 회전 가능 결합 수 | 3 |
| 무거운 원자 수 | 12 |
| 형식 전하 | 0 |
| 복잡도 | 147 |
| Polymers | Plastics & Rubber -> Glycidyl Ethers |
| 밀도 | 1.09 at 68 °F (NTP, 1992) - Denser than waterwill sinkRelative density (water = 1): 1.081.079 g/mL at 25 °C (lit.) |
| 용해도 | less than 1 mg/mL at 72 °F (NTP, 1992)Solubility in water: none |
| 인화점 | 200 °F (NTP, 1992)113 °C c.c.>230 °F |
| 끓는 점 | 498 °F at 760 mmHg (NTP, 1992)at 0.533kPa: 109-111 °C109-111 °C/4 mmHg (lit.) |
| 증기 밀도 | Relative vapor density (air = 1): 5.7>1 (vs air) |
| Physical Description | O-cresyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)Clear light yellow liquid[CAMEO]COLOURLESS LIQUID. |
| 증기압 | 0.514Pa at 20℃ |
| 굴절률 | n20/D 1.529(lit.) |
| 물리적 상태 | liquid |
| 용해도 | 840mg/L at 21℃ |
| BRN | 4585 |
| InChI | InChI=1S/C10H12O2/c1-8-4-2-3-5-10(8)12-7-9-6-11-9/h2-5,9H,6-7H2,1H3 |
| InChIKey | KFUSXMDYOPXKKT-UHFFFAOYSA-N |
| SMILES | O1CC1COC1=CC=CC=C1C |
| LogP(분배 계수) | 2.5 at 21℃ |
| NIST | Oxirane, [(2-methylphenoxy)methyl]-(2210-79-9) |
| EPA | o-Cresyl glycidyl ether (2210-79-9) |
안전 및 규제
| GHS 분류 | WarningH315: Causes skin irritation [Warning Skin corrosion/irritation]P203, P261, P264, P272, P273, P280, P302+P352, P318, P321, P332+P317, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
|---|---|
| 규제 정보 | Chemical: Oxirane, [(2-methylphenoxy)methyl]-Oxirane, 2-[(2-methylphenoxy)methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[(2-methylphenoxy)methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.Status: Active Update: 05-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14553Oxirane, [(2-methylphenoxy)methyl]-: Does not have an individual approval but may be used under an appropriate group standard |
| 기타 안전 정보 | IMAP assessments - Oxirane, [(2-methylphenoxy)methyl]-: Environment tier I assessment |
| 운송 라벨(DOT) | Class 9 |
| 화재 위험 | This chemical is combustible. (NTP, 1992) |
| 건강 유해성 | SYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin and eyes, and allergic dermatitis. |
| 유해성 요약 | May cause skin sensitization[ICSC] Danger of skin sensitization[MAK] |
| 반응성 그룹 | Ethers |
| EC 분류 | Symbol: Xn, NR: 38-43-68-51/53S: (2)-36/37-61Note: C |
| Reactivity Profile | O-CRESYL GLYCIDYL ETHER may attack some forms of plastics. (NTP, 1992) |
| Chemical Dangers | The substance can presumably form explosive peroxides. Reacts with acids, amines, bases and strong oxidants. |
| Air and Water Reactions | Insoluble in water. |
| Hazard Classes and Categories | Skin Irrit. 2 (100%)Skin irritation - category 2Serious eye damage/eye irritation - Category 2BSkin sensitization - Category 1ASkin corrosion/irritation - Category 2Muta. 2 |
| 소화 | Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)Use water spray, foam, powder, carbon dioxide. |
| 응급 조치 | Fresh air, rest.Remove contaminated clothes. Rinse and then wash skin with water and soap.First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Rinse mouth. |
| 응급 처치 | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
| 안전 보관 | Separated from strong oxidants, strong bases, strong acids and amines. Cool. Keep in the dark. |
| 비화재 누출 대응 | SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
| 누출 처리 | Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
| Isolation and Evacuation | Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: |
| Eye Prevention | Wear safety goggles or eye protection in combination with breathing protection. |
| Fire Prevention | NO open flames. |
| Inhalation Risk | No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C. |
| Skin Prevention | Protective gloves. Protective clothing. |
| Exposure Prevention | AVOID ALL CONTACT! |
| 유해 작용 | Skin Sensitizer - An agent that can induce an allergic reaction in the skin. |
| Signs and Symptoms | Cough. Sore throat.Redness. Pain. |
| Toxicity Data | LC50 (rat) = 6,090 mg/m3/4h |
| 수질 위해 등급(WGK) | 2 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | TZ3700000 |
| 운송 번호(UN) | UN 3082 9/PG 3 |
| 관세 코드 | 29109000 |
| 위험 문구(R) | 36/37/38-68-51/53-43-38 |
| 위험 표시 | Xi,N,Xn |
| 안전 문구(S) | 26-37/39-61-36/37 |
| 포장분류 | III |
| 위험 등급 | 9Aquatic Chronic 2Muta. 2Skin Irrit. 2Skin Sens. 1A |
| 기존화학 물질 | KE-24799 |
| 저장 분류 | 10 - Combustible liquids |
용도
일반 설명
Clear light yellow liquid.